A method for developing transient, predictive models of gas turbine engine performance using system identification techniques in conjunction with test cell data has been successfully demonstrated. Test cell data were obtained for both transient and steady-state operation from two F402-RR-406A USMC AV-8B engines at the Naval Aviation Depot (NADEP), Cherry Point, North Carolina. One engine was run to gather a single set of steady-state data consisting of 24 subsets of five seconds of data. The other engine was run to obtain two sets of transient data, recorded at three different rates of engine acceleration for each set. The acceleration rates of 3, 25, and 100 degrees of throttle per second were preset in the test cell controls. These rates correspond to the angular velocity of the fuel throttle during an acceleration. Each of these six transient test runs consisted of 25 seconds of data. Data were captured at a rate of five Hertz over the engine operating range from idle (26% Low Pressure spool speed) to full military power (105% LP spool speed) for all cases. A BASIC code developed at the NADEP required significant modification before it could be used to reduce the data. The modified code generated engine operating points consisting of mass flow rate, total pressure ratio, spool speed, and rate of acceleration for the inner fan, outer fan, and high pressure compressor. Finally, a multivariate regression technique using the SAS language was developed in cooperation with the Virginia Tech Statistical Consulting Center. This technique was used to generate a closed-form model of each component capable of predicting operating points at spool speeds and acceleration rates intermediate to those measured. / Master of Science

京都大学 / 新制・課程博士 / 博士(理学) / 甲第24169号 / 理博第4860号 / 新制||理||1695(附属図書館) / 京都大学大学院理学研究科物理学・宇宙物理学専攻 / (主査)教授 田中 貴浩, 准教授 久徳 浩太郎, 教授 橋本 幸士 / 学位規則第4条第1項該当 / Doctor of Science / Kyoto University / DFAM

Part B of two parts. Part A found at: http://hdl.handle.net/11375/18745 / <p> This report studies the xenon transient behaviour in a CANDU reactor as a function of time after shutdown, start-up and power setbacks. In addition, load cycling transients were obtained for typical daily load requirements. </p> / Thesis / Master of Engineering (MEngr)

<p> The photochemistry of 1,1-diphenylsilacyclobutane has been studied by steady-state and nanosecond laser flash photolysis (NLFP) techniques in order to investigate the mechanism of reaction of a transient silene with alcohols. NLFP of 1,1-diphenylsilacyclobutane (I) in acetonitrile solution at 325 nm results in the formation of 1,1-diphenylsilene (II) derived from excited-state [2+2]-cycloreversion of the silacyclobutane. The transient has a lifetime of 100 ns - 1.2 μS in acetonitrile solution at room temperature, depending on the presence of water in the solvent. Steady-state photolysis in the presence of various σ-bonded nucleophiles such as methanol results in the generation of a single product in each case, consistent with addition of the nucleophile to the silene (II). Absolute rate constants (kq) have been determined by NLFP techniques for reactions of the silene with water, methanol, ethanol, tert-butyl alcohol, 2-propanol, 2,2,2-trifluoroethanol, 1,1,1,3,3,3-hexafluoroisopropanol, and glacial acetic acid. The rate constants (kq) illustrate the following characteristics: linear quenching plots characteristic of second order kinetics, observation of small but detectable deuterium kinetic isotope effects, and an inverse Arrhenius temperature dependence. Two possible mechanisms will be discussed based on these results. (See Mechanisms in Thesis)</p> / Thesis / Master of Science (MSc)

<p> A multiple temporal-mode transformation is applied to the finite difference form of the space-dependent reactor kinetics equations with the aim of reducing the truncation error. The transformation method is incorporated into an existing alternaing-direction explicit code and is tested on three homogeneous problems in one and two dimenisions as well as on a one-dimensional space-dependent CANDU-type problem. The numerical results have confirmed some characteristics of this solution formalism with respect to accuracy and stability. In addition, this study has identified some areas for improvement to the multiple temporal-mode trans-· formation technique. </p> / Thesis / Master of Engineering (MEngr)

A near-net-shape process for the production of mullite matrix ceramic composites below 1300 °C has been achieved by reaction bonding AI2O3, silicon, mullite seeds and a eutectic of A12O3-SiO2-mixed rare earth oxide. The roles of the transient liquid phase from the eutectic and the mullite seeds are examined. The approximate eutectic composition was estimated from the A12O3-SiO2-Y2O3 phase diagram as 22 wt % AI2O3/46 wt% S102/3 2 wt% Y2O3. The fusion temperature of the mixed-rare-earth-based eutectic composition was lower (1175 °C vs. those of pure, rare earth oxides based eutectic composition; Pr6On/A12O3/SiO2: 1224 °C, EU2O3/AI2O3/S1O2: 1259 °C and Y2O3/Al2O3/SiO2: 1345 °C). The densification characteristics of the reaction-bonded mullite (RBM) mixture were investigated. Density increased with eutectic, and decreased with mullite seed contents. Oxidation and volume expansions due to Si and mullite formation are examined by thermogravimetric analysis (TGA) and dilatometric measurement. TThe measured weight gain and maximum volume expansion were lower than theoretical values due to preoxidation of the Si powder. Dilatometric curves indicated sintering shrinkage is compensated by the oxidation-induced volume-expansion. AI2O3 + SiO2 mixtures of the mullite composition exhibited shrinkage exclusively. X-ray diffraction of the RBM sinters display major mullite peaks and minor residual a-A12O3. Mullite develops with low residual AI2O3 when 7.5 wt% mixed-rare-earth-oxide eutectic and 5 wt% mullite seeds are incorporated into the mix. The final sinter is > 90 % theoretical density, > 90 % mullite, and suffers 2.2 % sintering shrinkage. Transmission-electron-microscopy (TEM) and Energy dispersive X-ray spectra (EDX) were employed to follow mullite evolution. Model samples were utilised to study diffusion-, and reaction-, rates. The highest reaction rates at the lowest temperature occur when the eutectic penetrates an AI2O3/S1 layer. Bimodal pellets with and without eutectic (or with and without mullite seeds) directly illustrate their roles. Mullite seeds promote mullite formation, but the transient liquid accelerates Si oxidation, mullite formation and densification. / Thesis / Master of Engineering (ME)

Solid Oxide Fuel Cells (SOFCs) are considered suitable for alternative energy solutions due to advantages such as high efficiency, fuel flexibility, tolerance to impurities, and potential for combined cycle operations. One of the main operating constraints of SOFCs is fuel starvation, which can occur under fluctuating power demands. It leads to voltage loss and detrimental effects on cell integrity and longevity. In addition, reformer based SOFCs require sufficient steam for fuel reforming to avoid carbon deposition and catalyst degradation. Steam to carbon ratio (STCR) is an index indicating availability of the steam in the reformer. This work takes a holistic approach to address the aforementioned concerns in SOFCs, in an attempt to enhance applicability and adaptability of such systems. To this end, we revisit prior investigation on the invariant properties of SOFC systems, that led to prediction of fuel utilization U and STCR in the absence of intrusive and expensive sensing. This work provides further insight into the reasons behind certain SOFC variables being invariant with respect to operating conditions. The work extends the idea of invariant properties to different fuel and reformer types. In SOFCs, transient control is essential for U, especially if the fuel cell is to be operated in a dynamic load-following mode at high fuel utilization. In this research, we formulate a generalized abstraction of this transient control problem. We show that a multi-variable systems approach can be adopted to address this issue in both time and frequency domains, which leads to input shaping. Simulations show the effectiveness of the approach through good disturbance rejection. The work further integrates the aforementioned transient control research with system level control design for SOFC systems hybridized with storage elements. As opposed to earlier works where centralized robust controllers were of interest, here, separate controllers for the fuel cell and storage have been the primary emphasis. Thus, the proposed approach acts as a bridge between existing centralized controls for single fuel cells to decentralized control for power networks consisting of multiple elements. As a first attempt, decentralized control is demonstrated in a SOFC ultra-capacitor hybrid system. The challenge of this approach lies in the absence of direct and explicit communication between individual controllers. The controllers are designed based on a simple, yet effective principle of conservation of energy. Simulations as well as experimental results are presented to demonstrate the validity of these designs.

After undergoing an extensive study about engine air mass flow measurement approaches as well as engine modelling for air mass flow prediction, a major problem found to exist is that engineers have still not found a suitable technique to accurately measure the air mass flow entering the cylinder of an internal combustion engine. The engine air mass flow is the most important parameter needed during engine development so the fuel control can be accurately calibrated and as a result increase performance and reduce emission output of an engine. The current methods used to determine the air mass flow lead to inaccuracies due to the large amount of mathematical assumptions and also sensor errors and as a result the mapping and calibration process of a new engine family takes approximately 2 years due to extensive modelling and testing required overcoming the above drawbacks. To improve this, the distributed lumped modelling technique (D-L) of the inlet manifold was chosen, where the intake system is separated into very small sections which are distributed continuously throughout the volume of the intake until entering the cylinder. This technique is validated against a CFD model of the engine’s intake system and real engine data as well as a 1D engine model.

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