Since the first discovery of a transiting planet in 2000, transmission spectroscopy has proved essential for characterising the rapidly increasing number of known extrasolar planets. When a planet is in a favourable alignment, it periodically passes (transits) in front of its host star, during which time it blocks a fraction of the stellar light. During a transit, the starlight passes through the planetary atmosphere, causing the signatures of atoms or molecules present in that atmosphere to imprint themselves on the stellar spectrum, allowing direct observation of a planet's atmospheric composition. At the start of this thesis, only two planets (HD 189733b and HD 209458b) had been studied in any detail, mainly from space. The two planets showed surprisingly different qualities for two objects with only a small temperature difference between them, and motivated both wider and more detailed studies of the exoplanet population. Since the start of my PhD, the amount of exoplanet knowledge has grown rapidly, with observations from the ground becoming important, and with studies branching out towards new planets. There are several contributions made by this thesis to the field. Chapter 3 details the detection of the resolved sodium D doublet in the atmosphere of HD 189733b, a planet with a featureless broad-band transmission spectrum dominated by Rayleigh scattering. The results confirmed the presence of sodium absorption as well as resolving the feature for the first time, and placing constraints on relative abundances. Furthermore, in Chapter 4, I outline a method based on earlier work which allows observers to retrieve atmospheric temperature information from resolved spectral features. This method is applied to the observations of HD 189733b, showing that the planet has a hot thermosphere similar to HD 209458b. The models are then also used in later chapters. I then present the first results from a ground-based optical long-slit spectroscopic survey in Chapter 5, and the first results from a space-based optical-near-IR spectroscopic survey in Chapter 6. From the ground, I detect absorption from sodium in the atmosphere of XO-2b, making this the first planet with sodium and potassium detected in its atmosphere. I also find that the Na I D feature lacks broad line wings, suggesting haze or cloud cover. From space, I observed the transmission spectrum of WASP-19b, finding solar abundance water features and a likely lack of predicted TiO features. WASP-19b is the first planet to have confirmed water features at solar-abundance level. In Chapter 7 I conclude and discuss future work, including a project aimed at understanding why WASP-19b lacks TiO features, and projects which move beyond the hot Jupiter class.

Recent spectroscopic observations of transiting exoplanets have permitted the derivation of the thermal structure and molecular abundances of H₂O, CO, CO₂, CH₄, metallic oxides and alkali metals in these extreme atmospheres. Here, for the first time, a fully-fledged retrieval algorithm has been applied to exoplanet spectra to determine the thermal structure and composition. The development of a suite of radiative transfer and retrieval tools for exoplanet atmospheres is described, building upon an optimal estimation retrieval algorithm extensively used in solar system studies. Firstly, the collection of molecular line lists and the pre-tabulation of the absorption coefficients (k-distribution tables) for high temperature application are discussed. Secondly, the best-fit spectra for hot Jupiters are demonstrated and discussed case by case. Available sets of primary and secondary transit observations of exoplanets are used to retrieve atmospheric properties from these spectra, quantifying the limits of our knowledge of exoplanetary atmospheres based on the current quality of the data. The contribution functions and the vertical sensitivity to the molecules are fully utilised to interpret these spectra, probing the structure and composition of the atmosphere. Finally, the retrievals provide our best estimates of the thermal and compositional structure to date, using the covariance matrices to properly assess the degeneracy between different parameters and the uncertainties on derived quantities for the first time. This sheds light on the range of diverse interpretations offered by other authors so far, and allows us to scrutinise further atmospheric features by maximising the capability of the current retrieval algorithm and to demonstrate the need for broadband spectroscopy from future missions.

Les Jupiters chauds sont des exoplanètes si proches de leur étoile que leur atmosphère peut perdre du gaz par échappement hydrodynamique. Les géantes gazeuses qui transitent sont un excellent moyen de comprendre ce processus, mais il faut étudier d'autres types de planètes pour déterminer son impact sur la population exoplanétaire. Cette thèse propose d'utiliser la spectroscopie du transit pour observer l'atmosphère de plusieurs planètes, étudier leurs propriétés et caractériser l'échappement hydrodynamique. Des raies de l'ultraviolet observées avec le télescope Hubble sont analysées avec le modèle numérique de la haute atmosphère que nous avons développé. Grâce à la raie Ly-? nous mettons en évidence les interactions énergétiques et dynamiques entre l'atmosphère des Jupiters chauds HD209458b et HD189733b et leurs étoiles. Nous étudions la dépendance de l'échappement à l'environnement d'une planète et à ses propriétés physiques, en observant une super-Terre et un Jupiter tiède dans le système 55Cnc. Grâce à des observations de HD209458b nous montrons que les raies du magnésium permettent de sonder la région de formation de l'échappement. Nous étudions le potentiel de la spectroscopie du transit dans le proche UV pour détecter de nouveaux cas d'échappement. Ce mécanisme est favorisé par la proximité d'une planète à son étoile, ce qui rend d'autant plus important la compréhension des processus de formation et de migration, qui peuvent être étudiés par l'alignement d'un système planétaire. Grâce à des mesures des spectrographes HARPS-N et SOPHIE nous étudions les alignements de 55Cnc e et du candidat Kepler KOI-12.01, dont nous cherchons aussi à valider la nature planétaire. / Hot Jupiters are exoplanets so close to their star that their atmosphere can lose gas because of hydrodynamic escape. Transiting gaseous giants are an excellent way to understand this mechanism, but it is necessary to study other types of planets to determine its impact on the exoplanetary population. This thesis aims at using transit spectroscopy to observe the atmosphere of several exoplanets, to study their properties and to contribute to the characterization of hydrodynamic escape. UV lines observed with the Hubble telescope are analyzed with the numerical model of upper atmospheres we developed. Using the Ly-? line we identify energetic and dynamical interactions between the atmospheres of the hot Jupiters HD209458b and HD189733b and their stars. We study the dependence of the escape on the environment of a planet and on its physical properties, through the observation of a super-Earth and a warm Jupiter in the 55 Cnc system. Using observations of HD209458b, we show that magnesium lines are a window on the region of formation of hydrodynamic escape. We study the potential of transit spectroscopy in the near-UV to detect new cases of atmospheric escape. This mechanism is fostered by the proximity of a planet to its star, which makes it even more important to understand the formation and migration processes that can be traced in the alignment of a planetary system. Using measures from the spectrographs HARPS-N and SOPHIE we study the alignments of 55 Cnc e and the Kepler candidate KOI 12.01, whose planetary nature we also seek to validate.

La spectroscopie de transit est un outil puissant pour la caractérisation de l'atmosphère d'exoplanètes. Plusieurs phénomènes peuvent contaminer un spectre de transmission, dont l'hétérogénéité de la surface de l'étoile hôte due à l'activité stellaire. À basse résolution spectrale, la différence entre le cordon de transit et le reste de la surface y laisse des signatures qui pourraient être attribuées à tort à la planète. Les risques associés incluent des biais sur la mesure du rayon et des abondances atmosphériques de planètes. Afin de trouver une solution à ce problème, cette étude consiste à modéliser en détail des surfaces stellaires et des spectres de transit à basse et à très haute résolution. On cherche d'une part à qualifier l'ampleur du problème à basse résolution et, d'autre part, à déterminer si la haute résolution permet d'isoler la contamination stellaire et ainsi résoudre le problème. La modélisation se concentre sur trois types d'étoiles, entre K hâtive et M tardive. Les modèles confirment l'importance du problème et l'absence de solution évidente à basse résolution, principalement pour les étoiles M. À haute résolution, on parvient à séparer les signaux de la planète et de l'activité stellaire. Cela permet de briser l'ambiguïté à basse résolution, pourvu que la planète ait une variation de vitesse radiale suffisante durant le transit. Ces résultats soulignent la valeur d'un suivi à haute résolution lorsque possible. Même avec le télescope James-Webb, il sera difficile d'avoir totalement confiance en les résultats de caractérisation d'atmosphères utilisant des données à basse résolution. / Transit spectroscopy is a powerful tool for the characterisation of exoplanet atmospheres. There exist multiple sources of contamination for transmission spectra, including stellar activity induced surface heterogeneities on the host star. At low spectral resolution, differences between the transit chord and the rest of the surface leave signatures in the spectra, which could then be wrongly associated with the planet. This can introduce biases in radius and atmospheric abundance measurements of exoplanets. To solve this issue, this study consists in carefully modeling stellar surfaces and transit spectra at low and very high spectral resolution. We seek to, on one hand, understand the importance of the problem at low resolution, and, on the other hand, determine if high resolution allows us to isolate stellar contamination and thus solve this problem. Modeling is focused on three types of stars, from early K to late M. Models confirm the importance of the issue and the absence of an obvious solution at low resolution, especially for M stars. At high resolution, we manage to effectively split the planet and stellar activity signals. This allows us to break the ambiguity from low resolution, provided the planet experiences a sufficient radial velocity variation during transit. These results highlight the strong value of high resolution follow-ups when feasible. Even with the James-Webb space telescope, it will be difficult to fully trust the results of atmospheric abundance retrievals using low resolution data.

Le système TRAPPIST-1 offre une opportunité sans précédent de caractériser les premières planètes potentiellement habitables en dehors de notre système solaire. Dans ce mémoire est décrit le développement d’un pipeline de réduction de données personnalisé pour le mode WIRC+Spec de la caméra infrarouge à grand champ récemment mise à niveau à l’observatoire Palomar. Nous introduisons une nouvelle approche d’ajustement de la fonction d’étalement du point basée sur la transformation de Karhunen-Loève pour extraire des courbes de lumière photométrique et spectroscopique de sources de forme irrégulière, que nous appliquons aux observations de l’exoplanète TRAPPIST-1d pour mesurer ses spectres de transmission dans les bandes J (1.1 à 1.4 µm) et Ks (1.95 à 2.35 µm). Un guide détaillé est présenté pour l’implémentation d’un calcul de profils de température incluant l’équilibre radiatif et convectif pour une modélisation atmosphérique efficace et précise. En comparant une multitude de scénarios atmosphériques aux observations de TRAPPIST-1d, nous obtenons des contraintes sur la composition et la structure de son atmosphère, excluant les scénarios sans nuages avec des métallicités inférieures à 300 fois la valeur solaire à 3σ. / The TRAPPIST-1 system provides an unprecedented opportunity to characterize the first potentially habitable planets outside our solar system. In this work we describe the development of a custom data reduction pipeline for the WIRC+Spec mode of the recently upgraded Wide Field Infrared Camera instrument on Palomar Observatory. We introduce a novel, Karhunen-Loève transform based approach to extract photometric and spectroscopic light curves from irregularly shaped sources, which we apply to observations of the TRAPPIST-1d exoplanet to measure the J band (1.1 to 1.4 µm) and Ks band (1.95 to 2.35 µm) transmission spectra. We also present a detailed guide into the implementation of a self-consistent, radiative-convective temperature structure calculation for efficient and accurate atmospheric modelling. Comparing a host of atmospheric scenarios to the observations of TRAPPIST-1d to date, we constrain its atmosphere, ruling out cloud-free atmospheres with metallicities lower than 300 times the solar value at 3σ confidence.