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Solvation, reactivity and spectroscopy of complexes of some first row transition metalsRadulović, Stojan January 1988 (has links)
The work in this thesis is mainly concerned with the discussion of effect of solvation on the reaction kinetics of inorganic complexes. Rate constants for chemical reactions in various aqueous cosolvent systems have been measured and analysed. Crystal structure of several Fe (II) complexes are analysed from crystallographic data for possible structural parameters which might have effect on solvation. Solubility data, for a range of inorganic salts containing simple and complex ions, are reported for aqueous solutions and for solutions in aqueous cosolvent mixtures. Transfer chemical potentials for single ions in aqueous i-PrOH and t-BuOH solvent mixtures are determined using solubility data for salts in conjunction with TATB, tetraphenylarsonium tetraphenylboranate, assumption and are compared with those in corresponding aqueous methanol, ethanol and acetone solvent mixtures. Kinetic data are reported for reaction between [Fe (gmi)3]²+ and hydroxide ions at atmospheric and elevated pressures in above binary aqueous mixtures. Initial state and transition state analysis of reactivity trends for hydroxide attack on other Fe (II) diimine complexes in aqueous methanol solvent mixtures are reported. Dependence of visible absorption spectra on solvent has been examined for a number of Fe (II) and Fe (III) mixed ligand complexes. Preliminary redox study of the of Fe (II) and Fe (III) complexes is also reported.
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Ligand effects on the metal ion catalyzed decarboxylation of dimethyloxaloacetic acidClaus, Kenneth Granger, 1941- January 1969 (has links)
No description available.
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The crystal structures of ransomite, CuFe₂(SO₄)₄·6H₂O, and roemerite, Fe"Fe"'₂(SO₄)₄·14H₂O, and a proposed classification for the transition metal sulfate hydratesWood, Michael Manning, 1937- January 1969 (has links)
No description available.
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STRUCTURE AND PROPERTIES OF CERTAIN PLANAR METAL CHELATES AND THEIR ADDUCTSCarter, Dean Edwin, 1942- January 1969 (has links)
No description available.
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KINETIC AND THERMODYNAMIC STUDIES ON CERTAIN TRANSITION-METAL CHELATES OFSUBSTITUTED 8-QUINOLINOLSBeimer, Robert Glenn, 1943- January 1969 (has links)
No description available.
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INFRARED SPECTRA OF TRANSITION-METAL NITROSYLSQuinby-Hunt, Mary S. January 1972 (has links)
No description available.
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Physical studies on some sulfur-containing transition metal complexes.Sawai, Tsutomu. January 1972 (has links)
No description available.
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Synthetic and spectroscopic studies on some transition metal thiocarbonyl and selenocarbonyl complexesCozak, Daniel January 1976 (has links)
No description available.
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A study of transition metal cubanetype complexes : metal ions in mixed oxidation statesHightower, Thomas Crawford 08 1900 (has links)
No description available.
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Polynuclear Schiff base complexes of some first row transition metal ionsBreece, James Lowell 12 1900 (has links)
No description available.
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