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by Tung Suet Lam. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2002. / Includes bibliographical references. / Abstracts in English and Chinese. / Table of Contents --- p.i / Acknowledgments --- p.iv / Abstract --- p.v / Abstract (Chinese version) --- p.vii / Abbreviations --- p.ix / List of Compounds --- p.xi / Chapter Chapter1. --- synthesis and structures of iron(ii) and cobalt(ii) complexes derived from pyridine-functionalized amido ligands / Chapter 1.1 --- INTRODUCTION --- p.1 / Chapter 1.1.1 --- General Background --- p.1 / Chapter 1.1.2 --- A Brief Review on Amides of the Late Transition Metals --- p.3 / Chapter 1.2 --- OBJECTIVES OF THIS WORK --- p.5 / Chapter 1.3 --- RESULTS AND DISCUSSION --- p.7 / Chapter 1.3.1 --- Alkali Metal Derivatives of N-Silylated 2-Aminopyridines --- p.7 / Chapter 1.3.1.a. --- "Synthesis of Aminopyridines [HN(SiMe3)》(2-C5H3N-6-R)] (R=H (1a), Me (1b)) and Their Lithium Derivatives" --- p.7 / Chapter 1.3.1.b. --- Synthesis of the Potassium Derivative [{K(L1)(tmeda)}2 ] (4) --- p.8 / Chapter 1.3.1.c. --- "Physical Characterization of Compounds 2a, 3 and" --- p.4 9 / Chapter 1.3.1.d. --- Molecular Structures of Compounds 3 and4 --- p.10 / Chapter 1.3.2 --- "Synthesis, Structures and Reactivities of Iron(II) and Cobalt(II) Amides" --- p.16 / Chapter 1.3.2.a. --- Synthesis of Mononuclear Iron(II) and Cobalt(II) Diamides --- p.16 / Chapter 1.3.2.b. --- Physical Characterization of Compounds 5-8 --- p.16 / Chapter 1.3.2.C. --- Molecular Structures of Compounds 5-8 --- p.17 / Chapter 1.4 --- EXPERIMENTAL FOR CHAPTER1 --- p.28 / Chapter 1.5 --- REFERENCES FOR CHAPTER1 --- p.31 / Chapter Chapter2. --- reaction of iron(II) and cobalt(II) amides with phenolic compounds / Chapter 2.1 --- "SYTHESIS, STRUCTURES AND REACTIVITIES OF IRON(II) AND COBALT(II) BIS(ARYLOXIDE)" --- p.36 / Chapter 2.1.a. --- "Reaction of Compounds 7 and 8 with 2,2 -ethylidenebis(4,6-di-tert-butyl phenol)" --- p.36 / Chapter 2.1.b. --- "Molecular Structures, Magnetic Moments, and Reactivities of Compounds 9and10" --- p.36 / Chapter 2.2 --- A GENERAL REVIEW ON CATECHOL DIOXYGENASES --- p.44 / Chapter 2.3 --- "SYTHESIS, STRUCTURES AND REACTIVITIES OF IRON(II) AND COBALT(II) CATECHOLATES" --- p.46 / Chapter 2.3.a. --- Synthesis of Binuclear Iron(II) and Cobalt(II) Catecholates --- p.46 / Chapter 2.3.b. --- Molecular Structures of Compounds 11 and12 --- p.48 / Chapter 2.3.c. --- Reactions of Compounds 11 and 12 with Dioxygen --- p.54 / Chapter 2.3.d. --- Identification of Oxidative Cleavage Products --- p.54 / Chapter 2.4 --- EXPERIMENTAL FOR CHAPTER2 --- p.56 / Chapter 2.5 --- REFERENCES FOR CHAPTER2 --- p.59 / Chapter Chapter3. --- synthesis of late transition metal amidinates / Chapter 3.1 --- INTRODUCTION --- p.62 / Chapter 3.1.1 --- General background --- p.62 / Chapter 3.1.1.a --- Metal´ؤAmidine Bonding Modes --- p.63 / Chapter 3.1.1.b. --- Preparation of Metal Amidinates Complexes --- p.64 / Chapter 3.1.2 --- "N-Silylated Benzamidinates of Li, Na and K 一 The Starting Materials" --- p.65 / Chapter 3.1.3 --- A General Review on The Chemistry of Low-Valent Late Transition- Metal Amidinates --- p.67 / Chapter 3.2 --- OBJECTIVES OF THIS WORK --- p.72 / Chapter 3.3 --- RESULTS AND DISCUSSION --- p.73 / Chapter 3.3.1 --- Synthesis and Structures of Lithium Benzamidinates --- p.73 / Chapter 3.3.1.a. --- "Synthesis of [Li(L3)(tmeda)] (L3 = [PhC(NSiMe3){N(2,6´ؤ Me2C6H3}]) and [Li(L4)(tmeda)] (L4 = [PyC(NSiMe3){N(2,6- Me2C6H3)}]) as Ligand´ؤTransfer Reagents" --- p.73 / Chapter 3.3.1.b. --- Physical Characterization of Compounds 15 and16 --- p.74 / Chapter 3.3.1.c. --- Molecular Structures of Compounds 15 and16 --- p.75 / Chapter 3.3.2 --- "Synthesis, Structures and Reactivities of Iron(II) and Cobalt(II) Amidinates" --- p.81 / Chapter 3.3.2.a. --- Synthesis of Mononuclear Iron(II) Benzamidinates --- p.81 / Chapter 3.3.2.b. --- Synthesis of a Binuclear Cobalt(II) Benzamidinate --- p.82 / Chapter 3.3.2.c. --- Physical Characterization of Compounds 17-19 --- p.83 / Chapter 3.3.2.d. --- Molecular Structures of Compounds 17-19 --- p.84 / Chapter 3.3.2.e. --- Reaction of Compound 18 with Dioxygen --- p.94 / Chapter 3.3.2.f. --- Molecular Structure of Compound20 --- p.95 / Chapter 3.3.3 --- Synthesis and Structures of Nickel(II) and Copper(I) Benzamidinates --- p.98 / Chapter 3.3.3.a --- Synthesis of a Nickel(II) Benzamidinate --- p.98 / Chapter 3.3.3.b. --- Synthesis of a Binuclear Copper(I) Benzamidinate --- p.99 / Chapter 3.3.3.c. --- Physical Characterization of Compounds 21 and22 --- p.101 / Chapter 3.3.3.d. --- Molecular Structures of Compounds 21 and22 --- p.102 / Chapter 3.3.4 --- Synthesis and Structures of Mononuclear Zinc(II) and Cadmium(II) Amidinates --- p.107 / Chapter 3.3.4.a --- Synthesis of Mononuclear Zinc(II) and Cadmium(II) Benzamidinates --- p.107 / Chapter 3.3.4.b. --- Physical Characterization of Compounds 23 and24 --- p.107 / Chapter 3.3.4.C. --- Molecular Structures of Compounds 23 and24 --- p.108 / Chapter 3.4 --- EXPERIMENTAL FOR CHAPTER3 --- p.113 / Chapter 3.5 --- REFERENCES FOR CHAPTER3 --- p.119 / appendix1 --- p.127 / appendix2 --- p.129

Lam, Pui Chi. / Thesis submitted in: November 2006. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2007. / Includes bibliographical references. / Abstracts in English and Chinese. / Table of Contents --- p.i / Acknowledgements --- p.v / Abstract --- p.vi / 摘要 --- p.viii / List of Compounds --- p.x / Abbreviations --- p.xiii / Chapter CHAPTER 1. --- A GENERAL INTRODUCTION TO METAL AMIDES / Chapter 1.1 --- GENERAL BACKGROUND --- p.1 / Chapter 1.2 --- OBJECTIVES OF THIS WORK --- p.7 / Chapter 1.3 --- REFERENCES FOR CHAPTER1 --- p.8 / Chapter CHAPTER 2. --- SYNTHESIS AND STRUCTURES OF GROUP 4 METAL AMIDES / Chapter 2.1 --- INTRODUCTION --- p.15 / Chapter 2.1.1 --- General Background --- p.15 / Chapter 2.1.2 --- Common Preparation Methods for Group 4 Metal Amides --- p.15 / Chapter 2.1.3 --- "An Overview on Titanium(IV), Zirconium(IV) and Hafnium(IV) Amides" --- p.17 / Chapter 2.2 --- AIMS OF OUR STUDIES --- p.26 / Chapter 2.3 --- RESULTS AND DISCUSSION --- p.27 / Chapter 2.3.1 --- Synthesis of the Ligand Precursor (HL1) and the Corresponding Lithium Derivative [Li(L1tmeda)] --- p.27 / Chapter 2.3.2 --- Synthesis and Structures of Monomeric and Dimeric Titanium(IV) Amides --- p.28 / Chapter 2.3.2.1 --- Synthesis of [Ti(L1 )Cl2(μ-Cl)2] (V and [TiL1)Ch3(THF)] (4) --- p.28 / Chapter 2.3.2.2 --- Reactivity Studies --- p.31 / Chapter 2.3.2.3 --- Physical Characterization of Compounds 3 and 4 --- p.33 / Chapter 2.3.2.4 --- Molecular Structures of Compounds 3 and 4 --- p.36 / Chapter 2.3.3 --- Synthesis and Structures of Mononuclear Zirconium(IV) and Hafnium(IV) Amides --- p.44 / Chapter 2.3.3.1 --- Synthesis of[M(L1)3Cl] (M = Zr 5 and Hf6) --- p.44 / Chapter 2.3.3.2 --- Reactivity Studies --- p.45 / Chapter 2.3.3.3 --- Synthesis of[MCL1)3H] (M = Zr7 and Hf8) --- p.48 / Chapter 2.3.3.4 --- Reactivity Studies of Compound7 --- p.49 / Chapter 2.3.3.5 --- Physical Characterization of Compound 8 --- p.51 / Chapter 2.3.3.6 --- Molecular Structures of Compound 8 --- p.53 / Chapter 2.3.3.7 --- Synthesis of [Zr(L1)3Me] (9) --- p.57 / Chapter 2.3.3.8 --- Reactivity Studies of Compound 9 --- p.58 / Chapter 2.3.3.9 --- Physical Characterization of Compound 9 --- p.59 / Chapter 2.3.3.10 --- Molecular Structure of Compound 9 --- p.60 / Chapter 2.4 --- EXPERIMENTALS FOR CHAPTER 2 --- p.64 / Chapter 2.4.1 --- General Procedures --- p.64 / Chapter 2.4.2 --- Synthesis of Compounds --- p.65 / REFERENCES FOR CHAPTER 2 --- p.68 / Chapter CHAPTER 3. --- SYNTHESIS AND STRUCTURES OF VANADIUM(III) AMIDO AND BENZAMIDINATO COMPLEXES / Chapter 3.1 --- INTRODUCTION --- p.74 / Chapter 3.1.1 --- General Background --- p.74 / Chapter 3.1.2 --- A Brief Introduction on Metal Amidinates --- p.75 / Chapter 3.1.3 --- An Overview on Vanadium(III) Amides --- p.77 / Chapter 3.1.4 --- An Overview on Vanadium(III) Amidinates --- p.82 / Chapter 3.2 --- AIMS OF OUR STUDIES --- p.85 / Chapter 3.3 --- RESULTS AND DISCUSSION --- p.86 / Chapter 3.3.1 --- Synthesis and Structures of Dinuclear Vanadium(III) Amides --- p.86 / Chapter 3.3.1.1 --- Synthesis of[V(L1)2(μ~Cl)]2(10) --- p.86 / Chapter 3.3.1.2 --- Reactivity Studies --- p.88 / Chapter 3.3.1.3 --- Synthesis of [V(L1)2(μ-H)]2 (11) --- p.90 / Chapter 3.3.1.4 --- Physical Characterization of Compounds 10 and 11 --- p.90 / Chapter 3.3.1.5 --- Molecular Structures of Compounds 10 and 11 --- p.94 / Chapter 3.3.2 --- Synthesis and Structure of Mononuclear Vanadium(III) Benzamidinate --- p.102 / Chapter 3.3.2.1 --- "Synthesis of [Li(L2)(tmeda)] (13) (L2 = [PhC(NSiMe3) (NC6H3Me2-2, 6)])" --- p.102 / Chapter 3.3.2.2 --- Synthesis of [V(L2)2Cl] (14) and trans´ؤ[V(tmeda)2Cl2] (15) --- p.103 / Chapter 3.3.2.3 --- Reactivity Studies --- p.104 / Chapter 3.3.2.4 --- Physical Characterization of Compound 14 --- p.107 / Chapter 3.3.2.5 --- Molecular Structure of Compound 14 --- p.107 / Chapter 3.4 --- EXPERIMENTALS FOR CHAPTER 3 --- p.111 / Chapter 3.4.1 --- General Procedures --- p.111 / Chapter 3.4.2 --- Synthesis of Compounds --- p.112 / Chapter 3.5 --- REFERENCES FOR CHAPTER 3 --- p.115 / Chapter CHAPTER 4. --- SYNTHESIS AND STRUCTURES OF CHROMIUM AMIDO AND BENZAMIDINATO COMPLEXES / Chapter 4.1 --- INTRODUCTION --- p.122 / Chapter 4.1.1 --- General Background --- p.122 / Chapter 4.1.2 --- An Overview on Chromium(III) Amides --- p.122 / Chapter 4.1.3 --- An Overview on Chromium(II) Amidinates --- p.125 / Chapter 4.2 --- AIMS OF OUR STUDIES --- p.129 / Chapter 4.3 --- RESULTS AND DISCUSSION --- p.130 / Chapter 4.3.1 --- Synthesis and Structures of A Monomeric Chromium(III) Amide and A Chromium(II) Benzamidinate --- p.130 / Chapter 4.3.1.1 --- Synthesis of[Cr(L1)3] (16) --- p.130 / Chapter 4.3.1.2 --- Synthesis of [Cr(L2)2] (17) --- p.132 / Chapter 4.3.1.3 --- Physical Characterization of Compounds 16 and 17 --- p.133 / Chapter 4.3.1.4 --- Molecular Structures of Compounds 16 and 17 --- p.135 / Chapter 4.4 --- EXPERIMENT ALS FOR CHAPTER 4 --- p.141 / Chapter 4.4.1 --- General Procedures --- p.141 / Chapter 4.4.2 --- Synthesis of Compounds --- p.141 / Chapter 4.5 --- REFERENCES FOR CHAPTER 34 --- p.144 / APPENDIX 1 / Physical Measurements and X-Ray Crystallography --- p.147 / APPENDIX 2 / "Mass Spectra, 1'H and 13C{]H} NMR Spectra, and IR Spectra" --- p.148 / APPENDIX 3 --- p.172 / Table A-1. Selected crystallographic data for compounds 3-4 --- p.173 / Table A-2. Selected crystallographic data for compounds 8-9 --- p.174 / Table A-3. Selected crystallographic data for compounds 10-11 --- p.175 / Table A-4. Selected crystallographic data for compounds 14，16-17 --- p.176

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Wong, Fai George. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2008. / Includes bibliographical references. / Abstracts in English and Chinese. / Abstract --- p.iii / 摘要 --- p.v / Acknowledgment --- p.vii / Table of Contents --- p.ix / Abbreviations --- p.xiii / Selected List of Tables --- p.xv / List of Compounds --- p.xvi / Chapter Chapter 1 --- Introduction on Metal Amides / Chapter 1.1 --- General Background --- p.1 / Chapter 1.2 --- A General Classification of A/-anionic Ligands --- p.1 / Chapter 1.3 --- Development of Late Transition Metal Amides --- p.3 / Chapter 1.3.1 --- The First Reported Metal Amides from Each Major Block of the eriodic Table --- p.4 / Chapter 1.3.2 --- Metal Amides Supported by the Simple [N(SiMe3)2]- Ligand --- p.4 / Chapter 1.3.3 --- From Simple to Bulkier Silylamido Ligands --- p.6 / Chapter 1.3.4 --- Metal Complexes Supported by Borylamido Ligands --- p.7 / Chapter 1.3.5 --- Metal Complexes Supported by Arylamido Ligands --- p.9 / Chapter 1.3.6 --- Metal Complexes Supported by erfluorinated Arylamido Ligands --- p.10 / Chapter 1.4 --- Objectives of This Work --- p.11 / Chapter 1.5 --- References for Chapter 1 --- p.13 / Chapter Chapter 2 --- Ligand Substitution Reactions of Divalent Late Transition Metal Amides / Chapter 2.1 --- General Background --- p.17 / Chapter 2.2 --- Objectives of This Work --- p.19 / Chapter 2.3 --- Results and Discussion --- p.20 / Chapter 2.3.1 --- Previous Work in Our Group --- p.20 / Chapter 2.3.2 --- Synthesis of Metal Complexes --- p.20 / Chapter 2.3.3 --- Molecular Structure of the Fe(ll) Complex 11 --- p.22 / Chapter 2.3.4 --- Preparation of Mixed Amide-Alkyl Complexes --- p.24 / Chapter 2.3.5 --- Molecular Structures of the Methyl Complexes 12-15 --- p.29 / Chapter 2.3.6 --- Attempts to repare Mixed Amide-Alkoxide Complexes --- p.39 / Chapter 2.3.7 --- Reactivity of the [Co(L2)Me(tmeda)] Complex (17) --- p.39 / Chapter 2.3.8 --- Molecular Structure of the Co(ll) Iodide Complex 18 --- p.43 / Chapter 2.4 --- Summary --- p.45 / Chapter 2.5 --- Experimental Section for Chapter 2 --- p.48 / Chapter 2.6 --- References for Chapter 2 --- p.51 / Chapter Chapter 3 --- Reduction Chemistry of Divalent Late Transition Metal Amides / Chapter 3.1 --- General Background --- p.54 / Chapter 3.2 --- Objectives of This Work --- p.57 / Chapter 3.3 --- Results and Discussion --- p.57 / Chapter 3.3.1 --- Reduction of the Complexes Mn(ll) and Co(ll) Complexes 7 and 9 --- p.57 / Chapter 3.3.2 --- Attempted Synthesis of the Mononuclear Co(l) Complex --- p.59 / Chapter 3.3.3 --- Molecular Structures of the Complexes 19 and 20 --- p.61 / Chapter 3.3.4 --- Reactivity of the Univalent Co(l) Complex [Co(L2)]2 (20) --- p.65 / Chapter 3.4 --- Summary --- p.67 / Chapter 3.5 --- Experimental Section for Chapter 3 --- p.68 / Chapter 3.6 --- References for Chapter 3 --- p.69 / Chapter Chapter 4 --- A reliminary Study on the Coordination Chemistry of erfluorinated Late Transition Metal Amides / Chapter 4.1 --- General Background --- p.71 / Chapter 4.2 --- Objectives of This Work --- p.73 / Chapter 4.3 --- Results and Discussion --- p.73 / Chapter 4.3.1 --- Synthesis of the Ligand recursor[HN(SiMe3)(C6F5)] (21) --- p.73 / Chapter 4.3.2 --- Synthesis of the Lithium Reagent [Li(L3)tmeda]] (22) --- p.74 / Chapter 4.3.3 --- Synthesis of the Fe(ll) and Co(ll) Complexes of the L3 Ligand --- p.75 / Chapter 4.3.4 --- Molecular Structures of the Chloride Complexes 23 and 24 --- p.77 / Chapter 4.4 --- Summary --- p.82 / Chapter 4.5 --- Experimental Section for Chapter 4 --- p.83 / Chapter 4.6 --- References for Chapter 4 --- p.85 / "Appendix 1 General rocedures, hysical Measurements, and X-Ray Structure Analysis" --- p.87 / Appendix 2 Selected Crystallographic Data --- p.89 / Appendix 3 NMR Spectra of Compounds --- p.94

[Typescript] / Includes bibliographical references. / 1 v. ; 30 cm. / Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / Thesis (Ph.D.)--University of Adelaide, Dept. of Physical and Inorganic Chemistry, 1966

Thesis (Ph. D.)--University of Washington, 2003. / Vita. Includes bibliographical references (leaves 159-164).

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