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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Photolytisch und thermisch induzierte Transmetallierung von Aminoborylenkomplexen / Photolytically and thermally induced transmetallation of amino borylene complexes

Bertsch, Stefanie January 2014 (has links) (PDF)
Aminoborylenkomplexe der Gruppe 6 [(OC)5M=BN(SiMe3)2] (M = Cr, Mo, W) reagieren mit Übergangsmetallkomplexen unter Transfer der Boryleneinheit bzw. in Transmetallierungsreaktionen und bilden dabei neuartige Borylenkomplexe. In dieser Dissertation wird die Synthese, Charakterisierung und Reaktivität der auf diesem Wege dargestellten Verbindungen - unter anderem Hydridoborylenkomplexe, Bis(borylen)komplexe und borylensubstituierte MOLPs - beschrieben. / Amino borylene complexes of group 6 [(OC)5M=BN(SiMe3)2] (M = Cr, Mo, W) undergo reactions with transition metal complexes to form novel borylene complexes. These reactions can be viewed either as borylene transfer or as transmetallation reactions. In this thesis the syntheses, characterizations and reactivities of these novel compounds – amongst others hydridoborylene complexes, bis(borylene) complexes and borylene substituted MOLPs - is reported.

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