Magnetic properties of Nb/Ni superconducting (SC) / ferromagnetic (FM) multilayers exhibit interesting properties near and below SC transition. A complex Field (H) – Temperature (T) phase boundary is observed in perpendicular and parallel orientation of ML with respect to DC field. We address the critical need to develop methods to make reliable magnetic measurements on SC thin films and ML, in spite of their extreme shape anisotropy and the strong diamagnetic response of the SC state. Abrupt, highly reproducible “switching” of the SC state magnetization near the normal-state FM coercive fields has been observed in Nb/Ni ML. The SC penetration depth l(Nb) > the SC coherence length xo(Nb) » 40 nm >> the FM layer thickness y(Ni) = 5 nm, abrupt magnetic reversals might be driven by strong supercurrent densities (J x M torques) that have the potential to flow into the Ni layers. Alternatively, sharp magnetization anomalies also can result from strong flux pinning by the periodic layered structure of ML, including “lock-in” of quantized flux lines (FL) parallel to the ML plane. Strong confinement of the supercurrents within ML planes might also lead to various phase transitions of the FL lattice (FLL) composed of one-dimensional chains and other unusual structures. Possible mechanisms for the switching anomalies must be evaluated while considering other experimental properties of Nb(x)/Ni(y) ML: 1) The upper critical magnetic field Hc2(T) exhibits a highly unusual anisotropy where the SC transition temperature Tc (H®0) for DC field H ^ ML plane exceeds the value for H || ML by ~ 0.5 K. 2) Nb/Ni ML samples do not consistently exhibit magnetic signatures for the onset of superconductivity, depending on the details of the sample mounting procedure and the AC or DC method used in SQUID magnetometry experiments. 3) Unusual “wiggles” or oscillations of order 10-30 mK were observed in Hc2(T) in AC SQUID experiments with H || ML and can be even larger (~0.16 K), depending upon the AC drive amplitude ho and frequency f .

京都大学 / 0048 / 新制・課程博士 / 博士(理学) / 甲第21555号 / 理博第4462号 / 新制||理||1640(附属図書館) / 京都大学大学院理学研究科物理学・宇宙物理学専攻 / (主査)教授 前野 悦輝, 教授 石田 憲二, 教授 寺嶋 孝仁 / 学位規則第4条第1項該当 / Doctor of Science / Kyoto University / DGAM

京都大学 / 新制・課程博士 / 博士(理学) / 甲第24399号 / 理博第4898号 / 新制||理||1700(附属図書館) / 京都大学大学院理学研究科物理学・宇宙物理学専攻 / (主査)教授 石田 憲二, 教授 松田 祐司, 教授 柳瀬 陽一 / 学位規則第4条第1項該当 / Doctor of Science / Kyoto University / DGAM

This thesis presents theoretical investigations of triplet superfluidity (triplet superconductivity) in quasi-one-dimensional organic conductors and ultra-cold Fermi gases. Triplet superfluidity is different from its s-wave singlet counterpart since the order parameter is a complex vector and the interaction between fermions is in general anisotropic. Because of these distinctions, triplet superfluids have different physical properties in comparison to the s-wave case. The author discusses in this thesis the interplay between triplet superconductivity and spin density waves in quasi-one-dimensional organic conductors, and proposes a coexistence region of the two orders. Within the coexistence region, the interaction between the two order parameters acquires a vector structure, and induces an anomalous magnetic field effect. Furthermore, the author analyzes the matter-wave interference between two p-wave Fermi condensates, and proposes a polarization effect. For a single harmonically trapped p-wave Fermi condensate, the author also shows that the expansion upon release from the trap can be anisotropic, which reflects the anisotropy of the p-wave interaction.

This thesis presents an experimental study of the superconducting proximity effect in sub-micrometer sized ferromagnetic discs. Such discs belong to a class of mesoscopic ferromagnets intermediate between microscopic magnets with dimensions below about 10nm that behave as single giant spins and macroscopic structures that are larger than approximately 1 micrometer where domains are formed to minimise stray fields. The magnetic structure of mesoscopic magnets is strongly dependent on their geometric shape, allowing for purposeful engineering of magnetic structures using modern lithographic techniques. The ground magnetic state of mesoscopic ferromagnetic discs is the magnetic vortex where unusual time-asymmetric triplet superconductivity is predicted to exist and survive up to the non-magnetic coherence length, that is orders in magnitude larger than the ferromagnetic singlet coherence length. Magnetic Force Microscopy (MFM) was used to directly study the magnetic structure of the discs. To detect the proximity effect in the vortices, Andreev interferometers were used with normal parts replaced with mesoscopic ferromagnetic discs in the magnetic vortex state. The samples were fabricated using electron-beam lithography and a modified shadow evaporation technique developed within this project, allowing the whole structure to be made with highly precise alignment, without breaking vacuum and avoiding redundant ferromagnetic elements disturbing the magnetic vortices. Observations were made of superconducting phase periodic oscillations in the conductance of the Andreev interferometers. Such oscillations provide unambiguous evidence of phase coherent electron transport through the ferromagnetic vortex. Finally, further experiments are discussed that would provide a more detailed understanding of the long range proximity effect in SFS junctions.

The work presented in this thesis was broadly focussed on the investigation of the magnetic behaviour of different superconducting materials in the form of bulk (singe crystals and pellets) and thin films (nanomagnetic devices like superconducting spin valves etc). Neutrons and muons were extensively used to probe the structural and magnetic behaviour of these systems at the nanoscale along with bulk characterisation techniques like high-sensitive magnetic property measurements, scanning probe microscopy and magneto-transport measurements etc. The nanoscale interplay of Superconductivity and Ferromagnetism was studied in the thin film structures using a combination of Polarised Neutron Reflectivity (PNR) and Low Energy Muon Spin Rotation (LE-µSR) techniques while bulk Muon Spin Rotation (µSR) technique was used for microscopic magnetic investigation in the bulk materials. In the Fe/Pb heterostructure, evidence of the Proximity Effect was observed in the form of an enhancement of the superconducting penetration depth (λs) with an increase in the ferromagnetic layer thickness (dF) in both the bilayered and the trilayered structures. The existence of an Inverted Magnetic Region was also detected at the Ferromagnet-Superconductor (F/S) interface in the normal state possibly originating from the induced spin polarisation within the Pb layer in the presence of the neighbouring Fe layer(s). The spatial size (height and width) of the Inverted Magnetic Region did not change much while cooling the sample below the superconducting transition temperature(Tc)and it also stayed unaffected by an increase in the Fe layer thickness and by a change of the applied magnetic field. In the superconducting spin valve structure containing Permalloy (Py) as ferromagnetic layer and Nb as the superconducting layer, LE-µSR measurements revealed the evidence of the decay of magnetic flux density (as a function of thickness) within the Nb layer symmetrically from the Py/Nb interfaces towards the centre of the Nb layer in the normal state. The thickness dependent magnetisation decay occurred over two characteristic length scales in the normal state that stayed of similar values in the superconducting state also. In the superconducting state, an additional contribution towards the magnetisation was found in the vicinity of the Py/Nb interfaces possibly originating from the spin polarisation of the singlet Cooper pairs in these areas. The nanoscale magnetic investigation on a highly engineered F/S/F structure (where each of the F blocks made of multiple Co/Pd layers with magnetic moments aligned perpendicular to the plane of these layers and neighbouring magnetic blocks separated by Ru layers giving rise to antiferromagnetic alignment) using LE-µSR showed an antisymmetric thickness dependent magnetic flux density profile with two characteristic length scales. In the superconducting state, the magnetic flux density profile got modified within the superconducting Nb₆₇Ti₃₃ layer near the F/S interfaces in a way similar to that of observed in the case of Py/Nb system, most likely because of the spin polarisation of the superconducting electron pairs. The vortex magnetic phase diagram of Bi₂Sr₂Ca₂Cu₃O10-δ was studied using the Muon Spin Rotation (µSR) technique to explore the effects of vortex lattice melting and rearrangements for vortex transitions and crossover as a function of magnetic field and temperatures. At low magnetic fields, the flux vortices undergo a first order melting transition from a vortex lattice to a vortex liquid state with increasing temperature while another transition also occurred with increasing field at fixed temperature to a vortex glass phase at the lowest temperatures. Evidence of a frozen liquid phase was found in the intermediate field region at low temperature in the form of a lagoon in the superconducting vortex state which is in agreement with earlier observations made in BiSCCO-2212. The magnetic behaviour of the unconventional superconductor Sr₂RuO₄ was investigated using µSR to find the evidence of normal state magnetism and the nature of the vortex state. In the normal state, a weak hysteretic magnetic signal was detected over a wide temperature and field range believed to be supporting the evidence of a chiral order parameter. The nature of the vortex lattice structure was obtained in different parts of the magnetic phase diagram and the evidence of magnetic field driven transition in the lattice structure was detected from a Triangular→Square structure while the vortex lattice stayed Triangular over the entire temperature region below Tc at low fields with a disappearance of pinning at higher temperatures.