Combined cycle power plants haven becoming one of the mainstream power plants in the twenty-one century. The emergence of high 600¢J exhaust temperature of the gas turbine, due to the recent rapid enhancement of aerospace material and blade cooling methods, upgrades the gas turbine from low efficiency dual pressure non-reheat unit to high efficiency triple pressure reheat combined cycle power plants. In addition, the increase of turbine inlet temperature by 10~15¢J every year leads to the renewal of the advanced models gas turbine less than ten years. There are three-turbine inlet temperature (TIT) definitions in the gas turbine: (1) TA defines firing temperature as the mass flow mean total temperature before the first-stage stationary diagram edge plane.( Westinghouse or MHI product) (2) TB defines fire temperature as the mass flow mean total temperature at the first-stage nozzle trailing edge plane, ( GE product). (3) TC defines ISO firing temperature; it is a stoichiometric combustion temperature. It is not a physical temperature. ( Siemens ¡® Alstom ABB product). This study shows how to calculate compressor inlet mass flow balance, turbine power balance and heat balance on the combustion chamber system. In order to prove correctness of the balance equation, the data are taken from the heat balance diagram and acceptance test of Nan-pu power station combined cycle. The result shows that the study is sultable for application of the optimum analysis for CCPP operation performance. This type of combined cycle power plant suits not only for the base-load but also for the cycling-load operation.