Magnesium alloys are excellent material candidate to reduce mass of automotive structures, and as such to meet the Department of Energy's targets in fuel economy and clean energy. However, magnesium alloys show poor ductility at room temperature, which is one of the most important impediments to achieving cost-effective manufacturing of wrought alloys and insuring good energy absorption in crash structures. This Master thesis aims to identify the mechanisms behind the low ductility of magnesium. Therefore, non-destructive EBSD analyses upon tension of both a strong and weak textured magnesium alloy were conducted with a focus on the role of twinning in fracture initiation. This study revealed five mechanisms responsible for early fracture, all of which relate to twinning activity. These mechanisms were involved directly in the shear incompatibility arising from interactions between twin-twin, twin-slip, twin-grain boundary, and double twinning. Backstress played a major role in twin-grain boundary and twin-twin boundary interactions.

Compression tests along the rolling and normal direction of AZ31B plate materials under 10 s strain rate were performed at room temperature to understand the effect of grain size on the formation of deformation twins. When compressed along the rolling direction, tension twins were formed in bands. Within the twin bands, nearly all grains contained tension twins, irrespective of grain size. And outside the bands, no twin was found. Under this deformation condition, grain size has no effect on the formation of tension twins. The reason for this is due to the fact that the formation of a tension twin can trigger the formation of tension twin in the neighboring grain, irrespective of the neighboring grain size. When compressed along the normal direction, no twin band was formed, and compression twins were formed evenly in the specimens. Under this deformation condition, it was found that the larger the grain size, the higher the fraction of grains which contained compression twins. This result indicates that compression twins are easier to be formed in the large grains.

In the Dead Season is a manuscript of poetry that explores, through family narrative, the tensions between ignorance and truth, between honor and mendacity, between violation and veneration, between love and loss, between grief and transcendence. Set in rural Texas, the poems in this collection describe a harsh and unforgiving landscape seen largely, though not exclusively, through the eyes of a central child narrator. Rattlesnakes, tarantulas, drought, flood, birth, death, the poems present everyday occurrences and suggest that we often experience events before we have the context, knowledge, or emotional maturity to make sense of them in any reasonable manner. This discontinuity leaves gaps in understanding that we fill with mythologies of our own making, mythologies that both masquerade as innocence and lead us too early to toxic truths. In a world where death is commonplace, true wonder is found in surprising places.

Multiphase pumping with twin-screw pumps is a relatively new technology that has been proven successful in a variety of field applications. By using these pumps to add energy to the combined gas and liquid wellstream with minimal separation, operators have been able to reduce capital costs while increasing overall production. In many cases, such as subsea operations, multiphase pumping is the only viable option to make remote wells economic. Despite their many advantages, some problems have been encountered when operating under conditions with high gas volume fractions (GVF). Twin-screw multiphase pumps experience a severe decrease in efficiency when operating under wet-gas conditions, GVF over 95%. Field operations have revealed severe vibration and thermal issues which can lead to damage of the pump internals, requiring expensive maintenance. The research presented in this thesis seeks to investigate two novel methods of improving the performance of twin-screw pumps under wet-gas conditions. The first involves increasing the viscosity of the liquid stream. We propose that by increasing the viscosity of the liquid phase, the pump throughput can be increased. Tests were conducted at high GVF using guar gel to increase the viscosity of the liquid phase. Along with results from a multiphase pump model the pump behavior under wet-gas conditions with increased liquid viscosity was evaluated. The experimental results indicate that at high GVF, viscosity is not a dominant parameter for determining pump performance. Possible reasons for this behavior were proposed. These results were not predicted by current pump models. Therefore, several suggestions for improving the model’s predictive performance were suggested. The second method is the direct injection of liquid into the pump casing. By selectively injecting liquid into specific pump chambers, it is believed that many of the vibration issues can be eliminated with the added benefit of additional pressure boosting capacity. Since this method requires extensive mechanical modifications to an existing pump, it was studied only analytically. Calculations were carried out that show that through-casing liquid injection is feasible. More favorable pressure profiles and increased boosting ability were demonstrated.

Multiphase pumping with twin-screw pumps is a relatively new technology that has been proven successful in a variety of field applications. By using these pumps to add energy to the combined gas and liquid wellstream with minimal separation, operators have been able to reduce capital costs while increasing overall production. In many cases, such as subsea operations, multiphase pumping is the only viable option to make remote wells economic. Despite their many advantages, some problems have been encountered when operating under conditions with high gas volume fractions (GVF). Twin-screw multiphase pumps experience a severe decrease in efficiency when operating under wet-gas conditions, GVF over 95%. Field operations have revealed severe vibration and thermal issues which can lead to damage of the pump internals, requiring expensive maintenance. The research presented in this thesis seeks to investigate two novel methods of improving the performance of twin-screw pumps under wet-gas conditions. The first involves increasing the viscosity of the liquid stream. We propose that by increasing the viscosity of the liquid phase, the pump throughput can be increased. Tests were conducted at high GVF using guar gel to increase the viscosity of the liquid phase. Along with results from a multiphase pump model the pump behavior under wet-gas conditions with increased liquid viscosity was evaluated. The experimental results indicate that at high GVF, viscosity is not a dominant parameter for determining pump performance. Possible reasons for this behavior were proposed. These results were not predicted by current pump models. Therefore, several suggestions for improving the model’s predictive performance were suggested. The second method is the direct injection of liquid into the pump casing. By selectively injecting liquid into specific pump chambers, it is believed that many of the vibration issues can be eliminated with the added benefit of additional pressure boosting capacity. Since this method requires extensive mechanical modifications to an existing pump, it was studied only analytically. Calculations were carried out that show that through-casing liquid injection is feasible. More favorable pressure profiles and increased boosting ability were demonstrated.

The use of twin-screw pumps for moving fluids is not new technology but its application to wet gas compression (high gas volume fraction [GVF]) is still considered relatively new. There are many advantages for using twin-screw pumps for oil field applications; three of the immediate improvements include reducing hardware costs, reducing well bore pressure, and producing a pressure boost to move the product to a central collection facility. While there are many advantages to using twin-screw pumps in wet gas applications, there are some problems that have been encountered while operating at high GVFs. When operating at high GVF, over 95 percent twin-screw pumps experience a severe loss of efficiency and an increase of operating temperature. A common way to increase the efficiency while operating in the high GVF range includes adding a liquid recirculation system where a portion of liquid is stored downstream of the pump and is injected into the pump inlet. These systems lower the effective GVF of the multiphase fluid below 95 percent in order to increase the pump efficiency. The first objective is to characterize the performance of a twin-screw pump fitted with a liquid recirculation system while operating under high GVF conditions. The second objective is to investigate the transient heat rise associated with high GVF operation. While traditional twin-screw pumps can be fitted with a liquid recirculation system to allow them to operate under high GVF conditions the pumps themselves are not optimized for wet gas compression and still suffer performance penalties. The results of this investigation show that the liquid recirculation system can allow the pump to operate under high GVF but the heat added to the system reduces the systems efficiency. Without a method of removing the heat generated in the pumping process the pump will not run at its optimal efficiency. The following investigation provides recommendations for further research in area of multiphase pumping using twin-screw pumps based on the characterization and transient studies provided in this thesis.

The spinel structure of LiMn2O4 powders react with the 1 mole Li2CO3 and 4 mole MnO2 powders by solid-state reaction at 800 oC, and then sintered at 1300 oC to become ceramics specimen. There are accompany phase transformation and non-stoichiometric composition during the cooling process. In X-ray diffraction analysis, the sintered specimen contains principal Li-deficiency Li1-XMn2O4 composition and minor of second phases LiMnO2 and Mn3O4. Lattice parameters also distorted by John-Teller effect. In electron microscopy observation, there are lamellae grains and defects in the specimen, such as twins, dislocations and stacking faults. In TEM analysis, tetragonal-LiMn2O4 structure has lamellae domains, and reflection twinning. However, this study for cubic-LiMn2O4 structure found that edge dislocations with Burger vector of 1/2<110> slip on {110} plane, and mixed(45o) dislocation with Burger vector of 1/2<100> slip on {100} plane.

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Yes / Twin screw granulation (TSG) has been applied to wet granulation, although its application in melt granulation has been more limited. This work explores potential advantages of hot melt granulation using twin screw extrusion. Four main operating and formulation parameters were investigated: screw speed, number of mixing elements, temperature, and binder percentage. Combinations of these factors were then studied to determine their impact on the quantity and characteristics of granules within the desired size range of 125 - 1000 µm. A screening design of experiments (DOE) study was used with each factor set at three levels, to investigate individual factor effects and interactions. Two types of mixing elements were studied: kneading block (KB) and chaotic elements. The type and number of mixing elements were found to be paramount in contributing to the quantity and characteristics of granules formed. Results obtained agreed with previous findings in literature on the influence of different screw elements on the characteristics of granules formed by twin screw granulation. Additionally, the study revealed the unique impact which different mixer elements have on both granule production and characteristics. Depending on the specific need or use of granules in required applications, the granulation process can be effectively designed to meet the end product quality and outcome.