Recently, Iwamoto[1] has proposed a passive-matrix LCD called VA-STN-LCD (Verically Aligned Super Twist Nemetic LCD), in which excellent electro-optic (EO) performance under high-multiplexing conditions has been demonstrated. It was pointed out that such a high EO performance was realized by achieving a pretilt angle of about 80 degree. In this study, we want to learn the different EO characteristic of separate pretilt angle and separate chiral-doped concentration of Negative Dielectric Anisotropy nemetic liquid crystal in vertically aligned cell.