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Thesis (M.S.)--Ohio State University, 1971. / Includes bibliographical references (leaves 89-91). Available online via OhioLINK's ETD Center

Thesis (M.S.)--University of Wisconsin--Madison, 1966. / eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references.

Eighty percent of all biologically treated waste waters in Europe are oxidised by the activated sludge process. Bulking sludge caused by the proliferation of filamentous organisms is the primary cause of failure of this system. The effect of various substrates in both laboratory scale, fully mixed and sequencing batch (SBR) reactor configurations were used to assess their combined effect on activated sludge microbial ecology and hence sludge settlement. Five different substrate types were used ; synthetic sewage, a basic monosaccharide, disaccharides, polysaccharides and amino acids. In all cases using the fully mixed reactor, bulking occurred while, good settling sludge was produced in the sequencing batch reactor. The cause of this bulking was deemed to be due to the lack of so called "selector effect" within the fully mixed reactor characterised by :- i) high rates of substrate consumption ii) high oxygen (or generally: electron acceptor) up take rate iii) enhanced growth of zoogleal bacteria iv) increased metabolic diversity This laboratory work was compared and contrasted with a pure oxygen activated sludge (VITOX) system treating a high strength pea processing waste water. This fully mixed system had proved difficult to operate since its installation and in the first two years of this study suffered bulking caused by low dissolved oxygen levels. In the third year a combination of a hydraulic problem and subsequent lack of control led to filamentous bulking. This particular bulking incident was controlled by the addition of chlorine to the aeration tank which was selectively toxic to the filamentous organisms present. Due to the studies carried out at both laboratory and full scale an initial contact zone was installed within the main aeration tank prior to the 4th year of this study so as to create an area of high floc loading and high substrate uptake. This initial anoxic contact zone proved successful in preventing the development of a poorly settling sludge and is in line with common practice for the elimination of filamentous bulking reported in the literature. Oxidation Reduction Potential (ORP) proved a reliable and appropriate monitor of conditions of low to zero D.O. experienced in the laboratory scale reactors and at full scale in the anoxic contact zone. It was also found that ORP could be used to detect when D.O. levels became completely depleted and monitor reductions in nitrate levels.

Includes bibliography. / This thesis attempts to resolve some of the major problems associated with lime treatment in waste water reclamation. The contribution to knowledge is briefly outlined below. One of the major problems associated with lime treatment is the instability of lime-treated effluent, which may result in serious calcium carbonate scale formation problems. In the thesis this instability is attributed to two fundamental causes, (1) Incomplete precipitation, i.e. a kinetic problem. (2) The unintentional absorption of carbon dioxide from the air by the highly alkaline lime-treated effluent, i.e. a contamination problem. Calcium carbonate and magnesium hydroxide precipitation are time dependent. As a consequence of this time dependency unstable effluent may be produced under reaction conditions commonly encountered in practice. An exhaustive study identified the major factors affecting the precipitation kinetics. Reaction system conditions required for producing a stable effluent are, (1) Lime slurry and sludge, in that sequence, must be thoroughly mixed with the waste water, preferably by means of in-line static mixers, before discharge to a completely stirred tank reactor. (2) A completely stirred tank reactor with a minimum mean residence time of two minutes must be provided for the dissolution and precipitation reactions to go as near to completion as possible. (3) The reactor contents must have a sludge concentration of the order of 10 000 mg l⁻¹.

The Timtek process involves crushing of small diameter trees to form mats which are coated with adhesive then pressed into boards. Crushing yields an effluent water that has a high biological oxygen demand (BOD), chemical oxygen demand (COD), and total suspended solids (TSS). This water must be remediated before it can be discharged into water ways. The objective of this study is to evaluate: 1) the co-composting potential for process waste water, scrim wood waste and poultry manure; and 2) the potential for phytoremediation of diluted process water using duckweed. The results showed that co-composting reduced the bulk and toxicity of both process waste water and wood waste. Plant growth studies showed the composted material is suitable for use as a soil amendment. The results of the phytoremediation study showed that the BOD of the water could be reduced, but levels were still too high for discharge in public waterways.

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