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Water Treatment Plants (WTPs) supply potable water which is transferred by pumps to various end users. WTPs and other sub-systems are energy intensive with pump installed capacities varying between 75 kW – 6 000 kW. It has therefore become important to optimise the utilisation of WTPs. Cost savings can be achieved and the load on the national grid can be reduced. The aim of this study is to develop and implement load management strategies on a municipal WTP. In this investigation the high lift pumps are deemed to be the largest consumers of electricity. Strategies to safely implement load management on a WTP were researched. By optimising the operations of the pumps, significant cost savings can be achieved. Comparisons between different electricity tariff structures were done. It was found plausible to save R 990 000 annually, on a pumping station with four 1 000 kW pumps installed, when switching to a time-of-use dependent tariff structure. Strategies to optimise plant utilisation while attempting a load management study include the optimisation of filter washing methods and raw water operations. An increase of 34% in efficiency for a filter backwash cycle was achieved. To accommodate the effects of the load management on the WTP, the operation of valves that allow water to distribute within the plant was also optimised. The implemented control strategies aimed to accomplish the full utilisation of the WTP and sub-systems to achieve savings. An average evening peak period load shift impact of 2.21 MW was achieved. Due to filter modifications the plant is able to supply 5% more water daily. A conclusion is drawn regarding the success of the strategies implemented. Recommendations are made for further research. / MIng (Mechanical Engineering), North-West University, Potchefstroom Campus, 2015

Mathematical analyses indicated that significant possibilities exist for load shifting projects on a Large Potable Water Utility (LPWU) in South Africa. A primary concern remained, i.e. whether the load variation would have an effect on the water quality. Extensive simulation and testing were initiated in order to prove that the load shift will not affect the water quality. In South Africa, the highest standard for drinking water is the Blue Drop award. The LPWU has received this award multiple times and strives to maintain it. An investigation was launched to determine if this load shifting project would have an effect on the quality standards to which the utility holds (SANS 241 (2011)). The LPWU has over 3000 km of pipelines to supply potable water to the industrial heartland of the country as well as millions of domestic users. The LPWU network is the longest pumping network in the world and is still expanding. The investigation included a simulation of a pumping simulation package to determine how the system would react to the changes. In this simulation, the load reduction in terms of Mega litre per day (Ml/day) was established. Results were compared to the normal operating parameters of the Water Treatment Works (WTW). The mathematical analysis in this investigation concluded that an evening peak load shift of 24.5 MW is achievable. This dissertation will emphasise the necessity of a detailed investigation. The investigations and simulation will determine that the volume of water is well within the operating parameters of the WTW. Studies were done on each area of the plant. In-depth conversations with WTW personnel revealed that the reduction of the volume of water in question will not have an effect on the water quality. Further, it was established that it would be possible to use the sumps of the water treatment works to achieve the desired load shift. By using the sumps of the WTW, a load shift can be done without stopping any process in the WTW with the exception of disinfection at the Booster Pump Stations (BPS), where the balancing reservoirs were used as buffer capacity. The investigation shifted to establish whether stagnant water and a change in dosage would have an effect on the water quality in regard to the reduction and recovery load. As expected, the water never became stagnant at any moment due to the fact that only a small portion of the load was reduced. The water quality and dosage report of the water utility was used and compared to normal operations. The planned load shift had no effect on any aspects of the water quality. The project is feasible and will reach the set targets without affecting the water quality. / MIng (Mechanical Engineering), North-West University, Potchefstroom Campus, 2015

Water Treatment Plants (WTPs) supply potable water which is transferred by pumps to various end users. WTPs and other sub-systems are energy intensive with pump installed capacities varying between 75 kW – 6 000 kW. It has therefore become important to optimise the utilisation of WTPs. Cost savings can be achieved and the load on the national grid can be reduced. The aim of this study is to develop and implement load management strategies on a municipal WTP. In this investigation the high lift pumps are deemed to be the largest consumers of electricity. Strategies to safely implement load management on a WTP were researched. By optimising the operations of the pumps, significant cost savings can be achieved. Comparisons between different electricity tariff structures were done. It was found plausible to save R 990 000 annually, on a pumping station with four 1 000 kW pumps installed, when switching to a time-of-use dependent tariff structure. Strategies to optimise plant utilisation while attempting a load management study include the optimisation of filter washing methods and raw water operations. An increase of 34% in efficiency for a filter backwash cycle was achieved. To accommodate the effects of the load management on the WTP, the operation of valves that allow water to distribute within the plant was also optimised. The implemented control strategies aimed to accomplish the full utilisation of the WTP and sub-systems to achieve savings. An average evening peak period load shift impact of 2.21 MW was achieved. Due to filter modifications the plant is able to supply 5% more water daily. A conclusion is drawn regarding the success of the strategies implemented. Recommendations are made for further research. / MIng (Mechanical Engineering), North-West University, Potchefstroom Campus, 2015

Mathematical analyses indicated that significant possibilities exist for load shifting projects on a Large Potable Water Utility (LPWU) in South Africa. A primary concern remained, i.e. whether the load variation would have an effect on the water quality. Extensive simulation and testing were initiated in order to prove that the load shift will not affect the water quality. In South Africa, the highest standard for drinking water is the Blue Drop award. The LPWU has received this award multiple times and strives to maintain it. An investigation was launched to determine if this load shifting project would have an effect on the quality standards to which the utility holds (SANS 241 (2011)). The LPWU has over 3000 km of pipelines to supply potable water to the industrial heartland of the country as well as millions of domestic users. The LPWU network is the longest pumping network in the world and is still expanding. The investigation included a simulation of a pumping simulation package to determine how the system would react to the changes. In this simulation, the load reduction in terms of Mega litre per day (Ml/day) was established. Results were compared to the normal operating parameters of the Water Treatment Works (WTW). The mathematical analysis in this investigation concluded that an evening peak load shift of 24.5 MW is achievable. This dissertation will emphasise the necessity of a detailed investigation. The investigations and simulation will determine that the volume of water is well within the operating parameters of the WTW. Studies were done on each area of the plant. In-depth conversations with WTW personnel revealed that the reduction of the volume of water in question will not have an effect on the water quality. Further, it was established that it would be possible to use the sumps of the water treatment works to achieve the desired load shift. By using the sumps of the WTW, a load shift can be done without stopping any process in the WTW with the exception of disinfection at the Booster Pump Stations (BPS), where the balancing reservoirs were used as buffer capacity. The investigation shifted to establish whether stagnant water and a change in dosage would have an effect on the water quality in regard to the reduction and recovery load. As expected, the water never became stagnant at any moment due to the fact that only a small portion of the load was reduced. The water quality and dosage report of the water utility was used and compared to normal operations. The planned load shift had no effect on any aspects of the water quality. The project is feasible and will reach the set targets without affecting the water quality. / MIng (Mechanical Engineering), North-West University, Potchefstroom Campus, 2015

Submitted in fulfilment of the requirements of the Degree of Master of Technology: Chemical Engineering, Durban University of Technology, 2013. / Lack of access to clean and safe potable water, especially for people living in rural areas of developing economies, is a matter of great concern in different parts of the world. Measures taken to address the challenges arising from this problem include the improvement of existing water purification methods and development of new appropriate technologies such as point of use (POU) water treatment technologies. One such appropriate POU technology is the Remote Rural Water Treatment System (RRWTS) developed at Durban University of Technology (DUT) in South Africa. The RRWTS is based on polyester woven fabric microfiltration (WFMF) membranes and other locally sourced materials. The filtration unit consists of flat sheet modules assembled into a pack and permeate outlets connected to a manifold and then to a tap. The system is gravity driven and therefore eliminates the use of pumps and electricity. This system has shown potential for use in water treatment as it produces permeate with turbidity below 1 NTU, has a high permeate flow rate, and is easy to use and maintain. However, the major challenge facing its use is that permeate does not meet the set microbiological standards for drinking water (zero E. coli in 100 mL treated water). The RRWTS can ideally remove 95 to 99 per cent of the influent E. coli. This necessitates the use of a separate disinfection step, often using chlorine for complete removal of microbial contaminants. The objectives of this study were: to investigate the incorporation of silver nanoparticles (AgNPs) into the WFMF membrane; to evaluate the disinfection efficacy of the AgNPs impregnated filter (coated filter); and to determine the long term performance of the coated filter in terms of disinfection and silver elution (90 days). The study was conducted in four stages. Firstly, AgNPs were incorporated on the membrane using in situ chemical reduction of silver nitrate using sodium borohydride. Secondly, the filters were characterized using scanning electron microscopy (SEM) to determine the morphology, and the Sessile drop method for contact angle measurement was employed to determine the membrane hydrophilicity. In addition, X-ray diffraction (XRD), Fourier Transform Infrared (FT-IR) spectroscopy and UV- Visible Spectroscopy iii were used to investigate the presence of AgNPs on the coated filter. Thereafter, the antibacterial efficacy of the filters was evaluated using a laboratory scale experimental rig and different microbial assays. Raw river water and deionized water spiked with E.coli (synthetic feed) were used as feed. Lastly, the effects of concentration of E.coli in the feed and silver elution on the disinfection performance of the coated filter over time were investigated. The performance criteria were based on permeate quality and they included: turbidity, concentration of E.coli, and silver concentration. The characterization results depicted that AgNPs were successfully immobilized on the WFMF membranes by in situ chemical reduction. The incorporation of AgNPs was ascertained using UV-Vis Spectrophotometry, FT-IR and XRD. The Sessile drop test indicated that the membrane became more hydrophilic (77 per cent decrease in water contact angle) and the permeability increased significantly as a result of the coating (p <0.05). The coated filters demonstrated excellent filtration performance producing permeate with turbidity less than 1 NTU for feed turbidities between 40 and 700 NTU. The disinfection efficacy was found to be excellent, producing permeate with zero E.coli concentration for feed concentrations between 10,000 CFU/ 100 mL and 85,000 CFU/100 mL. The E.coli removal efficiency was 100 per cent for a period of 63 days of continuous filtration. The ICP Atomic Emission Spectrometer (ICP-AES) results showed that the leaching of silver from the coated filters over time (90 days) was always below 0.1 mg/L which is the widely accepted guideline for potable water. From the literature surveyed, this is the first study which investigated the use of AgNPs in WFMF membranes for potable water disinfection. The coated filters treated water to the set international standards for potable water in terms of physical and microbiological quality. However, the study did not comprise investigation into the effect of different silver loadings on the filter performance. The study also employed E.coli as the indicator organism for faecal contamination. The results obtained can be used as a model for future work using other microorganisms and different silver loadings in order to compare the performance.

Thesis (PhD)--University of Stellenbosch, 2001. / ENGLISH ABSTRACT: Lignocellulose is the principal form of biomass in the biosphere and therefore the predominant renewable source in the environment. However, owing to the chemical and structural complexity of lignocellulose substrates, the effective and sustainable utilization of lignocellulose wastes is limited. Many environments where lignocellulose residues are ordinarily stored can be highly acidic (e.g. landfills), and under these circumstances biodegradation of the lignocellulose is slow and unhygienic. Owing to the metabolic activities of the micro-organisms, the initially acidified habitats rapidly undergoes self-neutralization. A number of pathogenic bacteria (coliforms and Salmonella sp.) are present during this slow degradation process and it is therefore imperative to improve the efficiency and hygienic effects of the biodegradation of the lignocellulose. Although the fundamentals of biodegradation of lignocellulose have been widely investigated, many issues still need to be resolved in order to develop commercially viable technology for the exploitation of these waste products. For example, owing to the complex, heterogeneous structure of lignocellulose, the degree of solubilization, modification and conversion of the different components are not clear. Likewise, the overall anaerobic degradation of lignocellulose is not understood well as yet. In this study, the emphasis was on the promotion of solid anaerobic digestion of lignocellulose wastes for environmental beneficiation and waste reutilization. The degradation of lignocellulose in landfill environments was first simulated experimentally. Once the microbial populations and the degradation products of the system were characterized, the promotion of anaerobic digestion by use of activated sludge was studied. This included acidogenic fermentation, as well as recovery of the methanogenic phase. Moreover, special attention was given to the further disposal of humic acids or humic acid bearing leachates formed in the digestive system, since these acids pose a major problem in the digestion of the lingocellulose. With ultrasonication, approximately 50% of the lower molecular weight fraction of humic acids could be decomposed into volatile forms, but the higher molecular weight fraction tended to aggregate into a colloidal form, which could only be removed from the system by making use of ultrasonically assisted adsorption on preformed aluminium hydroxide floes. This was followed by an investigation of the microbial degradation of humic acids and the toxicity of these acids to anaerobic consortia. Further experimental work was conducted to optimize the biological and abiological treatment of lignocellulose in an upflow anaerobic sludge blanket (DASB) reactor fed with glucose substrate. The humic acids could be partially hydrolysed and decomposed by the acid fermentative consortia of the granules in the DASB reactor. Finally, solid mesothermophilic lignocellulose anaerobic digestive sludge can be viewed as a humus-rich hygienic product that can improve the fertility and water-holding capacity of agricultural soil, nourish plants and immobilize heavy metals in the environment as a bioabsorbent. / AFRIKAANSE OPSOMMING: Lignosellulose is die hoofbron van biomassa in die biosfeer en is daarom ook die belangrikste hernubare bron in die omgewing. As gevolg van die chemiese en strukturele kompleksiteit van lignosellulose substrate, is die doeltreffende en volhoubare benutting van lignosellulose afval egter beperk. Die suurgehalte van die omgewings waar lignosellulose reste gewoonlik gestoor word, soos opvullingsterreine, kan hoog wees en onder hierdie omstandighede is die biodegradasie van die lignosellulose stadig en onhigiënies. As gevolg van die metaboliese aktiwiteite van die mikro-organismes ondergaan die aanvanklik aangesuurde habitatte vinnig self-neutralisasie. 'n Aantal patogeniese bakterieë (koliforme en Salmonella sp.) is deurgaans gedurende dié stadige natuurlike proses teenwoordig en dit is dus van die grootste belang om die effektiwiteit en die higiëne van die bioafbreking van die lignosellulose-substraat te verhoog. Alhoewel die grondbeginsels van die bioafbreking van lignosellulose reeds wyd ondersoek is, moet verskeie probleme nog opgelos word ten einde kommersieel haalbare tegnologie te ontwikkel vir die ontginning van afvalprodukte. Byvoorbeeld, as gevolg van die komplekse, heterogene struktuur van lignosellulose, is die graad van solubilisering en die modifikasie en omskakeling van verskillende komponente nog onduidelik. Net so word die algehele anaerobiese afbreking van lignosellulose ook nog nie ten volle verstaan nie. In hierdie ondersoek het die klem geval op die bevordering van soliede anaerobiese digestie van lignosellulose afval vir omgewingsverbetering en die benutting van die afval. Die afbreking van lignosellulose in opvullingsterreine is eers eksperimenteel gesimuleer. Nadat die mikrobiese populasies en die afbrekingsprodukte gekarakteriseer is, is die bevordering van anaerobiese digestie deur die gebruik van geaktiveerde slyk bestudeer. Dit het asidogeniese fermentasie ingesluit, sowel as herwinning van die metanogeniese fase. Spesiale aandag is gegee aan die verdere verwerking van humus sure en humussuurbevattende legate wat in die digestiewe stelsel gegenereer is, aangesien die sure probleme veroorsaak het met die vertering van die lignosellulose. Met ultrasoniese straling is nagenoeg 50% van die lae-molekulêre massafraksie van die humussure ontbind in vlugtige vorm, maar die hoë-molekulêre massafraksie het geneig om in 'n kolloïdale vorm te aggregeer, wat slegs uit die stelsel verwyder kon word deur middel van ultrasonies ondersteunde adsorpsie op voorafgevormde aluminiumhidroksiedvlokkies. Dit is gevolg deur 'n ondersoek na die mikrobiese afbreking van humus sure en die toksisiteit van die sure ten opsigte van anaerobiese konsortia. Verdere eksperimentele werk is gedoen ten opsigte van die biologiese en abiologiese behandeling van lignosellulose in 'n opwaartsvloeiende anaerobiese slikkombersreaktor (OASK) gevoer met glukosesubstrate. Die humus sure kon gedeeltelik gehidroliseer en ontbind word deur die suurgistende konsortia van die granules in die OASK reactor. Ten slotte kan die vaste termofiliese-mesofiliese anaerobiese lignosellulose verteringslik ook gesien word as 'n humusryke higiëniese produk wat die vrugbaarheid en die waterhoudende vermoë van landbougrond kan verhoog, plante kan voed en kan funksioneer as bioabsorbeerder van swaarmetale in die omgewing.

This critical overview document (COD) presents, discusses and brings together the selected portfolio of publications that the author believes make a significant contribution to the field of wastewater treatment, focusing on the removal of endocrine disrupting chemicals (EDCs) in wastewater treatment applications. The aim of the research within this COD was to investigate the fate, mechanisms and optimisation of EDCs removal in wastewater treatment applications. The key objectives were to: 1. Investigate and understand the mechanisms of removal of EDCs in wastewater and sludge treatment processes. 2. Evaluate novel methods for the removal of EDCs in water and wastewater treatment applications. 3. Establish the kinetic and thermodynamic properties of the removal processes to inform process modelling of full scale design of treatment processes.

This work was concerned with the determination of mass transfer and kinetic parameters of ozone reactions with four organic compounds from different families, namely reactive dye RO16, triclocarban, naphthalene and methanol. In order to understand the mechanisms of ozone reactions with the organic pollutants, a radical scavenger (t-butanol) was used and the pH was varied from 2 to 9. Ozone solubility (CAL*) is an important parameter that affects both mass transfer rates and chemical reaction kinetics. In order to determine accurate values of the CAL* in the current work, a set of experiments were devised and a correlation between CAL* and the gas phase ozone concentration of the form CAL*(mol/L) = 0.0456 CO3 (g/m3 NTP) was obtained at 20°C. This work has also revealed that t-butanol did not only inhibit hydroxyl radical reactions but also increased mass transfer due to it increasing the specific surface area (aL). Values of the aL were determined to be 2.7 and 3.5 m2/m3 in the absence and presence of t-butanol respectively. It was noticed that the volumetric mass transfer coefficient (kLa) has increased following the addition of t-butanol. Ozone decomposition was studied at pH values of 2 to 9 in a 500 mL reactor initially saturated with ozone. Ozone decomposition was found to follow a second order reaction at pH values less than 7 whilst it was first order at pH 9. When the t-butanol was added, the decomposition of ozone progressed at a lower reaction order of 1.5 for pH values less than 7 and at the same order without t-butanol at pH 9. Ozone decomposition was found significant at high pHs due to high hydroxide ion concentration, which promotes ozone decomposition at high pHs. The reaction rate constant (k) of RO16 ozonation in the absence of t-butanol was determined. The result suggests that RO16 degradation occurs solely by molecular ozone and indirect reactions by radicals are insignificant. The chemical reaction of triclocarban with ozone was found to follow second order reaction kinetics. The degradation of naphthalene using the liquid/gas-ozone (LGO) system was studied. This result showed that hydroxyl radicals seemed to have limited effect on naphthalene degradation which was also observed when a radical scavenger (t-butanol) was used. Reaction rate constants were calculated and were found around 100 times higher than values reported in the literature due to differences in experimental conditions. From the results of the experimental investigation on the degradation of methanol by ozone it was found that the rate constant (k) of the degradation reaction increased at pH 9. The reaction stoichiometry was found to have a value of 1 mol/mol. The two steps of the liquid/solid-ozone (LSO) system were studied on beds of silica gel and a zeolitic material (D915) and the ozone adsorption process was modeled and found that particle rate controls ozone adsorption step but liquid rate controls the water treatment step. Ozone desorption with pure deionised water was studied. The water flow rate was found to accelerate the desorption rates but pH was found to decrease the desorption rates. In contrast, the effect of pH was insignificant in the presence of t-butanol. Determination of the adsorption isotherms for RO16, naphthalene and methanol revealed that RO16 did not exhibit adsorption on silica gel, but both naphthalene and methanol showed adsorption on D915 described by Langmuir model.

Water and energy share an important relationship since it takes water to produce energy, and likewise, energy to pump, treat, and distribute water. This thesis explores the energy-water nexus in regards to electricity and transportation fuel production, as well as water treatment. It investigates how the Energy Independence and Security Act of 2007 might affect this interrelationship in the future since increases in corn cultivation for biofuels production are likely to lead to higher nitrate concentrations in US water reservoirs, which could trigger the requirement for additional energy consumption for drinking water treatment. The analysis indicates that advanced drinking water treatment might require an additional 2360 million kWh annually to treat drinking water currently exceeding the Environmental Protection Agency’s maximum contaminant level (MCL) limit of 10 mg per liter of nitrate-nitrogen. This is a 2100% increase in energy consumption for advanced water treatment to meet this MCL in comparison with surface water treatment alone. Although results indicate that most large surface and groundwater drinking water resources are not likely to exceed safe drinking water standards due to the expansion of corn-starch based ethanol production, smaller water reservoirs in agricultural regions are susceptible to nitrate contamination in the future. Consequently, these sources might require energy-intensive drinking water treatment to reduce nitrate levels below 10 mg per liter of nitrate-nitrogen. Based on these results, I conclude that projected increases in nitrate contamination in water may impact the energy consumed in the water treatment sector, because of the convergence of several related trends: (1) increasing cornstarch-based ethanol production, (2) increasing nutrient loading in surface water and groundwater resources as a consequence of increased corn-based ethanol production, (3) additional drinking water sources that exceed the MCL for nitrate, and (4) potentially more stringent drinking water standards for nitrate. / text