Chromium is a common groundwater pollutant originating from industrial processes such as metal plating, leather tanning and pigment manufacturing. Permeable reactive barriers (PRBs) have proven to be viable and cost-effective systems for remediation of chromium contaminated groundwater at many sites. The purpose of this research presented in this thesis is to focus on two parameters that affect the performance of PRB on chromium removal, namely the concentration of reactive media and groundwater flux by analyzing the data obtained from laboratory column studies. Laboratory scale columns packed with different amounts of iron powder and quartz sand mixtures were fed with 20 mg/l chromium influent solution under different fluxes. When chromium treatment efficiencies of the columns were compared with respect to iron powder/quartz sand ratio, the amount of iron powder was found to be an important parameter for treatment efficiency of PRBs. The formation of H2 gas and the reddish-brown precipitates throughout the column matrix were observed, suggesting the reductive precipitation reactions. SEM-EDX analysis of the iron surface after the breakthrough illustrated chromium precipitation. In addition to chromium / calcium and significant amount of iron-oxides or -hydroxides was also detected on the iron surfaces. When the same experiments were conducted at higher fluxes, an increase was observed in the treatment efficiency in the column containing 50% iron. This suggested that the precipitates may not be accumulating at higher fluxes which, in turn, create available surface area for reduction. Extraction experiments were also performed to determine the fraction of chromium that adsorbed to ironhydroxides. The analysis showed that chromium was not removed by adsorption to oxyhydroxides and that reduction is the only removal mechanism in the laboratory experiments. The observed rate of Cr(VI) removal was calculated for each reactive mixture which ranged from 48.86 hour-1 to 3804.13 hour-1. These rate constants and complete removal efficiency values were thought to be important design parameters in the field scale permeable reactive barrier applications.

Clinoptilolite samples obtained from two deposits in Turkey were tested for their potential in removing cadmium from aqueous solutions. Preliminary experiments in batch mode revealed inferior cadmium uptake at low pH. Particle size was found to have no effect on cadmium removal efficiency suggesting the use of exchangeable cations found in the internal/available sites. Increasing temperature yielded positive, whereas prewashing had no effect on cadmium removal using both clinoptilolite samples. The Langmuir model fitted the equilibrium data for both samples better than the Freundlich model. The capacity reached after conditioning represents about 4 and 3 fold increase for G&ouml / rdes and Bigadi&ccedil / samples, respectively. The relatively poor performance of Bigadi&ccedil / clinoptilolite was due to low clinoptilolite/high impurity contents. Further studies were carried out only with G&ouml / rdes clinoptilolite. The performance of the G&ouml / rdes samples conditioned with various chemicals were NaCl&gt / KCl&gt / As-received&gt / CaCl2&gt / HCl. 20BV of NaCl solution was found to be sufficient with no pH adjustment or water quality requirement during column conditioning. In column experiments, among the tested flowrates 5, 10 and 15 BV/hr, highest flowrate indicated inferior utilization of the removal capacity. No significant difference by decreasing particle size indicated pore diffusion resistance not to be a limiting factor. In five conditioning and regeneration cycles, clinoptilolite exhibited 36% increase in operating capacity. Cadmium removed by clinoptilolite in progressing cycles was concentrated by about 7 times. Overall, this study shows that Manisa-G&ouml / rdes clinoptilolite is advantageous for the removal of cadmium ions from aqueous solutions and hold great potential to be used in practical applications.

In the present study, the recovery of the indigo dyeing rinsing wastewater originating from a denim textile mill to the degree of reuse quality, which generally requires nanofiltration (NF), was investigated. In order to control flux decline and hence to maintain an efficient NF / coagulation, microfiltration (MF) and sequential MF plus ultrafiltration (UF) pretreatment process alternatives were tested. All pretreatment alternatives were optimized to reduce chemical oxygen demand (COD) and color load to NF. Coagulation process was investigated using the coagulants, aluminum sulfate (Al2(SO4)3.18H2O) and ferric chloride (FeCl3.6H2O) by running a series of jar tests. The results showed that coagulation process did not provide an effective and efficient pretreatment due to high dose of coagulant requirement. MF tests run by using 0.45, 2.5 and, 8 &micro / m membranes indicated that MF through 0.45 &micro / m pore-sized membrane is the best process providing 64% color and 29% COD removals, leading to a color value of 2493 Pt-Co and COD of 892 mg /L in the permeate. Application of sequential MF+UF filtration provided a significant benefit over single MF in terms of rejections and also permeate flux. UF applied after MF provided additional 62% color and 4% COD removals leading to 960 Pt-Co color and 856 mg/L COD. NF tests conducted using pretreated wastewater via single MF and sequential MF+UF indicated that single MF is the best pretreatment to NF and this treatment scheme provided 99% color, 97% COD and 80 % conductivity removals and satisfied reuse criteria.

Rapid urbanization and population growth have represented a great challenge to water resources management, since wastewater generated in urban areas forms a non-conventional source, wastewater reuse is being recognized as a sustainable water management approach. This study focuses on with the potential and practibility of implementing wastewater reuse techniques in Izmir region, especially with the aim to use treated wastewater and nutrient for agriculture. To this end, qualititative and quantitative agricultural water demand were considered. This thesis introduces a wastewater reuse planning model and optimization method with an emphasis on the wastewater treatment technology used as well as the agricultural demand in the area of the study. The model was developed with considerations over water quality, wastewater treatment and discharge. The objective of the model is to upgrade existing wastewater treatment plants or to design new treatment plants in regard to reuse wastewater in agriculture. The model is also capable of comparing treatment technologies from the point of design and cost. Three case studies were represented so as to demonstrate the modeling process and optimization studies for agricultural irrigation.

N-Nitrosamines are an emerging group of disinfection byproducts characterized by high carcinogenic risks at ng/L levels and by their frequent detection in water and wastewater treatment systems in the U.S. and other parts of the world. The overall goal of this research is to achieve a better understanding of the roles of common nitrosamine precursors in leading to N-nitrosamine formation in water and wastewater treatment systems. The specific objectives of this research are: (a) To probe the mechanisms of nitrosamine formation from commonly employed water treatment polymers, particularly polyDADMACs, during ozonation, (b) To evaluate the role of dithiocarbamate compounds as nitrosamine precursors in reaction with common water disinfection oxidants, and (c) To investigate the potential enhancement effect of activated carbons (AC) to promote transformation of amines to nitrosamines and identify the involved reaction mechanism. Results of this research show that, upon ozonation, polyDADMACs may yield N-nitrosodimethylamine (NDMA) at levels up to two orders of magnitude higher than current advisory guidelines for NDMA. Radical pathways may be responsible for the degradation of the quaternary ammonium ring groups in polyDADMACs to release of dimethylamine (DMA). Detection of significant amounts of nitrite after ozonation of polyDADMACs and DMA suggests the potential role of nitrosation pathway in NDMA formation. Study results also reveal dithiocarbamates as potent nitrosamine precursors with significant nitrosamine yields upon ozonation and monochloramination. Identification and quantification of reaction products suggest nitrosation and chlorinated-UDMH oxidation as primary reaction mechanisms in nitrosamine formation from ozonation and monochloramination of dithiocarbamates compounds, respectively. This research also demonstrates that many commercial AC materials may catalyze transformation of secondary amines to yield trace levels of N-nitrosamines under ambient aerobic conditions. This is a novel discovery with far-reaching implications because of the widespread usage of AC materials in numerous analytical and environmental applications. The study results show that the properties of AC materials and reaction conditions play a crucial role in the catalyzed nitrosamine formation and should be carefully selected to minimize analytical errors and undesirable nitrosamine formation in water samples. Overall, the mechanistic information obtained in this research will be useful for the water industry and research communities to develop more effective strategies to control undesirable nitrosamine formation in water and wastewater treatment systems and thus better protect the public health.

M. Tech. Chemical Engineering. / Discusses the HybridICE filter as a new but economical device for separating the ice from the slurry in freeze desalination processes. There is no direct information in the literature on the filter so there is a need to describe the principles behind the operation. There is also a need to investigate the filtering process in order to increase yield and purity of the ice produced. No design method exists for the filter. A design method has to be established so that when the required flow-rate is determined, the dimensions of the filter can be calculated.

M. Tech. Engineering: Chemical / Researches the usability and efficiency of the synthesized PPy/Al2O3 nanocomposite as adsorbent in Cr(VI) remediation from contaminated wastewaters.The specific objectives of the study are:to synthesise and characterize the PPy/Al2O3 nanocomposite ; to characterize the prepared nanocomposite using several sophisticated instruments such as, SEM, BET, XRD, et cetera ; to carryout batch adsorption equilibrium and kinetics studies for evaluating the performance of the nanosorbent and to gain insight into the underlying adsorption mechanisms.; to apply adsorption equilibrium and kinetic models.; to assess the breakthrough performance of the PPy/Al2O3 nanocomposite for Cr(VI) adsorption by varying operating parameters, in fixed bed column mode and to apply existing mathematical models to predict the performance of fixed bed adsorption systems and to obtain column design parameters.

M. Tech. Water Care. / Aims determining whether inadequate treatment of wastewater and the faecal pollution load of effluents and receiving water bodies in Sedibeng District and Soshanguve peri-urban area of Tshwane Metropolitan Municipality were a function of population growth. To achieve the aim of this study, the following objectives were pursued: Assess the variation in nutrient load and compliance of the physicochemical quality of effluents and receiving water bodies in terms of the South African and World Health Organization standards. Furthermore, the water quality index was also used to assess the overall physicochemical quality status of effluent and receiving water bodies. Assess the compliance of the microbial quality of effluents of the four wastewater treatment plants and their respective receiving water bodies in terms of the South African and World Health Organization limits. Determine the prevalence of Salmonella Typhimurium, Shigella dysenteriae and Vibrio cholerae in the targeted wastewater treatment works effluent and their respective receiving water bodies. Determine the possible public health risks of Escherichia coli, Salmonella Typhimurium, Shigella dysenteriae and Vibrio cholerae infections that could be acquired due to ingestion of or exposure to untreated water from the targeted receiving water bodies. Capture information regarding population growth and wastewater treatment plants in Sedibeng District and Soshanguve peri-urban area of Tshwane Metropolitan Municipality and determine whether under performance of the targeted wastewater treatment works could be attributed to population growth.

Many rural communities in South Africa do not have running water or electricity. The fetching and heating of water is therefore a time consuming and expensive daily ritual. The use of energy sources such as wood or coal are not readily available and cause environmental pollution. Although solar water heaters are commonly available in South Africa, they are very seldom used in rural areas. Whilst this can mostly be attributed to a high system cost, current designs also do not cater for specific rural problems such as the transporting or purification of water. A prototype model, designed with such an approach in mind, has already been constructed by TEMM International (Pty.) Ltd. The Solar Heat Barrow (SHB) was developed in the 1992 to 2003 period with the intention of combining a number of functions at low cost. Specific requirements were: low cost, a suitable design and materials for manufacture in large volume, sufficiently durable taking into account the harsh conditions of use. suitability for cases where no in-house piped water supply was available, the use of appropriate technology and the improvement of quality of life. The unit combines the absorption of solar radiation, the heating of a relatively small volume of water, the transport of the water from the point of supply and the storage of the hot water until it is used. Untreated water sources such as surface waters (streams, rivers, lakes, etc.) or unprotected open wells are the vehicles for waterborne bacterial diseases such as cholera and typhoid fevers. In the case where water is collected from these sources, the SHB has a build-in Purification Dispenser that purifies the water in the collector against waterborne bacterial diseases. Certain research questions need to be answered. They will be answered by demonstrating the SHB in two communities where no in-house piped water supply is available and by establishing the socio-economic response of the users. The research questions are as follow: What are the responses of the users concerning the SHB, in comparison to those of a control group, regarding its operation, durability, utility and satisfaction of needs? What is the daily use of hot water and the reduction in energy use and cost? To what extent will the target community purchase the SHB at the full or subsidised commercial price? Is there a business case that can be developed for the large scale production, marketing. financing and Small, Medium and Micro Enterprises (SMME) development of the SHB? It was decided to choose a community in the Valley of Thousand Hills in KwaZulu Natal as the demonstration site. The name of the community is Mabedlane. It is a remote rural area 20 km's north of Botha's Hill and is situated along the Umgeni River. The community is dependent on the river for domestic water. Most families are headed by women. The area has low levels of infrastructure, poor roads, a high unemployment rate and poor health facilities. The first survey, which was conducted before the test period started, showed a very positive response from potential users. From 112 questionnaires that were given to the people of Mabedlane, all indicated that they were interested in a product that can transport and heat water for domestic use. The socio-economic study has shown that the price per unit needs to be adapted as 85% of the people who participated in the survey indicated that they would only pay less than R100 for the product. 15% indicated that they would pay between RlOO and R200. From the second and third questionnaires it was clear that the users were satisfied with the heating performances of the SHB. The community was very interested in purchasing a SHB. They have realised that a SHB will improve their standard of living and regard it as a necessity in their day to day activities. It is apparent that people, who will benefit from a SHB most, are those who will not be able to pay the full retail price. Therefore, new business strategies have to be researched when implementing the SHB to the target market in South Africa. The idea of considering ways to sponsorlfund the SHB must also be investigated. / Thesis (M.Ing. (Mechanical Engineering))--North-West University, Potchefstroom Campus, 2004.

Endotoxins are a constituent of the lipopolysaccharide (LPS) complexes present in the outer layer of the cell wall of most Gram-negative bacteria and some cyanobacteria. The ingestion by a typical adult of amounts exceeding 1,000 endotoxin units (EUs) can cause fever, diarrhoea, vomiting, acute respiratory illnesses, and lung inflammation. In contrast, much smaller doses may lead to protective immunity against allergic diseases. / Endotoxins can be released in the air as well as in the water; previous studies have mainly focused on airborne endotoxins. Although many studies on endotoxins in raw and treated drinking waters have been performed, few have assessed seasonal variations and none have been conducted in Eastern Canada. Furthermore, a clear understanding of removal of endotoxins by various water treatment processes is still required. / Two methods to measure the concentrations of endotoxin were used and compared, the Limulus Amebocyte Lysate test (LAL) and the recombinant Factor C test (rFC). Raw water samples were taken from various drinking water sources around the Island of Montreal. The effects of free chlorine, UV radiation, and ozone were studied in batch experiments on filtered water samples via typical dosages and fluences used in drinking water treatment facilities. Residual concentrations for free chlorine were 0.8 and 1.6 mg/L; ozone doses were 0.5 and 1 mg/L; UV fluences were 40 and 100 mWs/cm2. Detention times of 20 and 60 minutes were tested for chlorine and 5 and 20 minutes for ozone. Grab sampling from three drinking water treatment plants in the Montreal area was performed during the months of June and late August/September 2006 and January 2007. Processes at these plants include coagulation and flocculation, sand filtration, ozonation and disinfection by chlorine. To test the variation in endotoxin concentrations during a sand filter cycle, samples were withdrawn directly from a filter in one of the treatment plants studied. The filtration cycle, from one backwash to the next one, lasts 72 h. Samples were collected immediately before the backwash, at the beginning and at the end of the ripening period, at the beginning of the filtration cycle and 48 h later, which corresponds to a half cycle period. / Of the two endotoxin detection methods used, LAL consistently gave slightly higher values compared to rFC; rFC also required more expensive hardware, but the method was less tedious and reagent costs were lower. Results presented, unless otherwise stated, were obtained with the rFC method. Endotoxin levels decreased in raw water samples between June and September. Concentrations ranged from 20 to 30 EU/mL in June, and decreased to 10 to 14 EU/mL in August and beyond. For the disinfection processes, the UV and free chlorine doses tested had little or no effect on the endotoxin concentrations, but ozone reduced the concentrations by up to 75%. Sand filtration and flocculation showed significant endotoxin removal efficiencies (50--60%). Levels remained around 5 EU/mL throughout the remaining treatment processes regardless of the influent concentration. Hence, endotoxin inactivation by free chlorine and UV does not occur with typical doses used in drinking water treatment plants; in contrast, flocculation and sand filtration, as well as ozonation, are much more effective.