Thesis (M.S.)--University of Hawaii at Manoa, 2006. / Includes bibliographical references (leaves 131-144). / xiv, 144 leaves, bound ill. 29 cm

Endocrine disrupting chemicals (EDCs) are a group of synthetic and natural chemicals that have the potential to mimic the hormone-like activities in the human body. This study was conducted to recognize whether recycled water (a source of EDCs) has the potential to contaminate the environment when such water is used for irrigation purposes. Batch sorption and miscible displacement experiments were conducted to elucidate the fate and transport of four EDCs including estrone, 17β estradiol, octylphenol and nonylphenol in a soil from Hawaii. The sorption capacity of the soil from two depths (2 ft as topsoil and 15 ft as saprolite) was estimated using recycled water and deionized water as the mobile phases. The transport parameters of these contaminants were obtained by using the inverse modeling approaches as provided in the HYDRUS 1D code. All four EDCs sorbed significantly on the soil. Octylphenol and Nonylphenol rapidly degraded during sorption. The Freundlich model was suitable to describe the sorption isotherm. The sorption nonlinearity was relatively higher for saprolite compared to topsoil. Both physical and chemical non-equilibrium processes were found to affect the mobility of the EDCs in the soil. The migration of EDCs in the soil was enhanced in recycled water due to the presence of dissolved organic carbon and elevated salt concentration. The ambient pH had little effect on sorption of EDCs on the soil from either depth.

This study examines whether recycled water (specifically grey water) is used in peri-urban agriculture in greater Port Elizabeth. It also investigates the socio-economic as well as environmental benefits of using recycled water in peri-urban agriculture. Community perceptions and narratives about the use of recycled water for farming purposes were also investigated. Study respondents were purposively selected from Motherwell and Uitenhage in Port Elizabeth. A qualitative research methodology and methods were used. This involved using purposive sampling to sample, select and interview 22 respondents and eight key informants. All the respondents were interviewed using in-depth semi-structured interviews. The study found that while many respondents have heard about water recycling, they are however not using recycled grey water for their peri-urban farming activities. Instead, peri-urban farmers continue to use water supplied by the municipality. Recycled water is mostly used for watering sport fields around Port Elizabeth. This continued usage of municipal water (instead of recycled water) is not only costly to the municipality but the individual farmers as well. The respondents were however aware of the benefits of using recycled water. These include economic (money saved from not paying irrigation water bills), environmental (nutrient contents found in recycled water) and socio-economic (conserving fresh available for use in other community purposes). The study recommends that the Nelson Mandela Metro Municipality should do more (through educational and environmental campaigns) to encourage peri-urban farmers to use recycled water in their farming activities.