Orientador: Ricardo de Lima Isaac / Tese (doutorado) - Universidade Estadual de Campinas, Faculdade de Engenharia Civil, Arquitetura e Urbanismo / Made available in DSpace on 2018-08-12T13:40:20Z (GMT). No. of bitstreams: 1 Gerolin_EleonilceRosaRossi_D.pdf: 4382249 bytes, checksum: 11ae4682864ae425b2aad5ee5844f76c (MD5) Previous issue date: 2008 / Resumo: A ocorrência de compostos considerados disruptores endócrinos (DE) em efluente de Estação de Tratamento de Esgoto (ETE) e em águas superficiais em concentrações de risco para animais silvestres constitui campo de pesquisa de elevado interesse devido à probabilidade de que esses micropoluentes não sejam removidos nos processos físico-químicos empregados em Estação de Tratamento de Água (ETA) convencional. O presente trabalho avaliou a ocorrência de estrógenos naturais estrona (E1), 17ß Estradiol (E2), Estriol (E3), o estrógeno sintético 17a Etinilestradiol (EE2) e Nonilfenol (NP) em água de abastecimento público das cidades de Campinas e Sumaré-SP. Para tal, coletou-se água bruta (do rio Atibaia, na entrada da estação) e água tratada nas ETAs 3 e 4 de Campinas e ETA 2 de Sumaré, num período de três semanas. Os procedimentos analíticos empregados foram extração em fase sólida e análise por cromatografia líquida de alta eficiência e espectrometria de massa (CLAE-EM/EM). A média dos resultados obtidos para água tratada de Campinas e Sumaré foram, respectivamente, de 0,10 e 0,08 ng/L de E1, 0,92 e 1,30 ng/L de E2, 0,70 e 0,62 ng/L de E3, 275 e 472 ng/L de EE2 e 6,14 e 4 ng/L de NP. O tratamento utilizado em Campinas remove, em média, acima de 80% dos DE em estudo, com exceção de EE2, cuja remoção foi de 38%. Em Sumaré, a remoção foi da ordem de 80% de E1 e E2, 64% de E3 ; 55% NP e 41% de EE2. Considera-se que a oxidação por cloro tenha sido preponderante na remoção dos DE alertando-se, porém, para a probabilidade da formação de subprodutos potencialmente estrogênicos. Mesmo ante tal eficiência de remoção, a presença de DE, detectados em água tratada, ainda que em pequenas concentrações, pode atribuir atividade estrogênica, haja vista que estrógenos naturais e sintéticos no ambiente podem exercer efeitos mesmo em concentrações muito baixas (1ng/L). / Abstract: The occurrence of potential endocrine disruptor compounds (EDC) in wastewater treatment plant (WWTP) effluent and surface waters at high concentrations harmful for aquatic life has been an interesting research field due to the probability of these micro pollutants to break through water treatment plant (WTP). The present paper evaluated the occurrence of natural estrogens such as estrone (E1), 17ß-estradiol (E2), estriol (E3), as well as the synthetic estrogen 17a ethinylestradiol (EE2) and nonylphenol (NP) at water supply systems of Campinas and Sumaré. Raw water from Atibaia River and treated water samples were collected from Campinas WTP-3-and-4 and Sumaré WTP-2 over a three-week period. The analytic technique used was solid phase extraction and liquid chromatography/ tandem mass spectrometry (LC-MS/MS). The average results obtained for drinking water in Campinas and Sumaré were, respectively, 0.03 and 0.06ng/L for E1, 0.93 and 1.32ng/L for E2, 0.70 and 0.72ng/L for E3, 91.2 and 154ng/L for EE2 and 6.14 and 4ng/L for NP. Campinas WTP obtained an average removal of = 80% of focused EDC, except for EE2, whose efficiency was 38%; Sumaré WTP removal efficiency was 80% for E1 and E2, 60% for E3 and NP and 41% for EE2. Chlorine oxidation was probably the major treatment step for EDC removal, though potentially estrogenic by-products could have been formed as well. The presence of EDC in drinking water, despite the low concentrations, could provide estrogenic activity, since it is well known that natural and synthetic estrogen in the environment can produce effects at very low concentration (1ng/L). / Doutorado / Saneamento e Ambiente / Doutor em Engenharia Civil

Since the demand for fresh potable water increases every year, it is important to have future water demand strategies in place. People expect a secure, high quality, water supply and the water supply industry is governed by increasingly stringent water quality guidelines and legislation. The Cape Metropolitan Area (CMA) faces the challenge of an increasing demand for fresh water in excess of the existing supply. The City is responsible for the planning and development of the local water supply resources as well as managing the water demand in the CMA and to supplement the water supply to the City of Cape Town from local sources. The ‘Voëlvlei Augmentation Scheme’ was identified as one of the options to augment the water supply to the CMA. This option would involve pumping winter water from the Berg River via a pipeline to the Voëlvlei water treatment plant (WTP). The Voëlvlei WTP was designed to treat water from the adjacent Voëlvlei Dam. This Voëlvlei WTP raw water has a higher turbidity and a lower colour in comparison to the Berg River water. The plant’s treatment conditions were optimized to remove this high turbidity. The Voëlvlei WTP raw water also contains a relatively high manganese concentration and coagulation therefore occurs at a high pH with ferric sulphate to remove the manganese during the initial stages of the water treatment process. As the quality of the Berg River water is different to that of the Voëlvlei WTP raw water, it might not be possible to treat the Berg River water at the Voëlvlei WTP using the plants current treatment parameters. The Berg River water could possibly be blended with the Voëlvlei WTP raw water before treatment at the WTP. If the Berg River water, or its blends, could not be treated at the Voëlvlei WTP using the plants current treatment parameters, then this water would have to be pre-treated before entering the plant. Various forms of pre-treatment could be used, e.g., conventional water treatment using either aluminium or ferric sulphate as primary coagulants or ion-exchange water treatment using the MIEX® resin or even a combination of both. The main objective of this study was to determine a treatment strategy for the Berg River water at the Voëlvlei WTP. It is therefore important to determine if the Berg River water could be treated at the Voëlvlei WTP using the current treatment regime. Also, if the Berg River water should be blended with the Voëlvlei WTP raw water, this study would determine which blend would be the most suited for treatment at the Voëlvlei WTP. If the Berg River water could not be treated directly at the Voëlvlei WTP, a pre-treatment strategy for this water should be determined. The cost of pretreatment of the Berg River water as compared to the cost of direct treatment at the Voëlvlei WTP should also be evaluated. In order to determine the best treatment strategy for the Berg River water at the Voëlvlei WTP, it was important to sample the Berg River water and the Voelvlei WTP raw water at regular intervals over a period of at least a year to determine its quality and the impact of seasonal changes. Various laboratory physical (e.g., turbidity) and chemical (e.g., total alkalinity) analyses were conducted on the Berg River water and Voëlvlei WTP raw water to determine its quality. The experimental procedure focused mainly on the Jar test which simulates the coagulation, flocculation and sedimentation processes at the Voëlvlei WTP. Jar tests were conducted on the Berg River water and the Voëlvlei WTP raw water using ferric sulphate and aluminium sulphate as coagulants to determine the optimum pH and optimum coagulant dosage concentration for each coagulant. The Berg River water was also blended with the Voëlvlei WTP raw water in three different proportions and Jar tests were conducted on these blends using ferric sulphate as the coagulant at a coagulation pH of 5.0 and a Fe3+ dosage of 5.0 mg/L. Jar tests were also conducted on these blends with the Voëlvlei WTP treatment parameters using ferric sulphate as the coagulant at a coagulation pH of 9.2 and a Fe3+ dosage of 3.5 mg/L. The analytical results showed a similar pattern for the characterization of the Berg River water and the Voëlvlei WTP raw water. The iron and aluminium concentrations were consistently low during the summer months with significant increases during the winter months. There were no significant seasonal impact on the UV absorbance and colour. The Jar test results of the Voëlvlei WTP raw water and the Berg River water with ferric sulphate as the coagulant showed an optimum Fe3+dosage of 3.0 to 4.0 mg/L and 4.0 to 6.0 mg/L, respectively, with an optimum coagulation pH range of 6.6 to 9.5 and 5.0 to 10.0, respectively. The Jar test results of the Voëlvlei WTP raw water and the Berg River water with aluminium sulphate as the coagulant showed an optimum Al3+ dosage of 2.5 to 3.0 mg/L and 4.0 to 5.0 mg/L, respectively, with an optimum coagulation pH of 6.0 to 7.0 and 6.0, respectively. The Jar test results obtained for all 3 blends were similar to each other. The UV absorbance of the treated water was consistently below the operational specification, while the turbidities were inconsistent and did not always comply with the SANS 241:2006 Specification (Class I) for drinking water. The iron of the treated water was also consistently above the specified value of <0.200 mg/L. The Jar tests conducted on all 3 blends, with the Voëlvlei WTP treatment parameters, also yielded similar results. The UV absorbance of the treated water was consistently above the maximum operational specification of 0.100, while the turbidities were also consistently above the SANS 241:2006 Specification of <1 NTU. Both ferric sulphate and aluminium sulphate can be used as coagulants to treat the Berg River water, although ferric sulphate would be the preferred choice due to its wide coagulation pH range and also because of differences in their health effects. The Voëlvlei WTP coagulates at a pH of 9.2 to remove turbidity and any manganese that might be present in the raw water. The manganese would not be removed at the low coagulation pH of aluminium sulphate. The specified treatment parameters, including the Voëlvlei WTP treatment parameters, used in treating the raw water blends were not effective and further investigation and research is necessary to determine its optimum treatment parameters. This study concluded that the Berg River water cannot be effectively treated at the Voëlvlei WTP using the plants treatment parameters, even if it is blended with the Voëlvlei WTP raw water. Therefore, the best treatment strategy for the Berg River water at the Voëlvlei WTP would be pre-treatment of the water before entering the Voëlvlei WTP. Although there are various ways of pre-treating the Berg River water, this study has identified the following possible pre-treatment strategies:<ul><li>pre-treatment with ferric sulphate and lime</li><li> pre-treatment with ferric sulphate and lime in conjunction with MIEX® resin</li><li> pre-treatment with MIEX® resin only</li></ul> Further research and investigation would be necessary to determine the best pretreatment strategy in terms of cost and efficiency. The pre-treated Berg River water would have to pass through the Voëlvlei WTP treatment process (i.e. high coagulation pH) to remove any manganese that might be present in the water. It is recommended that more samples should be taken at various points along the Berg River upstream of the Voëlvlei WTP over a longer period of time to compare the quality of water at these points in the river and also to monitor the effect of various run-off sites. Further research and investigation is necessary to determine the optimum treatment parameters for the Berg River water when blended with the Voëlvlei WTP raw water. Other blending ratios, different to those used in this study, should also be investigated. A more in-depth investigation is also necessary to determine the actual capital and operational costs for the pre-treatment of the Berg River water. / Dissertation (MSc)--University of Pretoria, 2011. / Chemical Engineering / unrestricted

The aim of the master thesis was to propose the reconstruction of the water treatment plant. I chose the water treatment plant in Čebín, which I have already describe with in the bachelor thesis. The water treatment plant has problems with increased iron, manganese and ammonium salts. In the first part I devoted myself to the current condition of the water treatment plant and the possibilities of removing the elements from the water. In the next chapter I compiled the equipment of the technological line. To remove iron and manganese, I suggested aeration using an injector, and for the removal of ammonium salts, potassium permanganate is used, which is used to regenerate the filters. A pair of pressure filters helps remove iron and manganese. In the last part of the thesis I described and evaluated the original condition of the water treatment plant. To evaluate the technical condition, I used the TEA Water web application.

Karst rivers are special type of rivers because of their hydrography conditions. They usually flow from non-karst area and as soon as they reach in to the karst area they disappear underground. There, they flow through cavities until they reach the surface again. The aim of this thesis is to assess the impact of water outflow from wastewater treatment plant on karst rivers. The study was done in the central area of CHKO Moravský kras where the impact of two WWTP on a cave system Rudické propadání – Býčí skála is evaluated. As a part of this study a half-year monitoring was carried out, which consisted of water sampling once every two weeks. In total, 13 water samples were taken from 8 sampling points. Also 4 additional one-time samples were taken from the cave system. Moreover, flow rate, temperature, conductivity, oxygen concentration and pH were measured at the sampling point. Afterwards, the content of undissolved solids, CODCr, BOD, N-NH4+, N-NO2-, N-NO3-, P-PO43- and total phosphorus were determined in the samples. The change of parameters in time and during the flow in the river was observed from the measured values. The balance of pollutants in particular parts of the river was calculated. The outflow values from waste water treatment plants were compared to the emission limits for surface waters and the parameters of rivers were compared to the environmental quality standards. According to the results, it can be observed that the water quality improves after passing through the cavities. It was proven that the outflows from the observed waste water treatment plants are negatively influencing the water streams. The most serious problem is the wash up of sludge from WWTP Rudice and its consequent sedimentation in the river and/or outflow to the Rudické propadání.

is Diploma’s thesis is addressing the issues of technical drying, principles and types of technical drying, solar drying possible usefulness of sewage sludge in the Czech Republic, its availability during the season, the legislation related to the processing of sewage sludge and design of pilot scale solar dryer.

The aim of this thesis is to assess the impact of water outflow from wastewater treatment plant on karst rivers. The study was done in the northern area of Moravský kras protected landscape, where the impact of WWTP Ostrov u Macochy on a cave system Lopačské propadání was studied. As a part of this study a half-year monitoring was carried out, which consisted of water sampling every two weeks. In total, 13 water samples were taken from 7 sampling points. Moreover, flow rate, temperature, conductivity, oxygen concentration and pH were measured at the sampling point. Afterwards, the content of undissolved solids, COD, BOD, N-NH4+, N-NO2-, N-NO3-, NKi and total phosphorus were determined in the samples. The change of parameters in time on the sampling points and further along the flow of the river was evaluated from the measured values. The outflow values from waste water treatment plants were compared with the emission limits for surface waters and the values of river water parameters were compared with the environmental quality standards. It wasn’t proven that the outflow from the observed waste water treatment plant is negatively influencing the water stream. The most serious problems are: -The WWTP was designed for treatment of sewage from Ostrov u Macochy, which involved separate sanitary and storm sewers. After finishing the WWTP, a uniform sewer was built. -High concentration of total phosphorus on the outflow from WWTP. -Poor quality of Lopač brook water already before the outflow vent from WWTP.

Avloppsreningsverket i Hallsberg kommun är beläget i direkt anslutning till Hallsberg, med Ralaån som recipient. Tekniken på reningsverket bygger på principerna för en klassisk aktivslamanläggning med mekanisk rening, kemisk rening, biologisk rening och en slambehandling där rötning av primär- och sekundärslam används för utvinning av biogas. Hallsberg ARV har under en längre tid haft problem med kvävereningen. Under senaste åren har man överskridit riktvärdet för kväveutsläpp vid ett flertal tillfällen och under 2009 överskreds även gränsvärdet. Riktvärdet för Hallsberg ARV är i dagsläget satt till 10mg NH4-N/l som medelvärde per månad, gränsvärdet är satt till 10 mg NH4-N/l som medelvärde per kalenderår. Då Hallsberg ARV inte drivs vid full kapacitet antas en minskning av kväveutsläppen vara möjlig att genomföra genom trimning av befintligutrustning och processer på verket. Detta antagande låg till grund för det här examensarbetet som syftar till att optimera kvävereningen på Hallsberg ARV. I optimeringen ingick en teknisk, ekonomisk och miljömässig utvärdering av olika alternativa lösningarna för att förbättra funktionen hos anläggningen. Extra hänsyn togs till energi- och kemikalieåtgång i syfte att få en så effektiv drift av verket som möjligt. Arbetet genomfördes genom en initial litteraturstudie på området, vartefter en provtagningsserie om fyra veckor realiserades på verket. Data som ligger till grund för slutsatserna i projektet har också inhämtats från onlinemätare på verket samt från äldre externt analyserade prover. Efter analys av insamlad data antas orsakerna till Hallsberg ARV:s höga utsläpp av kväve bero på en kombination av flera faktorer: -Vid vår och höst kan brunnsslamintaget vara så stort att bräddning sker ut till verket. Detta leder till att kvävebelastningen höjs så kraftigt att nitrifierarna inte hinner acklimatisera sig och får förhöjda kväveutsläpp till följd. -Mycket kväve följer med slammet från simultanfällningen till rötningen. Detta kan påverka halten kväve i rejektet från rötkamrarna som i sin tur kan leda till störningar i kvävereningen. -Centrifugens rejekt innehåller mycket kväve och körs idag endast under ett par dagar i veckan vilket leder till stora variationer i inkommande kvävehalt. -En hög förfällning av fosfor och organiskt material har bidragit till en låg halt av organiskt material i denitrifikationen. Sammantaget föreslås att vidare studier bör genomföras av ovan nämnda områden för att driften på Hallsberg ARV ska kunna drivas med så låga miljömässiga och ekonomiska kostnader som möjligt. / The waste water treatment plant in Hallsberg municipal is situated adjacent to Hallsberg, with Ralaån as a recipient. The technique at the waste water treatment plant is based on the principles for a classical activated sludge treatment plant and includes mechanical treatment, chemical treatment, biological treatment, and a sludge treatment where the digestion of primary and secondary sludge is used for extraction of biogas. Hallsberg waste water treatment plant has during some time had problems with the nitrogen removal with high nitrogen emissions as a consequence. The target value has been exceeded a couple of times during the last years and in 2009 the limit value was exceeded as well. The target value for Hallsberg waste water treatment plant is 10 mgNH4-N/l as an average value per month, the limit value is set to 10 mg NH4-N/l, as an average value per year. Since the waste water treatment plant in Hallsberg not is operating at full capacity, a lowering of the nitrogen emissions is assumed to be possible though a trimming of the existing equipment and of the processes on the site. This assumption formed the basis for this thesis, designed to optimize the nitrogen removal at the waste water treatment plant in Hallsberg. A technical, economical and environmental evaluation was included in the optimization to improve the function of the plant. Extra evaluations were made in the energy- and chemical consumption in order to streamline the operations at the plant as much as possible. The project was carried out through an initial literature-investigation followed by a four week period of sampling and analyzing at the site. The data that form the conclusion in this project has also been collected through online measurements at the plant as well as through analyses of older samples. After analyzing the collected data, the reasons for the high emissions of nitrogen is thought to be due to a combination of reasons: -During the spring and the autumn the external intake of well sludge can lead to a direct release of sludge in to the plant. The change of nitrogen content will not give enough time for the nitrifying bacteria to acclimatize, with elevated emissions of nitrogen as a consequence. -The usage of simultaneous precipitation could lead to an irregular concentration of nitrogen released to the treatment plant from the digesters. This in turn could contribute to higher nitrogen emissions. -The irregularities of the usage of the centrifuge contribute to nitrogen irregularities and contribute to the difficulties of acclimatization of the nitrifying bacteria. -A high pre-precipitation of phosphorus and organic matter has contributed to a level of organic material in the denitrifikation below what is recommended. To sum up, further investigations are suggested in the above mentioned areas to make the operations at the plant carried trough at the lowest possible environmental and economically cost.

No description available.

Foi pesquisada a aplicação de métodos, em nível de laboratório, através dos quais é possível otimizar, tratar e dispor resíduos de lavagem de filtros de estações de tratamento de água (Caso ETA do rio Descoberto - ETA-RD Brasília). Na clarificação da água de lavagem dos filtros, observou-se o efeito favorável da adição de polímero para melhorar a separação líquido-sólido é, portanto, as eficiências de remoção de turbidez, cor aparente, sólidos suspensos e coliformes totais. Observou-se melhor sedimentabilidade do lodo a ser desaguado. Os ensaios de centrifugação, em escala de bancada, mostraram que o método aplicado auxilia na determinação da dosagem a ser usada numa centrífuga em escala real. Foram avaliados três métodos de disposição do lodo adensado da ETA-RD em ETE: 1) sedimentação com esgoto sanitário e posterior digestão anaeróbia do lodo; 2) Digestão anaeróbia e 3) digestão aeróbia. Os melhores resultados foram obtidos com a digestão anaeróbia. Os estudos realizados mostraram que há diversas alternativas de tratamento e disposição desses resíduos, mas é necessário, sempre que possível, a avaliação das diferentes alternativas para selecionar a(s) mais apropriada(s) a cada caso em particular, pois fatores como custos e disponibilidade de de sistemas ou equipamentos, definirão a aplicabilidade ou não de determinado método. / It was researched the application of methods on laboratory bench scale to optimize the reuse, treatment and disposal of wastes from filter backwash of Water Treatment Plant - WTP (WTP-RD Descoberto River, Brasília case). In the clarification process of this waste, favorable effect of addition of polymer for best liquid-solid separation and, thus, better removal efficiencies of turbidity, apparent color, suspended solids and total coliforms was observed. Better sedimentability of the sludge occurred. The centrifugation tests showed that the applied method help on determination of dosagem to be used in full scale. Three methods to dispose thickened sludge of WTP-RD on wastewater treatment Plants - WWTP were evaluated: 1) Sedimentation with domestic sewage and anaerobic digestion of sludge; 2) Anaerobic digestion and 3) Aerobic digestion. Best results were obtained with anaerobic digestion. The results showed that there are alternatives of treatment and disposal of wastes of WTP, but is necessary, if possible, to make the evaluation of this alternatives to select the most appropriate(s) in each case because factors as costs, systems or equipments availability, will define the applicability or not of a particular method.

Foi pesquisada a aplicação de métodos, em nível de laboratório, através dos quais é possível otimizar, tratar e dispor resíduos de lavagem de filtros de estações de tratamento de água (Caso ETA do rio Descoberto - ETA-RD Brasília). Na clarificação da água de lavagem dos filtros, observou-se o efeito favorável da adição de polímero para melhorar a separação líquido-sólido é, portanto, as eficiências de remoção de turbidez, cor aparente, sólidos suspensos e coliformes totais. Observou-se melhor sedimentabilidade do lodo a ser desaguado. Os ensaios de centrifugação, em escala de bancada, mostraram que o método aplicado auxilia na determinação da dosagem a ser usada numa centrífuga em escala real. Foram avaliados três métodos de disposição do lodo adensado da ETA-RD em ETE: 1) sedimentação com esgoto sanitário e posterior digestão anaeróbia do lodo; 2) Digestão anaeróbia e 3) digestão aeróbia. Os melhores resultados foram obtidos com a digestão anaeróbia. Os estudos realizados mostraram que há diversas alternativas de tratamento e disposição desses resíduos, mas é necessário, sempre que possível, a avaliação das diferentes alternativas para selecionar a(s) mais apropriada(s) a cada caso em particular, pois fatores como custos e disponibilidade de de sistemas ou equipamentos, definirão a aplicabilidade ou não de determinado método. / It was researched the application of methods on laboratory bench scale to optimize the reuse, treatment and disposal of wastes from filter backwash of Water Treatment Plant - WTP (WTP-RD Descoberto River, Brasília case). In the clarification process of this waste, favorable effect of addition of polymer for best liquid-solid separation and, thus, better removal efficiencies of turbidity, apparent color, suspended solids and total coliforms was observed. Better sedimentability of the sludge occurred. The centrifugation tests showed that the applied method help on determination of dosagem to be used in full scale. Three methods to dispose thickened sludge of WTP-RD on wastewater treatment Plants - WWTP were evaluated: 1) Sedimentation with domestic sewage and anaerobic digestion of sludge; 2) Anaerobic digestion and 3) Aerobic digestion. Best results were obtained with anaerobic digestion. The results showed that there are alternatives of treatment and disposal of wastes of WTP, but is necessary, if possible, to make the evaluation of this alternatives to select the most appropriate(s) in each case because factors as costs, systems or equipments availability, will define the applicability or not of a particular method.