Interest in the chemical constitution of montan wax began with the work of Von Boyen, who in 1901 showed montanic acid to be a constituent of the wax. In the years that followed the literature has been rich with respect to investigations of montan wax. Most of the literature concerns itself with the technology of the wax, its uses, methods of refining and purification. Much has also been written on its chemical make-up. It was the purpose of this research to explore the possibility of forming urea adducts of the normal components of montan wax, and to investigate the properties of the adducts and the waxes regenerated from the decomposed adducts.

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Call number: LD2668 .T4 1955 H78 / Master of Science

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Thesis (Ph. D.)--University of Michigan, 1936. / "Reprinted from the Journal of the American chemical society, 58 ... (1936)."

Thesis (Ph. D.)--University of Wisconsin--Madison, 1959. / Typescript. Vita. eContent provider-neutral record in process. Description based on print version record. Includes bibliographies: leaves 56, 78.

From Introduction: Wax and wax-like substances have been defined in many ways. One reasonably extensive definition, by Hatt and Lamberton (1956) is given below: "The term "wax" seems best used to denote a group of substances which qualitatively have certain physical properties in common. These properties are familiar ones, for in almost all countries some natural wax - beeswax, Japan wax, Chinese insect wax, the carnauba and candelilla waxes of the Americas - has been an important material in art and industry from prehistoric times. Waxes are understood to be opaque or translucent solids, which melt without decomposition to form mobile liquids at temperatures in the region of 100⁰C. They differ in hardness, but are all essentially soft substances with poor mechanical strength. Most waxes can be easily shaped or kneaded at a little above ambient temperatures. In fact, the term could easily have been made to cover the whole class now named thermoplastics." Pure n-paraffins would be too crystalline and brittle for use as waxes, whereas mixtures of n-paraffins have some valuable properties. The molecules bear such close resemblance to one another that they form mixed crystals of lowered crystallinity and the melting point is a function of the mean molecular weight. This is a desirable feature for it permits crystallinity and brittleness to be reduced without a marked loss in the melting point or hardness. It also allows a mixture to simulate a pure compound very closely. Waxes, in general, have been put to a large number of uses. They are used, for example, in candles, polishes, paper-coating, plastics, printing, matches, rust protectants and insulation. Each application requires its own appropriate range of wax properties.