Pothole wetlands are ubiquitous throughout the Prairie Pothole Region and since 1900, 40-70% of potholes in the region have been drained to increase agricultural production. This thesis describes factors influencing spatial and temporal variations in wetland water quality and characteristics of drainage water. Research was conducted at Smith Creek watershed, southeastern Saskatchewan, where there has been controversy over recent renewed efforts to drain wetlands. Following snowmelt in 2009, 67 wetlands were sampled to determine whether spatial variations in wetland water quality were attributable to land cover, permanence classes, and surface drainage characteristics. Wetlands with cropped uplands had greater TP and K than wetlands with wooded and grassed uplands; TP, TDN, and DOC were higher in seasonally than permanently ponded wetlands; and salts were lower in wetlands with wooded uplands compared to wetlands with cropped and grassed uplands. Measurements of water quality of one permanently ponded wetland over a 20 week period in 2008 showed that the wetland acted as a solute trap. Variations in salts and DOC were influenced by hydrological processes such as runoff, evaporation, and shallow groundwater seepage, whereas variations in nitrogen, phosphorus, and bacteria were influenced by biotic, sorption, and hydrological processes. The experimental drainage of this wetland in November 2009 demonstrated that its water quality was an important control of drainage water quality. Further, the wetland ditch acted as a simple conduit, i.e., little solutes loss or gain occurred along it. In spring 2009, water quality along seven ditches and five natural connections that form between wetlands (termed spills) was compared. Concentrations of most solutes were similar, except TDN, DOC, HCO₃^-, K⁺, and Ca²⁺ that were higher in ditches than spills. Minimal changes in water quality along ditches and spills occurred, likely due to the low temperatures occurring in spring that restrict biotic processing and sorption. Notably, because ditches connect wetlands to streams, as opposed to spills that connect adjacent wetlands, ditches have a greater potential to contribute to downstream solute loading. Wetland drainage efficiency and wetland water quality were deemed the factors critical to determining solute exports via ditches. Results of wetland water quality and drainage characteristics can be useful to future modeling exercises and could be used to inform wetland drainage practices and policies.

Identifying the ecological mechanisms that determine food web structure is critical for understanding the causes and consequences of diversity. The objective of this thesis was to identify the mechanisms structuring aquatic food webs across environmental gradients from a multi-level perspective (individual to ecosystem) using integrative methodology and field experiments to test classic ecological theory. My results demonstrate support for the dynamic constraints hypothesis, which predicts habitats with greater disturbance should have shorter food chains, but are not consistent with the ecosystem size hypothesis that predicts larger ecosystems have longer food chains. Insect and amphibian richness increased with increasing pond size and hydroperiod, indicating that insertion of new consumers into pond communities was driving variation in food-chain length. A multivariate analysis testing the influence of physicochemical variables on food-web characteristics revealed that hydroperiod and pond area had a strong influence on amphibian and invertebrate assemblages, trophic diversity and 15N range. Food-chain length did not respond strongly to any one variable, but instead responded weakly to multiple environmental variables, suggesting interacting influences on food-web structure. Conversely, the trophic niche of amphibian larvae was not influenced by pond hydroperiod, but did exhibit ontogenetic diet shifts. Populations of amphibian larvae with broader niche widths also had increased individual variation, supporting the niche variation hypothesis. In addition, I assessed whether species diversity influenced the magnitude of cross-habitat resource flow between aquatic and terrestrial habitats via emerging aquatic insects, metamorphosing amphibians, and litter deposition. Deposition into ponds far exceeded carbon exported via insect and amphibian emergences. We found a negative relationship between resource flux and the diversity of amphibians and insects, which contradicts the general pattern of positive biodiversity-ecosystem function relationships. My research strongly suggests environmental variation is a key process in shaping food-web structure and function and that multiple methodologies are needed to understand temporal and spatial dynamics of aquatic ecosystems.

Mercury is an environmental contaminant of global concern. The distribution of mercury in freshwater systems is poorly characterized in Mexico, despite widespread contamination from industrial and urban effluents. The land use, geology, and hydrology of the Lake Zapotlán basin, Mexico are conducive to the delivery of elevated mercury in water to the lake due to untreated wastewater discharge, deforestation, and local volcanic history. To assess a mercury exposure risk to fish consumers, the concentrations of total Hg (THg) in water inputs, surface waters, sediments, and the commercial catch of tilapia and carp were investigated. Results indicate that despite high particle-bound inputs of THg to the lake in runoff and wastewater, THg in sediments and surface waters were low. Dense Typha latifolia dominated wetlands are believed to retain THg inflow from water inputs. Concentrations of THg in tilapia and carp were low, suggesting low mercury bioavailability in this system.

Public recognition of the value of wetlands has risen quickly over the past 25 years and numerous policies and programs have been developed to address threats to the quantity and quality of wetlands. However, management of wetland resources located on private land often involves a perceived conflict between social and private interests since landowners usually cannot benefit economically from keeping wetlands on site unless they convert them to alternative uses such as agricultural crops. In order to avoid further degradation and ensure the various environmental benefits wetlands provide, there is a need for government intervention by delivering effective policies. This will be realized through an effective economic valuation process for wetland benefits.<p> This thesis investigates wetland and riparian zones management, with greater emphasis placed on the Prairie Pothole Region (PPR) of Saskatchewan where the majority of the land is privately owned. Using data from a survey of landowners, the perceived cost of conserving wetland and associated riparian zones is quantified through their willingness to accept (WTA) compensation for a proposed 10-year economic incentive-based program. In addition, the role of landowner and farm characteristics on this perceived cost of conservation has also been assessed. As indicated by the results from two probit models that were developed, per acre payment has a significant positive effect on the probability a landowner will accept the program offer; the average payment respondents required being $32.58/acre. Other factors such as the landowners previous experience dealing with the wetland, personal preferences correlated with economic benefits and landowners who have an heir to take over the farm are also found to have significant impact on their participation decision. For those respondents who did not complete the WTA question, past relative experience, knowledge about wetlands, age, and the agricultural region the farm is located are revealed to be factors that affect to the provision of an explicit answer.

Mercury is an environmental contaminant of global concern. The distribution of mercury in freshwater systems is poorly characterized in Mexico, despite widespread contamination from industrial and urban effluents. The land use, geology, and hydrology of the Lake Zapotlán basin, Mexico are conducive to the delivery of elevated mercury in water to the lake due to untreated wastewater discharge, deforestation, and local volcanic history. To assess a mercury exposure risk to fish consumers, the concentrations of total Hg (THg) in water inputs, surface waters, sediments, and the commercial catch of tilapia and carp were investigated. Results indicate that despite high particle-bound inputs of THg to the lake in runoff and wastewater, THg in sediments and surface waters were low. Dense Typha latifolia dominated wetlands are believed to retain THg inflow from water inputs. Concentrations of THg in tilapia and carp were low, suggesting low mercury bioavailability in this system.

Hurricanes are one of the primary threats to the Texas coastal environment and economy. They generate large wave and storm surges that have caused much damage on the Texas coast in the past. Understanding both the hydrodynamic processes that damage coastal habitats and hurricane hazard and risk are critical to preserve coastal vegetation and quantify its benefits to coastal storm protection. The goal of this project is to quantify the impact of wave attenuation and wave refraction as well as the development of coherent structures in marsh fringes and the formation of a rip current system over wetlands on storm protection. The 3D Shallow Water Wave Basin at Texas A&M University hosted a series of large-scale experiments considering an idealized wetland model to pursue this goal. Study of the marsh geometry of the Texas coast was done in order to scale the experiments to the size of the Haynes Laboratory 3D-Water Wave Basin using a Froude and a Reynolds scalings. Particularly, averaged size and idealized shape of marsh segments in the area of Dalehite Cove in Galveston Bay were considered. Three sets of different wave conditions and water levels were tested to approximate different intensities of storm surge. Identical tests with both vegetated and non-vegetated marshes were run to compare the influence of the vegetation in storm conditions, and three different spacings between marsh segments were tested. In the basin, normally incident regular waves were generated at three water circulation structures. Data analysis allows the determination of the impact of discontinuous marsh segments on wave attenuation and wave refraction. Coherent structures such as rip current and the circulation pattern were analyzed to study the change in the flow field during passage of the waves. The experimental measurements were able to describe the wave transformations over the marsh segments. The influence of coastal wetlands was identified to affect the hydrodynamic process and reduce the total wave energy which is dissipated and redistributed by vegetation. The presence of the mounds induced an important decrease in the wave height, in addition to the damping of the waves by the vegetation stems. The variation in spatial coverage of the wetland model has been shown to highly affect the flow dynamics by generating offshore directed flow in the channel and onshore directed flow on the marsh mounds. This experimental approach provides a further understanding of flow dynamics by waves and surge in wetlands, at a large scale.

Reconciling human landscapes with wildlife needs can demand innovative solutions. Enhancing wildlife conservation in agricultural landscapes requires habitat restoration; returning marginal farmlands to wetlands in a way that remains productive for farmers can aid existing strategies. This study develops and explores the feasibility of an ecological design to rehabilitate wet, poor quality farmland into a wetland that can serve as wildlife habitat while producing a crop. Research targets methods of biophysical site restoration that are feasible for farmers to initiate; identification of temperate wetland crops with potential to meet economic and ecological criteria; and parameters for meeting farmers' needs in terms of management and desirability. Scientific literature on wetland and restoration ecology is examined and integrated with agricultural studies and interview responses from landowners involved in alternative food production. Primary data collection for design development centers on coastal British Columbia, where competing land uses have degraded many former wetlands while the region's fertile soils support prolific, diversified farming. Qualitative, semi-structured interviews with key informants involved in local food production were conducted as part of a participative research process in order to get input and feedback throughout design development. A case study site was chosen in a seasonally flooded agricultural watershed outside of Duncan, B. C. A design is proposed that combines five habitat types with a naturalized cropping system. Major findings include the potential use of many wild and native plants as crops, as a way to provide sufficient economic returns and maintain ecological sustainability. Current opportunities for wetland agriculture include niche marketing, added value products, agrotourism, and increasing sales through farm reputation. Possible deterrents include product marketing, and the unfamiliarity of the plants from a farming perspective, where levels of acceptable damage imposed by fluctuating water conditions, weed competition, and herbivory are undetermined. Participant response was positive overall with regards to the design and preliminary results indicate that such a system could be feasible. Public interest and technical ability to create an agricultural wetland exist; developing creative marketing for such products in North America appears to be the primary challenge. The design is thus proposed as a long-term study to minimize risk for interested landowners. Redesigning human landscapes to include wild species is an important step towards a more sustainable society.

A boreal forest wetland (L979) was flooded in 1993 at the Experimental Lakes Area, Ontario to imitate a hydroelectric reservoir and to study the effects of flooding on greenhouse gas production and emission. Flooding initially caused CO&#8322; and CH4 emission rates to increase and changed the wetland from a small, natural carbon sink to a large source of carbon. The increased production of greenhouse gases in the peatland also caused the majority of the peat to float to the surface creating floating peat islands, within 4 years of flooding. The floating peat islands are a larger source than the central pond of CH4 to the atmosphere due to the high water table and small oxidation zone as compared to the earlier undisturbed peatland. The floating peat islands had an average flux of 202 ± 66 mg C-CH4/m²/day comparable to rates measured in 1995. Methane flux rates are spatially and temporally variable ranging from ?117 to 3430 mg C-CH4/m²/day. The variability is partly due to episodic releases of gas bubbles and changes in overlying pressure from the water table. The development of floating peat islands created an underlying water pocket. The water pocket increased water movement between the central pond and the peatland and led to increased peat temperatures and methane oxidation, and removal of debris from the water pocket. DIC, CH4, and O&#8322; concentrations, and &#948;13C-DIC, &#948;13-CH4, and &#948;18O-O&#8322; values in the water pocket were similar to values in the central pond. Before flooding, the &#948;13C-CH4 values from the peatland ranged between ?36 and ?72? indicating that about 65 to 90% of the methane was oxidized before flooding. After flooding, the median &#948;13C-CH4 value from the floating peat islands was ?52? indicating that about 30% of the methane was oxidized before it was emitted to the atmosphere. Since the floating islands are now vegetated, photosynthesis and transport via plants allow the movement of oxygen into the peat islands Methane oxidation in the central pond was similar in 2001 and 2002. DIC and CH4 isotope mass budgets from June 3 to September 23, 2002 indicate that inputs were smaller than outputs at L979. Calculated net DIC and CH4 production in the central pond was 8490 and 432 kg C, with &#948;13C-DIC of -18. 5 ? and &#948;13C-CH4 of -32. 5?. Decomposition of peat was the source of DIC and CH4. O&#8322; saturation levels indicate that the pond is always undersaturated and that respiration dominates the system; however, the &#948;18O-O&#8322; also indicates that photosynthesis is an important process in the central pond of L979. The peat islands contributed about 90% of the total CH4 flux, whereas the open water areas contributed 10%. This indicates that formation of peat islands in a hydroelectric area can significantly affect the greenhouse gas emissions to the atmosphere. The average flux of CH4 from the entire wetland in 2002 was 202 ± 77 mg C-CH4/m²/day, equivalent to 44 ± 17 g C-CH4/m²/year (year = 220 days). This is higher than preflood values of 0. 5 g C-CH4/m²/year in 1992, and the early post-flood value of 8. 9 g C-CH4/m²/year in 1993/1994. The wetland continues to emit methane after ten years of flooding at higher than preflood rates.

Dissolved oxygen (DO) is one of the most important environmental factors necessary to sustain aquatic life. The Southern Grand River is characterized with extensive marshes. This study focuses on the Dunnville Marsh in the Southern Grand River. The spatial and temporal variation in dissolved oxygen was studied in the Dunnville Marsh and the Grand River over a one year cycle during 2007 to 2008. Dunnville Marsh exhibited little influence on the oxygen regime of the river. The Grand River; however, could influence the oxygen regime in the marsh during the spring when waters are high but exerts little influence during the rest of the year. There were no great differences in DO between the wetland and the river during the high water spring melt period; however notable differences occurred in the summer and fall. Oxygen stable isotopes and diel O2 measurements showed that ecological factors probably were influencing the DO cycle in Dunnville Marsh, whereas both ecological and weather factors influenced the cycle in the Grand River. Monthly δ18O-DO data from the river revealed a shift towards atmospheric equilibrium compared to the wetland. These data exhibited less photosynthetic activity in the fall and more photosynthetic activity during the summer. The wetland showed higher photosynthetic activities in the summer than the river. Nitrogen input from the agricultural areas was low at most of the time and had minimal influence on the DO in the Dunnville Marsh. Despite low nitrogen input the attenuation ability of the Dunnville Marsh was apparent, presumably due to plant uptake, especially in the northern part of the marsh. Based on the δ18O-water signature in late April (after the flood season) it appears river water extended about two-thirds along the main stream well into Dunnville Marsh. River water, probably inundates a significant part of the Dunnville Marsh in early April (flood peak), when water flow was more than 10 fold higher than later in April following the peak flood season. River water can be intruded into the marsh and brought the DO to similar saturations as in the river in spring.

The boreal landscape is complex mosaic of vast forests, lakes and wetlands. Through the landscape flows a fine network of streams and rivers, carrying dissolved and suspended material from atmospheric deposition and weathering of soils and bedrock to downstream recipients. This thesis investigates the transport of U, Th and other metals in the boreal landscape by comparing a set of catchments with contrasting characteristics, ranging from 0.12-68 km2 in area. Using uranium (234U/238U) and oxygen isotopes (δ18O) it was demonstrated that catchment size has a strong impact on the hydrological pathways and on the mobilisation of uranium. Both tracers also displayed a consistent shift towards more superficial sources and more superficial flow pathways when going from winter baseflow conditions to the spring flood. Large spatiotemporal variability was observed with U fluxes ranging from 1.7 -30 g km-2 a-1. Using a wide set of hydrochemical parameters and landscape characteristics it was demonstrated that wetlands play a decisive role for the biogeochemical cycling of many metals. Comparing normalised fluxes of 13 different elements (Al, Ba, Ca, Cr, Cu, La, Mg, Na, Ni, Si, Sr, U and Y) 73% of the spatial variance could be explained based on the wetland coverage and the affinity for organic matter, the latter of which was quantified using thermodynamic modelling. Hence, it was possible to link the large-scale transport patterns of a wide range of metals to fundamental biogeochemical properties. When restraining the analysis to the smaller streams (&lt;10 km2), the explanatory power increased to 88%. For elements such as Na and Si with low affinity for organic matter the decrease in wetland-dominated catchments corresponded closely to the area of mineral soils that had been replaced by peat, indicating that reduced weathering was the main cause of the decrease. For organophilic metals the decrease in wetland-dominated catchments was even greater, suggesting that there also was an accumulation of these metals in the peat. This was confirmed by investigating the distribution of radionuclides in local mire, which revealed considerable accumulation of uranium and thorium along the edges of the mire. Based on the inventories of uranium and thorium and their distribution in the peat it was concluded that the mire historically had been a sink for these metals and that it most likely will continue to be so for a long time to come. All and all, wetlands were estimated to decrease the fluxes of metals from the boreal forests to downstream lakes and oceans by 20-40%, depending on how strongly they bind to organic matter.