This thesis extends our fundamental knowledge in the area of high oxidation state chemistry of xenon trioxide, XeO3. Oxygen coordination to the Xe(VI) atom of XeO3 was observed in its adducts with triphenylphosphine oxide, [(C6H5)3PO]2XeO3, dimethylsulfoxide, [(CH3)2SO]3(XeO3)2, pyridine-N-oxide, (C5H5NO)3(XeO3)2, and acetone, [(CH3)2CO]3XeO3. The crystalline adducts were characterized by low-temperature single-crystal X-ray diffraction and Raman spectroscopy. Unlike solid XeO3, which detonates when mechanically or thermally shocked, the solid [(C6H5)3PO]2XeO3, [(CH3)2SO]3(XeO3)2, and (C5H5NO)3(XeO3)2 adducts are insensitive to mechanical shock, but undergo deflagration when exposed to a flame. Both [(C6H5)3PO]2XeO3 and (C5H5NO)3(XeO3)2 are air-stable at room temperature. The xenon coordination sphere in [(C6H5)3PO]2XeO3 is a distorted square pyramid and provides the first example of a five-coordinate Xe center in a XeO3 adduct. The xenon coordination sphere of the remaining adducts are distorted octahedral comprised of three equivalent Xe---O secondary contacts that are approximately trans to the primary Xe–O bonds of XeO3. Hirshfeld surfaces of XeO3 and (C6H5)3PO in [(C6H5)3PO]2XeO3 show the adduct is well-isolated in its crystal structure and provide a visual representation of the secondary Xe---O bonding in this adduct. Crown ethers have been known for over 50 years, but no example of a complex between a noble-gas compound and a crown ether or another polydentate ligand had been reported. Xenon trioxide is shown to react with 15-crown-5 to form the kinetically stable (CH2CH2O)5XeO3 adduct which, in marked contrast with solid XeO3, does not detonate when mechanically shocked. The crystal structure shows that the five oxygen atoms of the crown ether are coordinated to the xenon atom of XeO3. The gas-phase Wiberg bond valences and indices and empirical bond valences indicate the Xe---Ocrown bonds are predominantly electrostatic, σ-hole, bonds. Mappings of the electrostatic potential (EP) onto the Hirshfeld surfaces of XeO3 and 15-crown-5 in (CH2CH2O)5XeO3 and a detailed examination of the molecular electrostatic potential surface (MEPS) of XeO3 and (CH2CH2O)5 reveal regions of negative EP on the oxygen atoms of (CH2CH2O)5 and regions of high positive EP on the xenon atom that are also consistent with σ-hole bonding. Reactions of crown ethers with HF acidified aqueous solutions of XeO3 at room-temperature yielded adducts of 12-crown-4, (CH2CH2O)4XeO3, and 18-crown-6, [(CH2CH2O)6XeO3∙2H2O]2∙HF, whereas slow cooling of a solution of XeO3 with 18-crown-6 in acetone yielded (CH2CH2O)6XeO3∙2H2O. The adducts (CH2CH2O)4XeO3 and (CH2CH2O)6XeO3∙2H2O are shock-insensitive whereas the former adduct is air-stable at room temperature. The low-temperature, single-crystal X-ray structures show the Xe atom of XeO3 coordinated to the oxygen atoms of the crown ether ring. Uncharacteristic xenon coordination numbers exceeding six (including the three primary bonds of XeO3) were observed for all crown ether adducts. Raman spectroscopy frequency shifts are consistent with complex formation and provided evidence for the 2,2,1-cryptand adduct of XeO3. Gas-phase Wiberg bond valences and indices and empirical solid-state bond valences confirmed the electrostatic nature of the Xe---O bonding interactions. Comparisons between the XeO3 and SbF3 18-crown-6, 15-crown-5, and 12-crown-4 complexes are made. Incorporation of xenon trioxide, XeO3, into inorganic polyatomic salts under ambient conditions has been observed in several mixed xenate salts; K[XeO3XO3] (X = Cl, Br), K2[XeO3SeO4]∙HF, K[(XeO3)nZO3] (Z = I, N), and M2[(XeO3)nCO3]∙xH2O (M = Na, K, Rb, Ba). Raman spectroscopy was used to identify the aforementioned compounds and K[XeO3ClO3], K[XeO3BrO3], K2[XeO3SeO4]∙HF, and Rb2[(XeO3)2CO3]∙2H2O were also characterized by low-temperature, single-crystal X-ray diffraction. The xenon atom of XeO3 is seven coordinate in K[XeO3ClO3] and six coordinate in all other compounds with Xe---O distances that are significantly less than the sum of the Xe and O van der Waals radii. These salts provide examples of XeO3 coordinated to inorganic compounds and may provide insights into the inclusion of xenon oxides in minerals. / Thesis / Master of Science (MSc)

Traditional 1H lung imaging using MRI faces numerous challenges and difficulties due to low proton density and air-tissue susceptibility artifacts. New imaging techniques using inhaled xenon gas can overcome these challenges at the cost of lower signal to noise ratio. The signal to noise ratio determines reconstructed image quality and is an essential parameter in ensuring reliable results in MR imaging. The traditional RF surface coils used in MR imaging exhibit an inhomogeneous field, leading to reduced image quality. For the last few decades, fractal-shaped antennas have been used to optimize the performance of antennas for radiofrequency systems. Although widely used in radiofrequency identification systems, mobile phones, and other applications, fractal designs have yet to be fully researched in the MRI application space. The use of fractal geometries for RF coils may prove to be fruitful and thus prompts an investiga- tion as the main goal of this thesis. Preliminary simulation results and experimental validation results show that RF coils created using the Gosper and pentaflake offer improved signal to noise ratio and exhibit a more homogeneous field than that of a traditional circular surface coil. / Thesis / Master of Applied Science (MASc)

No description available.

Astrophysical observations give convincing evidence for a vast non-baryonic component, the so-called dark matter, accounting for over 20% of the overall content of our Universe. Direct dark matter search experiments explore the possibility of interactions of these dark matter particles with ordinary baryonic matter via elastic scattering resulting in single nuclear recoils. The ZEPLIN-III detector operated on the basis of a dualphase (liquid/gas) xenon target, recording events in two separate response channels { scintillation and ionisation. These allow discrimination between electron recoils (from background radiation) and the signal expected from Weakly Interacting Massive Particle (WIMP) elastic scatters. Following a productive first exposure, the detector was upgraded with a new array of ultra-low background photomultiplier tubes, reducing the electron recoil background by over an order of magnitude. A second major upgrade to the detector was the incorporation of a tonne-scale active veto detector system, surrounding the WIMP target. Calibration and science data taken in coincidence with ZEPLIN-III showed rejection of up to 30% of the dominant electron recoil background and over 60% of neutron induced nuclear recoils. Data taking for the second science run finished in May 2011 with a total accrued raw fiducial exposure of 1,344 kg days. With this extensive data set, from over 300 days of run time, a limit on the spin-independent WIMP-nucleon cross-section of 4.8 10-8 pb near 50 GeV/c2 WIMP mass with 90% confidence was set. This result combined with the first science run of ZEPLIN-III excludes the scalar cross-section above 3.9 10-8 pb. Studying the background data taken by the veto detector allowed a calculation of the neutron yield induced by high energy cosmic-ray muons in lead of (5.8 0.2) 10-3 neutrons/muon/(g/cm2) for a mean muon energy of 260 GeV. Measurements of this kind are of great importance for large scale direct dark matter search experiments and future rare event searches in general. Finally, this work includes a comprehensive measurement of the energy dependent quenching factor for low energy nuclear recoils in a plastic scintillator, such as from the ZEPLIN-III veto detector, increasing accuracy for future simulation packages featuring large scale plastic scintillator detector systems.

Inert gases in metals can occur due to ion implantation, from a plasma in a magnetron device or as a result of being by-products of nuclear reactions. Mainly because of the nuclear applications, the properties of the inert gases, helium, argon and xenon in the body centred cubic (bcc) iron crystal are examined theoretically using a combination of molecular dynamics, static energy minimisation and long time scale techniques using empirical potential functions. The same techniques are also used to investigate argon and xenon in aluminium. The primary interest of the work occurred because of He produced in nuclear fission and its effect on the structural materials of a fission reactor. This structure is modelled with perfectly crystalline bcc Fe. In bcc iron, helium is shown to diffuse rapidly forming small bubbles over picosecond time scales, which reach a certain optimum size. In the initial phase of He accumulation, Fe interstitials are ejected. This occurs instantaneously for bubbles containing 5 He atoms and as the more He accumulates, more Fe interstitials are ejected. The most energetically favourable He to vacancy ratios at 0 K, vary from 1 : 1 for 5 vacancies up to about 4 : 1 for larger numbers of vacancies. An existing He bubble can be enlarged by a nearby collision cascade through the ejection of Fe interstitials, allowing more He to be trapped. Ar and Xe in bcc Fe prefer to be substitutional rather than interstitial and there are large barriers to be overcome for the inert gas atoms to diffuse from a substitutional site. Bubbles that form can again be enlarged by the presence of a nearby collision cascade or at very high temperatures. In this case the most energetically favourable vacancy ratios in the bubbles is 1: 1 for Ar and from 0.6: 1 to 0.8: 1 for Xe. For Ar and Xe, bubble formation is more likely as a direct result of radiation or radiation enhanced diffusion rather than diffusion from a substitutional site. Ar in aluminium is also studied. Ar atoms in fcc Al prefer to be substitutional rather than interstitial and evolution into substitutional occurs over picosecond time scales at room temperature. Bubble formation can occur more easily than in bcc iron, mainly because the barriers for vacancy diffusion are much lower but the time scales for bubble accumulation are much longer than those for He. A vacancy assisted mechanism is found which allows Ar to diffuse through the lattice. Finally some preliminary results on the energetics of different geometrical structures of larger Xe bubbles in Al are investigated since experiment has indicated that these can become facetted.

Thesis (Ph. D.)--University of Missouri-Columbia, 1997. / Typescript. Vita. Includes bibliographical references (leaves 197-202). Also available on the Internet.

Thesis (Ph. D.)--University of Missouri-Columbia, 1997. / Typescript. Vita. Includes bibliographical references (leaves 197-202). Also available on the Internet.

The hunt for Dark Matter plays a truly critical role in contemporary physics. At both the largest and smallest scales, deep questions are being raised about the fundamental nature of the universe - questions that confirmation and then characterisation of particle dark matter will provide many answers to. This thesis presents some of the world's most sensitive searches to date for certain types of axion dark matter, axion-like particles, and two-neutrino double electron capture. These have been conducted using the Large Underground Xenon (LUX) experiment. Evidence for dark matter and physics beyond the Standard Model of particle physics is described in Chapter 1, while Chapter 2 gives an overview of proposed candidates for particle dark matter. The various experimental approaches being used to detect particle dark matter are presented in Chapter 3. Direct detection with time projection chambers plays a major role in this thesis, with particular interest in the LUX detector, that is described in its components and operations. Chapter 4 presents LUX direct searches for weakly interacting massive particles. Although I have contributed to these analyses, they are included for completeness only, as they are not part of my central work. The LUX collaboration's searches for axion dark matter and axion-like particle have delivered world-leading results on the axion-electron coupling constant. These results, that I personally led and which have been published in Physics Review Letters, are presented in Chapter 5, along with sensitivity studies, also led by me, made for the future LUX-ZEPLIN experiment. Finally, a search for two-neutrino double electron capture of 124Xe, that I performed using LUX data to extract a limit on the half life of the process, is presented in Chapter 6. Although being allowed by the Standard Model, two-neutrino double electron capture shares the matrix element calculation framework with the neutrinoless channel of the same process, becoming of great interest in the scope of neutrino physics. Conclusions follow and close the thesis.

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