Effective treatment of carbon fiber components to improve delamination resistance is vital to the application of such materials since delamination is one of the biggest concerns regarding the use of composites in the aerospace sector. Due to the significant application benefit gained from increased stiffness to density ratio with composite materials, innovative developments resulting in improved through-thickness strength have been on the rise. The inherent anisotropy of composite materials results in an added difficulty in designing structural elements that make use of such materials. Proposed techniques to improve the through-thickness strength of laminar composites are many and varied; however all share the common goal of improving inter-laminar bond strength. This research makes use of novel materials in the field of wet flocking and Z-pinning. Cellulose nanofibers (CNFs) have already demonstrated excellent mechanical properties in terms of stiffness and strength, originating at the nano-scale. These materials were introduced into the laminate while in a sol-gel suspension in an effort to improve load transfer between laminate layers. The effect of CNFs as lightweight renewable reinforcement for CFRPs will be investigated. Carbon nanotube (CNT) additives were also considered for their beneficial structural properties. / Master of Science

Z-pinning is a through-thickness reinforcement technology for polymer composite materials that has been developed and commercialised over the past fifteen years. The through-thickness reinforcement of composites with thin metallic or fibrous pins aids in suppressing delamination, improving impact damage tolerance and increasing joint strength. Z-pins are applied to the composite part during its manufacture. Pins are embedded within sheets of foam and placed over the unconsolidated part. Subsequently, the foam is compacted and the pins transferred into the part, which is usually an uncured prepreg. In this manner, large numbers of pins can be inserted quickly and easily. The pinned composite is then cured using conventional processes. The use of z-pins is currently limited to several high performance composite structures, most notably Formula One racing cars and F/A-18 E/F (Superhornet) fighter aircraft, although the technology has potential applications in a d iverse variety of aerospace and non-aerospace composite structures. A limited understanding of the mechanical performance of z-pinned parts under high load and fatigue loading conditions currently hinders the application of z-pinned composites. The aim of this PhD project is to investigate the mechanical properties, strengthening mechanics and failure mechanisms of z-pinned carbon/epoxy laminates and joints. The effect of z-pin reinforcement on the tensile and flexural properties of laminates under monotonic and fatigue loading is studied. The sensitivity of these properties to the volume content and diameter of the z-pins is systematically studied by experimentation and analytical modelling. This PhD also evaluates the efficacy of z-pins in improving the load-bearing properties of carbon/epoxy lap joints. Improvements to the room temperature and elevated temperature properties of z-pinned lap joints under monotonic and fatigue tensile loading were determined. The effect of strain rate on the load-bearing properties of z-pinned lap joints was also evaluated. A further aim of the PhD project was to assess the z-pin manufacturing process and the microstructural damage caused by that process. The outcome of this study augments the analysis of the me chanical properties of z-pinned laminates and joints.