Spelling suggestions: "subject:"zinc -- bsynthesis."" "subject:"zinc -- bioynthesis.""
1 |
Measurement of cross sections for 65Cu([alpha],p) 68Zn nuclear reaction at low energy with comparison to Hauser-Feshbach statistical model / Measurement of cross sections for 65copper([alpha],p) 68zinc nuclear reaction at low energy with comparison to Hauser-Feshbach statistical modelDeboer, Richard J. January 2005 (has links)
Where did the elements come from? Why are they found in the abundance that they are? These are two of the fundamental questions that the field of astrophysics has sought to answer. The first major studies of elemental synthesis were done in the 1950's and 1960's. Most notable among them was the Burbidge, Burbidge, Fowler, and Hoyle paper [Clayton 73]. This paper set forth the general theory of elemental synthesis in stars and supernovae by means of nuclear reactions. It remains the leading theory for elemental abundance today.As with most theories, the picture of elemental synthesis remains incomplete. While it is thought that the overall theory is correct, there are still many mysteries in the details. There are several kinds of nuclear reactions that occur in stars and supernova that create the elements heavier than iron. They include the r-process, s-process, and p-process, along with several others. However, there are some elements whose creation is not fully understood. There are a variety of reasons for this, which will be discussed.In our experiment we studied the nuclear reaction properties of an isotope of Copper (65Cu). It is theorized that it is produced by the p-process during a supernova explosion. The p-process can be described simply as the collision of an alpha particle with a large atomic nucleus with a proton byproduct. Little actual experimental data has been taken involving the p-process, which is why we chose this reaction. The experiment was done using the Tandem Van de Graaff Accelerator at Ohio University. / Department of Physics and Astronomy
|
2 |
Sinteza, strukturna, fizičko-hemijska i biološka karakterizacija novih N-heterocikličnih liganada i njihovih kompleksa sa jonima prelaznih metala / Synthesis, structural, physico-chemical and biological characterization of N-heterocyclic ligands and their complexes with transition metal ionsMađari Jožef 08 October 2018 (has links)
<p>Opisane su sinteze novih liganada bis(ftalazin-1hidrazon)-2,6-diacetilpiridna (Hz<sub>2</sub>DAP·2HCl), bis(3-hlorpiridazin-6-hidrazon)-2,6-diacetilpiridina (Hp<sub>2</sub>DAP), 3-hlorpiridazin-6-hidrazon di(2-piridil) ketona (HpDPK), ftalazin-1-hidrazon di(2-piridil)<br />ketona (HzDPK) i ftalazin-1-hidrazon piridin-2-karbaldehida (HzPY). Zajedničko svojstvo dobijenih liganada je što sadrže piridinski i diazinski prsten i sadrže samo donorne atome azota. Tokom nastajanja kompleksa dolazi do deprotonacije liganada. Svi ligandi su okarakterisani elementalnom analizom, termoanalitičkim metodama i metodom IR spektroskopije, dok neki i metodom NMR spektroskopije kao i rendgenskom strukturnom analizom.Za sintezu koordinacionih jedinjenja primenjeni soli Co(II), Ni(II), Cu(II) i Zn(II). Dobijeni kompleksi su okarakterisani elementalnom analizom, konduktomerijskim i magnetnim merenjima, IR spektroskopijom i termoanalitičkim metodama. Barem jedan kompleks iz svake serije je okarakterisan i rendgenskom strukturnom analizom. Urađena su i ispitivanja antimikrobne aktivnosti odabranih jedinjenja prema predstavnicima grampozitivnih i gram-negativnih bakterija i kulturu kvasca. Pored toga, urađena su i ispitivanja citotoksične,antiproliferativne i inhibitorne aktivnosti jedinjenja prema roditeljskim i multirezistentnim T-limfomnim ćelijama kancera. Utvrđeno je da neka jedinjenja pokazuju izrazito mikrobicidno, citotoksično, antiproliferativno i inhibitorno dejstvo.</p> / <p>The synthesis of new ligands dihydrochloride salt of 2,6-diacetylpyridne bis(phthalazine-1hydrazone) (Hz<sub>2</sub>DAP•2HCl), 2,6-diacetylpiridine bis(3- chloropyridazine-6-hydrazone) (Hp<sub>2</sub>DAP), di(2-pyridyl)ketone 3-chloropyridazine- 6-hydrazone (HpDPK), di(2-pyridyl)ketone phthalazine-1-hydrazone (HzDPK) and pyridine-2-carbaldehide phthalazine-1-hydrazone (HzPY) have been described. All the ligands contain pyridine and diazine core and all of them have only nitrogen donor atoms. During the complex formation the deprotonation of ligands takes places. All of the ligands have been characterized by elemental analysis,thermoanalytical methods and IR spectroscopy. In some cases also by NMR spectroscopy and X-ray structural analysis.Co(II), Ni(II), Cu(II) and Zn(II) salts were used for the synthesis of the coordinational compounds. The obtained complexes were characterized by elemental analysis, molar conductivity and magnetic measurements, IR spectroscopy and thermoanalytical methods. At least one complex of each series were characterized by X-ray structural analysis.The antimicrobial activity of some of the compounds toward Gram-positive/Gram- negative bacteria furthermore, the cytotoxic, antiproliferative and inhibitory activity toward sensitive parental andmultiresistant T-lymphoma cancer cells have also been carried out. It can be concluded that some of the compounds exhibit outstanding antimicrobial, cytotoxic, antiproliferative, and inhibitory activity.</p>
|
Page generated in 0.0445 seconds