Thesis (M. Tech. Engineering: Electrical--Vaal University of Technology) / The air-breathing Direct Methanol Fuel Cell (DMFC) and Zinc Air Fuel Cell (ZAFC)were experimentally studied in a climate chamber in order to investigate the impact of climatic environmental parameters such as varying temperature and relative humidity conditions on their performance. The experimental results presented in the form of polarization curves and discharge characteristic curves indicated that these parameters have a significant effect on the performance of these fuel cells. The results showed that temperature levels below 0ºc are not suitable for the operation of these fuel cells. Instead, it was found that air-breathing DMFC is favored by high temperature conditions while both positive and negative effects were noticed for the air-breathing ZAFC. The results of the varying humidity conditions showed a negative impact on the air-breathing DMFC at a lower temperature level but a performance increase was noticed at a higher temperature level. For air-breathing ZAFC, the effect of humidity on the performance was also found to be influence by the operating temperature. Furthermore, common atmospheric air pollutants such as N20, S02, CO and N02 were experimentally investigated on the air-breathing DMFC and ZAFC. At the concentration of 20 ppm, these air contaminants showed to have a negative effect on the performance of both air-breathing DMFC and ZAFC. For both air-breathing DMFC and ZAFC, performance degradations were found to be irreversible. It is therefore evident from this research that the performance of the air-breathing fuel cell will be affected in an application situated in a highly air-polluted area such as Vaal Triangle or Southern Durban. It is recommended the air-breathing fuel cell design include air filters to counter the day-to-day variations in concentration of air pollutants.

M. Tech. (Electrical, Applied Electronics and Electronic Communication, Faculty of Engineering and Technology) Vaal University of Technology| / The demand for efficient and environmentally friendly power sources has become a major topic around the world. This research explores the capability of the zinc-air fuel cell to replace conventional power sources for various applications, more specifically telecommunication systems. The research consisted of a theoretical study of the zinc-air fuel cell and its components, as well as their performance characteristics. A zinc-air fuel ce.ll and test rig were built, and the system was tested under various conditions. It was found that the zinc-air fuel cell has an advantage over other fuel cells in that it does not require any expensive materials or noble metals, reducing the overall cost of such a system. The fuel cell showed the potential to power various applications, but problems persisted in the fueling process as well as constant leaking of the aqueous electrolyte.