京都大学 / 0048 / 新制・課程博士 / 博士(理学) / 甲第18778号 / 理博第4036号 / 新制||理||1581(附属図書館) / 31729 / 京都大学大学院理学研究科物理学・宇宙物理学専攻 / (主査)准教授 松田 和博, 教授 八尾 誠, 教授 田中 耕一郎 / 学位規則第4条第1項該当 / Doctor of Science / Kyoto University / DFAM

No description available.

Increased accident rates during the nighttime and wet weather conditions on the United States highways necessitate the enhancement of highway concrete barrier visibility. The visibility of these delineators is dependent on their reflectivity. Several methods are proposed that stand to increase the reflectivity of these concrete barriers, such as the use of white cement versus gray cement and the attachment of raised pavement markers to the side of the barriers. The incorporation of recycled glass into the concrete mixture is one of the proposed methods that was put through further laboratory study. The aim of the laboratory testing was to identify proper mixing proportions that mitigate the potential for the alkali-silica reaction (ASR) in recycled glass aggregate concretes without producing any negative effects on the compressive strength of the concrete. The retroreflectivity of these concrete mixtures was also evaluated and is presented in this report.

Voluminous Eocene to Oligocene intermediate to silicic volcanic rocks related to subduction erupted throughout the Great Basin and were supplanted by bimodal eruptions of basalt and rhyolite related to extension in the Miocene. Locally, in the northern East Tintic Mountains of central Utah, this important transition is marked by a distinctive package of mafic alkaline magmas that reveal important details about the nature of this fundamental change. A late Oligocene anorthoclase-bearing shoshonite lava in the Boulter Peak quadrangle contains megacrysts of anorthoclase, with phenocrysts of olivine, clinopyroxene, magnesiohastingsite, magnetite, and apatite. The anorthoclase grains occur as glomerocrysts with irregular, resorbed edges, indicating they are not in equilibrium with the mafic phenocrysts in the shoshonite. They are interpreted to be xenocrysts incorporated into an ascending mafic magma that came into contact with a partially crystallized syenite. The mafic magma involved was probably derived by partial melting of the lithospheric mantle based on its high Mg/Fe ratios, magnesian phenocrysts, high water content, and high ratios of lithophile to high field strength elements. The syenite body likely crystallized from a highly differentiated melt. The 40Ar/39Ar age of the shoshonite is 25.35±0.04 Ma, and appears to represent the transition from subduction before the onset of extension (Christiansen et al., 2007). Other Oligocene mafic units in the area may represent different variations of the mafic alkaline endmember for the mixing process. The Gardison Ridge dike, a potassic alkaline basalt with an 40Ar/39Ar age of 26.3±0.3 Ma, contains olivine and clinopyroxene phenocrysts that are compositionally very similar to those found in the shoshonite. Other mafic dikes have even higher alkalis. All of these dikes have similar trace element patterns, with negative Nb and positive Pb anomalies, and high Ba and K concentrations. The minette of Black Rock Canyon (28.45±0.13 Ma) also contains high alkalis, particularly K, and its trace element pattern shows positive Ba and negative Nb anomalies. The clinopyroxene phenocrysts in the minette are also very similar to those found in the other alkaline rocks. The high water contents of these units are evidenced by amphibole in the shoshonite, phlogopite in the minette, and the lack of plagioclase phenocrysts in the basaltic dikes. The ages, mineral assemblages, and chemical compositions show that these late Oligocene alkaline magmas formed after a shallowly subducting oceanic slab peeled away from the overlying continental lithosphere and rolled back. Hot asthenosphere flowed in to replace the subducting plate and caused partial melting of the variably metasomatized lithospheric mantle. These alkaline magmas include the shoshonite, mafic alkaline dikes, and minette of Boulter Peak; they mark the transition from older subduction-related magmatism to Miocene magmatism caused by lithospheric extension.

Optical absorption spectra of alkali halide crystals containing H⁻ ions (U-centres) are calculated using a two-parameter model to describe the defect. It is shown that this model gives a satisfactory account of the observed anharmonic sideband of the main U-centre absorption band in the infrared, and also of the impurity-induced far infrared absorption for the two host crystals considered, potassium bromide and potassium iodide. The broadening of localized modes and resonances is also discussed. In particular, the anharmonic broadening is calculated for the main U-centre line in KI and KBr and for a localized gap mode in KI:KH. / Thesis / Doctor of Philosophy (PhD)

<p>This study was planned as a combination of detailed field mapping, thin section petrography, whole rock geochemistry and amphibole chemistry of the rocks of the Port Coldwell intrusion. It was hoped that the results of the detailed field mapping would give a clearer picture of the stratigraphy and structure of the intrusion. It was hoped to define the mineralogy and textures of the various phases of the Port Coldwell intrusion enabling a postulation of possible physical conditions under which crystallization occurred. Through whole rock chemical analysis it was hoped to correlate the petrochemistry with the stratigraphy, and so to provide a chemical explanation of the differentiation process. Furthermore, it was hoped to classify the gabbros and through differentiation trends provided by the plots of the analyses, to determine whether the gabbro could be a feasible parent of the other phases of the intrusionThe amphibole found in each phase of the intrusion was to be determined in order to discover elemental trends and to provide corroborating evidence of a differentiation sequence suggested by other sources. </P> / Thesis / Master of Science (MSc)

<p> The alkali metal dichromates show extensive polymorphism. The crystal structures of the polymorphs α-Na2Cr2O7, β-Na2Cr2O7, β1-Rb2Cr2O7 and P21/c NaRbCr2O7 have been determined with x-ray methods. Crystal data were determined for β2-Rb2Cr2O7, P1 Cs2Cr2O7 and the P21/c NaCsCr2O7.</p> <p> The dichromate ions found in this work have been compared with the dichromate ions found in other crystal structure determinations. The anions are described in terms of the bridging oxygen angles b and the torsion angles α1 and α2. Many of the dichromate ions are close to having C2v symmetry with values for α1 and α2 close to zero and bridging angles of around 124°. But there is a number of dichromates with α1 = -α2 and 0°<|α|<60° for which the bridging angle varies between 131° to 141°.</p> <p> The structures determined in this work are discussed as part of a unified description of thortveitite like and dichromate like structures in terms of layers of Y2O7 anions. In terms of this description and Brown and Calvo's classification a structure is proposed for the β2Rb2Cr2O7, while for the structure of NaCsCr2O7 it is suggested that it is isostructural to that of P21/c NaRbCr2O7. The phase transition of α-Na2Cr2O7 to β-Na2Cr2O7 is considered and it is suggested that a twisting thermal mode plays an important role in this as well as in other transitions.</p> / Thesis / Doctor of Philosophy (PhD)

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The alkali-aggregate reaction was first reported in 1940 as a cause of severe cracking in some concrete structures. It is only in recent years that papers have been published dealing with the effects of AAR on the performance of structures. This thesis outlines a methodology for numerical simulation of the response of concrete subjected to continuing AAR. First a constitutive model is presented based on the framework proposed by Pietruszczak (1996). The formulation incorporates an assumption that the rate of expansion depends on the confining pressure, the age of concrete and the temperature. The progress in the reaction is coupled with the degradation of mechanical properties, in particular the elastic modulus and the compressive and tensile strengths. Subsequently, the procedures for generating finite element models are described, including geometric modeling, mesh generation techniques, graphical representation of the results and interfacing between pre- and post-processor and the finite element solvers. The numerical analysis, undertaken in this thesis, pertains to the Beauharnois Powerhouse, situated in Quebec, Canada. The powerhouse has been experiencing problems related to a continuing expansion of concrete due to AAR since the early 1960’s. The progressive formation of macrocracks and the volumetric expansion in concrete has caused operational problems, such as the reduction in clearance between turbine runner blades and throat rings. In this study, typical structural units of the Beauharnois Powerhouse were selected for the numerical analysis. The AAR constitutive model was applied in a finite element framework. Mechanical properties of concrete were carefully evaluated based on available experimental data. Simulations were focused on the deformation and the time history of progressive macro/microcracking due to continuing reaction. Structural responses under isothermal as well as non-isothermal conditions were simulated. The results of the numerical analyses were then compared with in-situ measurements. / Thesis / Master of Engineering (ME)