The genetic algorithm (GA) is used to design helical antennas that provide a significantly larger bandwidth than conventional helices with the same size. Over the bandwidth of operation, the GA-optimized helix offers considerably smaller axial-ratio and slightly higher gain than the conventional helix. Also, the input resistance remains relatively constant over the bandwidth. On the other hand, for nearly the same bandwidth and gain, the GA-optimized helix offers a size reduction of 2:1 relative to the conventional helix. The optimization is achieved by allowing the genetic algorithm to control a polynomial that defines the envelope around which the helix is wrapped. The fitness level is defined as a combination of gain, bandwidth and axial ratio as determined by an analysis of the helix using NEC2. To experimentally verify the optimization results, a prototype 12-turn, two-wavelength high, GA-helix is built and tested on the Virginia Tech outdoor antenna range. Far-field radiation patterns are measured over a wide frequency range. The axial-ratio information is extracted from the measured pattern data. Comparison of measured and NEC-2 computed radiation patterns shows excellent agreement. The agreement between the measured and calculated axial-ratios is reasonable. The prototype GA-helix provides a peak gain of more than 13 dB and an upper-to-lower frequency ratio of 1.89. The 3-dB bandwidth of the antenna is 1.27 GHz (1.435 GHz - 2.705 GHz). Over this bandwidth the computed gain varies less than 3 dB and the axial-ratio remains below 3 dB. / Master of Science

This master's thesis presents a study on a slot and microstrip patch as the two main types of antennas for the use on Cube Satellite (CubeSat). A study on the fundamentals of the slot antenna is researched and a circularly polarized (CPd) cavity-backed cross slot antenna and its two-element array for the CubeSat are designed and fabricated. Fabricated two-element phased array cross slot antenna has higher radiation gain and steered radiation pattern compared to the fabricated single cross slot antenna. A CPd square microstrip patch antenna for the application of the CubeSat is designed and compared with a commercial CPd microstrip patch antenna. It is concluded that our designed microstrip patch antenna has a better performance compared to the commercial one. The last part of the research focuses on the design of miniaturized slot antennas for the CubeSat working at an ultra high frequency (UHF) band. The different techniques and challenges that we face through the miniaturization are articulated throughout the research and expanded upon in this thesis. The antenna simulations were performed using Ansoft High Frequency System Simula- tor (HFSS) and the final designs for the CPd cavity-backed single and two-element cross slot antennas and CPd microstrip patch antenna were fabricated using a circuit board milling machine. These were then measured inside an anechoic chamber for the radiation pattern. Both antennas had high radiation gain and good CPd radiation quality.

A new variation of the spherical helical antenna made of a wire wound over a hemispherical surface and backed by a conducting ground plane is introduced. A constant spacing is maintained between the turns of winding. The geometry of this antenna is fully described by the number of turns and the radius of hemispherical surface. In addition to the hemispherical geometry, truncated double spherical helices are also examined. Radiation properties of the proposed antennas are studied both theoretically and experimentally. The wire antenna code ESP (electromagnetic surface patch), which is based on the method of moments, is used to obtain simulation results. The results for far-field patterns, gain, axial ratio, bandwidth, and input impedance are presented. Several prototypes of this antenna were constructed and tested using an outdoor antenna range. Far-field patterns were measured over a wide range of frequencies. The measured and calculated radiation patterns are in good agreement. A unique property of the hemispherical helix is its broad half-power beamwidth. Furthermore, this antenna provides circular polarization and relatively high gain over a narrow frequency range. The results of this research show that, for example, a 4.5-turn hemispherical helix with a radius of 0.02 meter designed for operation around 2.8 GHz provides a half-power beamwidth of about 90 degrees, more than 9 dB gain, and less than 3 dB axial ratio over a 300 MHz bandwidth. The input impedance of the antenna is largely resistive and is about 150 ohms in the above frequency range. Compared with a full spherical helix, the hemispherical helix provides comparable radiation characteristics, but occupies only half the volume. The compact size of this antenna makes it attractive to mobile communication applications / Master of Science

No description available.

A thesis submitted to the Faculty of Engineering,University of the Witwatersrand, Johannesburg, in fulfilment of the requirements for the degree or Doctor of Philosophy. / The aim of the thesis is to develop techniques for the analysis of antennas composed of dipoles and folded dipoles,that are efficient relative to the method-of-moments. (Abbreviation abstract) / AC2017

Wireless communication is part of our daily life in several applications, such as cell phones, wireless printers, sensors, etc. Each wireless device requires at least one antenna to communicate with other devices. In 2002, Federal Communications Commission (FCC) assigned a frequency spectrum from 3.1 GHz to 10.6 GHz for ultra-wideband communications. Several narrowband antennas require to cover the entire range. Unlike narrowband antennas, ultra-wideband antennas need to cover the wide frequency band. This research mainly focuses on physically small antenna designs. The first antenna discussed in this dissertation is a dual, triple trident antenna with dimensions 24 mm × 28 mm × 0.785 mm, which will operate from 3 GHz to 12.15 GHz [58]. The first antenna consists of six tridents symmetrical along the vertical direction. The second antenna design is a novel rectangular ring ultra-wideband antenna [59]. Large antennas operate for low frequency, and small antennas work for high frequency. The number of rings increased in wideband antenna to 9 from 4 to check the design methodology. The rectangular ring ultra-wideband antenna has dimensions 24 mm × 26 mm × 1.52 mm. This antenna operates from 3.12 GHz to 12.85 GHz. The third antenna design is an ultra-wideband dual square trident planar antenna. This antenna’s overall size is 26 mm × 24 mm × 1.56 mm [60]. This antenna has impedance bandwidth from 3.65 GHz to 12.50 GHz. The fourth antenna design is an ultra-wideband antenna with a band notch from 5.05 GHz to 5.9 GHz [61]. This antenna consists of two tridents and two split-ring resonators along the microstrip feed line. The overall size of this antenna 26 mm ×24 mm × 1.53mm. Simulations are carried out using the CST microwave studios® to analyze the antenna performance. Experiments are conducted to verify the simulated results using vector network analyzers for impedance and anechoic antenna chamber for radiation characteristics of the antenna. All four antennas are excellent for the wireless device due to their compact size and planar designs.

Light absorption in metal catalyst nanoparticles can excite charge carriers to generate hot electron (and complimentary hot holes) with energy higher than the Fermi level. When hot electrons possess energy high enough, they exhibit a high tendency to inject into antibonding orbitals of adsorbates on the photoexcited metal nanoparticles, weakening the corresponding chemical bonds to promote chemical reactions with accelerated reaction kinetics and improved selectivity. Such hot-carrier chemistry has been reported on plasmonic metal nanoparticles, such as silver and gold, which exhibit strong surface plasmon resonances (SPRs) and strong light absorption. However, these metal nanoparticles are not suitable catalysts because their affinity toward interesting molecules is limited. In contrast, most transition metals, such as platinum-group metals and early transition metals, are industrially essential catalysts, but light absorption power in metal nanoparticles is low due to the absence of SPRs in the visible spectral range. Therefore, it is intriguing to explore the potential of hot-carrier catalytic chemistry on photoexcited non-plasmonic metal nanoparticles. Upon the absorption of the same optical power, metal nanoparticles with a small size usually exhibit a high probability of hot electron production and high efficiency of injecting hot electrons into adsorbates. It is challenging to have strong light absorption power and operation stability of the catalyst metal nanoparticles with small sizes. In this thesis, dielectric light antenna, i.e., spherical silica nanoparticles with strong surface scattering resonances near their surfaces, is introduced to support the metal catalyst nanoparticles, enabling improved light absorption power in the metal nanoparticles and operation stability. This thesis focuses on ultrafine rhodium (Rh) nanoparticles (with sizes ranging from 1.7 nm to 4.2 nm) that are widely used as thermal catalysts in many important industry reactions, especially for oxygen-containing species conversion, an oxyphilic feature of Rh nanoparticles. Firstly, this dissertation conducted a comparative study to investigate the influence of silica geometry, nanospheres, and rodlike nanoparticles on the light absorption of Rh nanoparticles. Both silica substrates enhanced the light absorption of loaded Rh nanoparticles due to elongated light scattering paths (random scattering) and enhanced electromagnetic field intensity (resonant scattering). However, silica nanospheres support both resonant scattering and random light scattering modes, exhibiting a higher Rh absorption than the usage of rodlike silica nanoparticles. The light resonant scattering modes on highly symmetrical silica nanospheres enable producing "hot spots" with a much higher electromagnetic field intensity than incident light intensity. This study then investigated the effect of silica geometries on photocatalytic performance. The CO2 hydrogenation was studied as a model reaction. The Rh/silica nanosphere system exhibited a faster photocatalytic kinetic than the case of rodlike silica nanoparticles. It is possibly due to the enhanced light power density around the silica nanospheres. The results give a promise of expanding Rh nanoparticles from thermo-catalysis to photocatalysis. Secondly, this dissertation moves onto accelerating aerobic oxidation of primary alcohols to aldehydes, which was benefited from activated oxygen molecules by hot electron injection. This study found that photoexcited Rh nanoparticles enabled accelerating the alcohol oxidation kinetics by four times at a light power intensity of 0.4 W cm-2, accompanied by a reduced activation energy of 21 kJ mol-1. The derived Langmuir-Hinshelwood rate equation was used to fit the oxygen partial pressure results. Photo-illumination promotes the cleavage of associatively adsorbed oxygen molecules into adsorbed oxygen atoms, reducing the energy barrier. Besides, the silica-supported Rh nanoparticles exhibited a higher photocatalytic performance because of the good colloidal stability and enhanced light absorption of small-sized Rh particles. This part of the dissertation shows the possibility of hot-electron mediated reaction pathways towards a desirable kinetic of alcohol oxidation. Thirdly, it will be meaningful to use the abstracted protons from cheap alcohol sources to reduce other organic molecules rather than dangerous hydrogen gas. This dissertation then investigated the possibility of using an isopropanol solvent as a hydrogen source to reduce nitrobenzene and the feasibility of enhancing the selectivity of the reaction with the light illumination. The results showed that the isopropanol was spontaneously oxidized, producing acetone. Light illumination onto Rh particles selectively enhanced the coupling of reduced nitrobenzene intermediates to produce azoxybenzene. The selectivity of nitrobenzene and production rates gradually increased with a higher number of light photons. Photo-illumination promotes both aniline and azoxybenzene production rates. Hot electrons on Rh particles possibly enabled activating nitrobenzene molecules and increasing concentrations of reduced nitrobenzene intermediates. It resulted in a higher possibility of condensation product and azoxybenzene selectivity, which could not be obtained by elevating temperature without light illumination. This part of the work demonstrated the feasibility of hot electrons from Rh nanoparticles to tune the reaction selectivity in a liquid phase. Lastly, it is challenging to modulate the selectivity of CH4 from CO2 hydrogenation because of the competitive CO production. This dissertation moves towards enhancing both kinetic rates and selectivity of CH4 for gaseous CO2 hydrogenation by photoexcited Rh nanoparticles. Light illumination onto Rh/silica nanosphere particles resulted in the selectivity of CH4 over 99% in contrast to ~70% under dark conditions at 330 oC and with an absorbed light power intensity of 1.5 W cm-2. The activation energy of CH4 production and CO2 consumption gradually decreased with higher light power intensity because of the transient injection of hot electrons into adsorbates to activate intermediates. Increasing operating temperature and light power intensity synergistically enhanced the reaction kinetics. Besides, a middle-sized Rh nanoparticle showed a better photocatalytic performance than that of the largest-sized Rh nanoparticles because of the balance in hot-electron production efficiency and intrinsic catalytic performance. Partial pressure dependence and in situ infrared characterizations showed that the critical stable intermediates for CH4 production should be hydrogenated CO2 species (HCOO* COOH*) and hydrogenated CO* species (carbonyl hydride or HxCO*). The light illumination exclusively enhanced the dissociation of CO2 and CO* without apparent influence on CO* desorption. Under high reaction temperature, light illumination preferred a faster CO* conversion than CO2 dissociation, leading to high CH4 selectivity. This result was also supported by higher methanation rates of CO gas under light illumination. The infrared result showed a reduced stretching frequency of CO*, which supported the possibility of the electron from Rh back-donating into antibonding orbitals of strongly adsorbed CO* species. However, hot electrons from silver nanoparticles with a weak COOH* or CO* adsorption could not efficiently activate carbon-species and could not promote CO2 hydrogenation kinetics. This dissertation offers an avenue of enhancing light absorption of small-sized Rh nanoparticles and expanding its usage from thermal catalysis to photocatalysis for driving oxidation and reduction reactions. The reactants share a common feature containing oxygen elements, a strong affinity with rhodium metal for efficient hot electron injection. We studied the light power intensity and temperature-dependence, showing the accelerated reaction kinetics by hot electron-driven pathways. Photo-excited rhodium nanoparticles were believed to promote the cleavage of chemical bonds O-O, N-O, and C-O to drive chemical transformations. The findings offer insights into developing the scope of non-plasmonic metal nanoparticles in photocatalytic reactions for industrial applications. / Chemistry

In recent years, microwave ablation therapy has become widely investigated as an alternative treatment to cancer. This method is one of the newest forms of ablation techniques for the removal of tumors and is minimally invasive compared to alternative treatments. One drawback to many of the current microwave ablation systems is the narrowband nature of the antennas used for the probe, such as dipole antennas. This study aims to compare ablation results of both ultra-wideband and narrowband ablation techniques. An ultra-wideband ablation probe is designed that operates from 400MHz to 2.6GHz and are compared to two designed narrowband ablation probes that operate at 915MHz and 2.4GHz, respectively. These ablation probes are tested in tissue mimicking gels and porcine liver. Provided results for this thesis will include probe designs, simulation results, and ablation experiments.

The United States Department of Defense tests its weapons systems to many different real as well as man-made environments prior to deploying the systems to the troops. The intent of testing is to insure the systems function as they are intended without adverse reactions. One of the required tests is a Radiation Hazards test to insure that non-ionizing radio frequency waves generated by transmitters, such as radios and jammers, do not cause harm to personnel, ordnance or fuel. This test is typically performed at a DoD test lab and data taken at the lab is used to determine safe operating parameters for a particular piece of equipment. This thesis presents measurements as well as mathematical models to demonstrate methods that can be employed to take more relevant Radiation Hazards data.

No description available.