abstract: Growth of the Phoenix metropolitan area led to exposures of the internal bedrock structure of surrounding semi-arid mountain ranges as housing platforms or road cuts. Such exposures in the Sonoran and Mojave deserts reveal the presence of sedimentary calcium carbonate infilling the pre-existing fracture matrix of the bedrock. Field surveys of bedrock fractures filled with carbonate (BFFC) reveal an average of 0.079 +/- 0.024 mT C/m2 stored in the upper 2 m of analyzed bedrock exposures. Back-scattered electron microscopy images indicate the presence of carbonate at the micron scale, not included in this estimation. Analysis of the spatial extent of bedrock landforms in arid and semi-arid regions worldwide suggests that ~1485 GtC could potentially be stored in the upper 2 m horizon of BFFCs. Radiocarbon dating obtained at one of the sites indicates it is likely that some of the carbonate was flushed into the bedrock system during glacial wet pulses, and is stored on Pleistocene timescales or longer. Strontium isotope analysis at the same site suggest the potential for a substantial cation contribution from weathering of the local bedrock, indicating the potential exists for sequestration of atmospheric carbon in BFFCs. Rates of carbon release from BFFCs are tied to rates of erosion of bedrock ranges in desert climates. / Dissertation/Thesis / M.A. Geography 2013

abstract: A fundamental gap in geomorphic scholarship regards fluvial terraces in small desert drainages and those terraces associated with integrating drainages. This dissertation analyzes four field-based case studies within the Sonoran Desert, south-central Arizona, with the overriding purpose of developing a theory to explain the formative processes and spatial distribution of fluvial terraces in the region. Strath terraces are a common form (Chapters 2, 3, 4) and are created at the expense of bounding pediments that occur on the margins of constraining mountainous drainage boundaries (Chapters 1, 2, 3). Base-level fluctuations of the major drainages cause the formation of new straths at lower elevations. Dramatic pediment adjustment and subsequent regrading follows (Chapter 3), where pediments regrade to strath floodplains. This linkage between pediments and their distal straths is termed the pediment-strath relationship. Stability of the base level of the major drainage leads to lateral migration and straths are carved at the expense of bounding pediments through an erosional asymmetry facilitated by differential rock decay between the channel bank and bed. Fill terraces occur within the Salt River drainage basin as a result of the integration processes that connect formerly endorheic basins (Chapter 4). The topographic, spatial, and sedimentologic relationship of the Stewart Mountain terrace (Chapter 4) points to a different genetic origin than the lower terraces in this basin. The high Stewart Mountain fill terrace records the initial integration of this river. The strath terraces inset below the Stewart Mountain terrace are a result of the pediment-strath relationship. These case studies also reveal that the under-addressed drainage processes of piracy and overflow have significant impacts in the evolution of drainages the lead to both strath and fill terrace formation in this region. / Dissertation/Thesis / Ph.D. Geography 2013