Atmospheric monitoring of radionuclides as part of the International Monitoring System requires the capability to differentiate between a radionuclide signature emanating from peaceful nuclear activity and one emanating from a well-contained underground nuclear explosion. While the radionuclide signatures of nuclear weapons are generally well known, radionuclides must first pass through hundreds of meters of earth to reach the surface where they can be detected and analyzed. Less well known is the affect that subsurface vertical transport has on the isotopic signatures of nuclear explosions. In this work, a model is developed, and tested, simulating the detonation of a simple underground nuclear explosion and the subsequent vertical transport of resulting radioxenon to the surface. First, the fast-fission burn of a fissile spherical core surrounded by a layer of geologic media is modeled, normalized to 1 kton total energy. The resulting source term is then used in the testing and evaluation of the constructed vertical transport model, which is based on the double-porosity model of underground fluid transport driven by barometric pumping. First, the ability of the vertical transport code to effectively model the underground pressure response from a varying surface pressure is demonstrated. Next, a 100-day simulation of the vertical migration of a static source is examined, and the resulting cumulative outflow of roughly 1% initial inventory outflow per cycle is found to closely follow the analytical predictions. Finally, calculated radioxenon source terms are utilized to model the resulting vertical transport and subsequent surface outflow. These results are found to be consistent with the physical expectations of the system, and lastly a cursory sensitivity analysis is conducted on several of the physical parameters of the model. The result is that the vertical transport model predicts isotopic fractionation of radioxenon that can potentially lie outside of currently accepted standard bounds. / text

Understanding the gas phase flow and transport of volatile organic compounds (VOCs) in unsaturated zones is indispensable to develop effective environmental remediation strategies, to create precautions for fresh water protection, and to provide guidance for land and water resources management. Atmospheric pressure and water table fluctuations are two important natural processes at the upper and lower boundaries of the unsaturated zone, respectively. However, their significance has been neglected in previous studies. This dissertation systematically investigates their influence on the gas phase flow and transport of VOCs in soil and ground water remediation processes using analytically and numerically mathematical modeling. New semi-analytical and numerical solutions are developed to calculate the subsurface gas flow field and the gas phase transport of VOCs in active soil vapor extraction (SVE), barometric pumping (BP) and natural attenuation taking into account the atmospheric pressure and the water table fluctuations. The accuracy of the developed solutions are checked by comparing with published analytical solutions under extreme conditions, newly developed numerical solutions in COMSOL Multiphysics and field measured data. Results indicate that both the atmospheric pressure and the tidal-induced water table fluctuations significantly change the gas flow field in active SVE, especially when the vertical gas permeability is small (less than 0.4 Darcy). The tidal-induced downward moving water table increases the depth-averaged radius of influence (ROI) for the gas pumping well. However, this downward moving water table leads to a greater vertical pore gas velocity away from the gas pumping well, which is unfavorable for removing VOCs. The gas flow rate to/from the barometric pumping well can be accurately calculated by our newly developed solutions in both homogeneous and multi-layered unsaturated zones. Under natural unsaturated zone conditions, the time-averaged advective flux of the gas phase VOCs induced by the atmospheric pressure and water table fluctuations is one to three orders of magnitude less than the diffusive flux. The time-averaged advective flux is comparable with the diffusive flux only when the gas-filled porosity is very small (less than 0.05). The density-driven flux is negligible.