The objectives of this research are to accomplish Multilayer Ceramic Capacitors, MLCCs used Temperature compensated type Ceramic powder and different design and size to confer its characteristic. The first to speak about Taiwan capacitors property development to point Multilayer Ceramic Capacitors from 1960 to recently.The manufacture procedure from Normal Metal Electronic procedure change to Base Metal Electronic procedure. The second to quote the relation document to explain Temperature compensated type Multilayer Ceramic Capacitors characteristics and main electric characteristics and the related factors such as Frequency, Test Signal Level, DC Bias, Temperature, Time, Insulation resistance and Break down voltage. The last from sample manufacture flow and structure analysis to electric characteristic measure analysis and result to discuss opposite factor characteristics. To bring up develop direction and reference material.