A Masters Dissertation submitted to the faculty of Science, University of the Witwatersrand in fulfillment of the requirements for the Masters` degree. Johannesburg 2016. / The Middle Stone Age (MSA) levels (c. 100 – 72 ka) (thousand years) at Blombos Cave, South Africa, contain buried remnants of human existence and their activities (these include ochre-stained shell beads, processed ochre pieces, bone tools, stone tools, and ochre processing toolkits). A preliminary study on the occupation layers at Blombos Cave was done in order to chemically and physically characterise the sediment deposits. The interpretation of the information preserved in these sediments, as a result of human activities, was achieved by using the following characterisation techniques: FT-IR, ICP-OES/MS, CHNS analysis as well as pH and EC measurements. Fluctuations in the bio-essential trace elements (K, P, Mg, Ca, S, Fe, Al, Cr, Na, Cu and C) and in the markers of in situ burning (P, K, C, Ca and Mg) through the MSA levels suggested a non-contiunous anthropogenic occupation of the cave. Further, the dark coloured layers were indicative of periods when heavy human activities, such as fire use, were encoutered. These layers were characterised by high levels of P, K, C, Ca and Mg, also elevated pH and EC levels were observed. The calcite origin for these sediment deposits was confirmed to be pyrogenic. The layers found to contain large bone, ochre and shell densities (with no evidence of fire use) had high levels of Fe, P high Ca and low EC. The calcite origin for these sediment deposits was geogenic. Biogenic calcite was only observed in the more recent CA and CC layers. Substantial amounts of ochre assemblages were recovered from the MSA levels at Blombos Cave. Among these was an ochre processing toolkit recovered from the CP layer (c.100 ka). Ochre is abundant in African archaeological sites after 165 ka and is likely to have played a symbolic role in the lives of prehistoric people. It contains an iron-oxide mineral as well as accessory minerals. When mixed with a binder (such as fat or water) ochre can be used as a pigment. A large number of fragmented bone remains were found in the M1 and M2 levels. It is suggested that the majority of the fragmentation occurred while the bones were in a fresh state; implying marrow extraction by the site occupants. The exploitation of bone marrow was crucial in order to extract the fat and use it as a binder during the pigment production. Some of the broken and marrow-extracted bones were heated and used as fuel during seasons when wood was scarce while the other bones were deliberately engraved for symbolic intent. The characterisation of the ochre processing toolkit was achieved by mineralogical analysis and elemental fingerprinting. FT-IR analysis revealed that the general matrix of the ochre samples comprised of hematite (Fe2O3) or goethite (α-FeO(OH)) as the main chromophores and clay minerals (such as kaolinite (Al2Si2O5(OH)4), muscovite [(KF)2(Al2O3)3(SiO2)6(H2O)] and illite [K(Al4Si2O9(OH)3)]), calcite (CaCO3) and quartz (SiO2) as the main accessory minerals. PXRD analysis confirmed Fe2O3, Al2Si2O5 (OH)4, [K(Al4Si2O9(OH)3)] and SiO2 to be the predominant mineral phases in the ochre, implying this specific type of ochre was preferred during the production of the pigment. Fe2O3 contributed the red hue and the aluminosilicates their clayey properties making them good extenders of the pigment. Multivariate statistics and Fe ratios made it possible to identify elements important for differentiating the ochre recovered from the CP layer. Analysis of variance (ANOVA one-way) showed a statistically significant difference between the ochre residues in terms of trace elemental profiling. The variance suggested different geological origins for the ochre. FT-IR was used as a screening technique for any organic residues associated with the toolkit and GC-MS was used to identify the preserved organic residues. These were mostly lipids and terpenes. The identified bio-molecular markers; stearic acid and dehydroabietic acid were exploited to give insight on the origin of the residues. Stearic acid suggested the use of animal fat while dehydroabietic acid implied the use of a resin (potentially as a binder in the pigment). The characterisation investigations revealed that the prehistoric populations at Blombos Cave specifically sourced hematite and aluminosilicate- containing ochre pigments in order to fulfil their social and cultural demands. The MSA site occupants’ chemical understanding of these materials suggested they were technologically advanced. Keywords: Blombos Cave, MSA levels, ochre, mineralogical analysis and elemental fingerprinting. / LG2017

Analytical methods for extracting detailed functional and technological information from Middle Stone Age stone tools were refined and developed. This was achieved within a theoretical framework that insists on multiple-stranded evidence for behavioural interpretation. The methods include micro-residue analysis, macrofracture analysis and usewear analysis. Stone tool assemblages – spanning the period between about 100 000 and 50 000 years ago – from Sibudu Cave, Umhlatuzana Rock Shelter, Klasies River Cave 2 and Blombos Cave were analysed. Results derived from macrofracture analyses, that are often conducted as an initial study to assess whether tool classes could have been used in hunting weapons, are used to formulate the following working hypotheses for Stone Age hunting technologies in South Africa: a) some pre-Howiesons Poort pointed tools were used as hafted butchery knives, while others could have been used to tip hunting weapons; b) Howiesons Poort backed tools were probably used as interchangeable pieces in hafted hunting weapons; c) post-Howiesons Poort points were used to tip hunting weapons; d) Later Stone Age hunting technologies were different from those practiced during the Middle Stone Age. The macrofracture results also provided interesting comparable data showing distinct time-related clustering of the results. Although more tools that could have functioned as hunting weapons must be analysed to evaluate the authenticity of these observations, the results suggest that macrofracture studies are important for the study of change in Stone Age hunting behaviours. The main methodological contribution of this thesis is micro-residue analysis. Advances in this method developed from blind tests on replicated flakes with residues derived from the processing of plant and animal products. Lessons learned from previous blind tests shaped the new research reported here and lead to improved methodology and interpretative skills. The last test in the series of four resulted in the most accurate interpretations because, prior to Test 4, iv identification difficulties experienced during the first three blind tests were addressed through replication. The new work reported here highlights some of the difficulties that can be experienced in the morphological identification of microscopic organic residues, particularly the distinction between animal and plant residues. It is specifically recommended that multi-stranded evidence be used for the identification of animal and plant residues. Micro-residue analysis of archaeological samples provided direct evidence for functional and hafting interpretations. These can be used to evaluate the hypotheses based on the results of macrofracture analyses and to provide data for further detailed interpretations. For example, it is shown that: a) retouched points from the Still Bay were used as knives hafted to wooden handles; b) segments from the Howiesons Poort were probably hafted in bone and wood shafts in different hafting configurations that varied during the span of the technocomplex; c) Howiesons Poort segments were mostly used on animal material; d) ochre was mixed into the adhesive recipes during the post-Howiesons Poort, the Howiesons Poort and possibly during the Still Bay technocomplexes at Sibudu Cave. Thus, the multi-analytical approach followed throughout the study contributes evidence for the early development of sophisticated and variable hunting and hafting technologies used by anatomically modern humans in South Africa. Our current knowledge of behavioural trends during the Middle Stone Age has been expanded, allowing rare glimpses into the everyday activities of people living in the deep past. Perceptions of a static, pre-modern technology and unvaried faunal exploitation during the Middle Stone Age in southern Africa are unfounded.

A thesis submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, in fulfilment of the requirements for the degree of Doctor of Philosophy. 2016 / The analysis of faunal remains from archaeological sites can reveal much about past behaviour, palaeoenvironments and bone technology. This is especially pertinent for the Middle Stone Age (MSA): a period that corresponds to both the behavioural and anatomical development of Homo sapiens. In this thesis, I examine the faunal remains from Blombos Cave (BBC) and Klipdrift Shelter (KDS), two significant MSA sites about 45 km apart along the present-day southern Cape coast. The focus of the analyses is on the Still Bay (SB) layers (c. 75 – 68 thousand years ago [ka]) at BBC and the Howiesons Poort (HP) layers (c. 65 – 59 ka) at KDS. The aim of this thesis is to explore subsistence behaviour and environmental conditions during the SB and HP in the fynbos region of the southern Cape. I also investigate the effects of trampling on bone and whether trampling and other types of taphonomic modification can be used to infer occupational intensity in cave and rock shelter sites. Taphonomic data indicate that significant differences exist between the SB and HP faunal assemblages at BBC and KDS, respectively. Carnivores and scavengers had a greater effect on the SB than on the KDS assemblage. Furthermore, subsistence activities at KDS focused on marrow extraction while filleting was probably an important strategy at BBC. Taxonomic analyses indicate that the representative fauna from both sites is generally consistent with what is expected in the fynbos biome but with some noticeable differences. Grazers, for example, are significantly more prevalent at KDS than BBC while seal is more common at BBC. Other zooarchaeological data also show differences in prey selection strategies. Diet breadth is more extensive at KDS than at BBC, although bovid mortality profiles at BBC are more juvenile-dominated. I propose that many of these contrasting patterns imply that subsistence intensification is more evident in the HP layers at KDS than in the SB at BBC. Moreover, the taphonomic data suggest that the SB at BBC was a low-intensity, sporadically occupied period in contrast to the high-intensity occupations, particularly during the middle layers of the HP at KDS. The results of the KDS analysis also indicate a shift in environmental conditions during the HP and show links between prey selection, the environment and occupational intensity during this period. Trampling experiments indicate that trampling can generally be distinguished from butcherymarks, although bioturbation in shelly deposits can sometimes result in marks that mimic cutiii marks. More importantly, experiments show that pitting and abrasion are a more significant indicator of trampling than lines that resemble cut-marks. Based on these experiments, I argue that trampling modification can be used to infer occupational intensity at archaeological sites. Trampling marks in the KDS assemblage, for example, correspond well with the high occupational periods as indicated by other taphonomic data. Trampling and taphonomic data support the notion that BBC was a low-intensity, sporadically occupied site during the SB. By incorporating taxonomic, taphonomic and novel methods of skeletal-part analyses, this study contributes to our knowledge of human subsistence and palaeoenvironments during the SB and HP in the southern Cape. This thesis strengthens and adds to other research that has demonstrated variability in subsistence behaviour during the MSA. / LG2017