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Graph invariants a tool to analyze hydrogen bonding in ice and water clusters /Kuo, Jer-Lai, January 2003 (has links)
Thesis (Ph. D)--Ohio State University, 2003. / Title from first page of PDF file. Document formatted into pages; contains xiv, 108 p.: ill. (some col.). Includes abstract and vita. Advisor: Sherwin J. Singer, Dept. of Chemistry. Includes bibliographical references (p. 100-108).
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Effect of ethanol wet-bonding of hydrophobic adhesive to dentinManan, Nor Malina Binti. January 2010 (has links)
published_or_final_version / Paediatric Dentistry / Master / Master of Dental Surgery
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Micro-push-out bond strength and the modes of failure for a fibre-reinforced resin-post system cemented using three adhesive lutingcements after cyclic loadingLiang, Hai-chiung., 梁海瓊. January 2010 (has links)
published_or_final_version / Endodontics / Master / Master of Dental Surgery
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Effect of benzalkonium chloride on resin-dentine bondAli, Sadia Piyar. January 2011 (has links)
published_or_final_version / Paediatric Dentistry / Master / Master of Dental Surgery
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Effects of zirconate coupling agents on resin modified composites bonding to zirconia surfacesWong, Dai-cheung, Jonathan., 黃大彰. January 2012 (has links)
published_or_final_version / Dental Materials Science / Master / Master of Science in Dental Materials Science
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Aspects of solvents in dentine bondingEkambaram, Manikandan January 2015 (has links)
Degradation starts at the resin-dentine bonded interfaces within a few months’ of bonding. There are two major causes of degradation of the bonded interfaces over time. The simplified dental adhesives that are routinely used in the contemporary clinical dental practice are extremely hydrophilic and are prone to water sorption, leading to hydrolytic degradation. Dentine matrix-bound metalloproteinases (MMPs) and cysteine cathepsins (CCs) are proteolytic enzymes that have been shown to degrade the uninfiltrated demineralized collagen at the bottom of the hybrid layer.
Ethanol-wet bonding (EWB) with hydrophobic adhesive has been proven to improve the longevity of resin-dentine bonds in vitro. Chlorhexidine (CHX) treatment of demineralized dentine before bonding with adhesive resin has been shown to preserve resin-dentine bond durability in vivo and in vitro by inhibition of dentine matrixbound MMPs and CCs. However, it is not known whether simultaneous application of CHX and EWB would have any interactional effect on stability of resin-dentine bonds.
1-Ethyl-3-[3-dimethylaminopropyl] carbodiimide hydrochloride (EDC), both a dentine collagen cross-linker and a MMP inhibitor, has been shown to preserve dentine bond durability in vitro. However, both EDC and CHX are prepared in aqueous solutions using water as a solvent for application. The MMPs are hydrolases and the presence of residual water in the demineralized dentine following EDC and CHX applications will enhance dentine bond degradation.
The general aims of this thesis were to investigate the effects of solvents in resindentine bonding, in particular the role of solvents in the enhancement of resin-dentine bond durability.
In the earlier part of this thesis, the adjunctive application of 2% CHX with EWB using the simplified dehydration protocol for 60 s was examined as a bonding strategy to preserve dentine bond durability to sound and caries-affected dentine. The adjunctive application of EWB and CHX preserved bond durability of hydrophobic adhesive to both sound and caries-affected dentine after 12 months’ ageing. The same bonding strategy was applied to preserve the bond durability of luting fibre post to radicular dentine. However, the addition of 2% CHX to EWB did not further improve bond durability of hydrophobic adhesive to radicular dentine, when compared to EWB alone.
In the later part of this thesis, the role of the solvents (commonly used in commercial dentine adhesives) in the enhancement of dentine bond preservation potential by CHX and EDC were assessed. The incorporation of 2% CHX in ethanol showed greater inhibitory effect on matrix-bound proteases than 2% CHX in water. Conversely, the use of acetone as a solvent for EDC also enhanced its dentine collagen cross-linking potential. The dentine collagen cross-linked by EDC in acetone was more resistant to enzymatic degradation.
Within the limitations of this thesis, it could be concluded that solvents play a significant role in the enhancement of dentine bond durability. In general, ethanol and acetone are better than water for the preservation of dentine bond durability. / published_or_final_version / Dentistry / Doctoral / Doctor of Philosophy
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H-bond directed self-assembly of oligomeric molecular strands and hydrogen mediated rhodium-catalyzed reductive cyclization of 1,6-enynesGong, Hegui 28 August 2008 (has links)
Not available / text
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Intermolecular and intramolecular hydrogen bonding in 8-quinolinol and 2-methyl-8-quinolinolSwartz, William Richard, 1945- January 1969 (has links)
No description available.
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Experimental and theoretical studies of hydrogen bonding.Bricknell, Bradley Colin. January 1995 (has links)
The theoretical and experimental work in this thesis is primarily aimed at
i) the quantification of the strengths of a number of hydrogen bonded
systems, and ii) exploring the relationships that exist between the various
physico-chemical properties determined in this study, which are related to
the hydrogen bonding phenomenon.
To this end a three part study of some hydrogen bonded systems has been
undertaken. The study involves using a number of theoretical and
experimental procedures, including a theoretical ab initio molecular orbital
study, infrared spectroscopic determinations and a thermodynamic
investigation involving measuring enthalpies and volumes of mixing and
applying a theoretical model of interacting liquid mixtures.
Conclusions based on ab initio molecular orbital theory, thermodynamic and
infrared spectroscopic results conducted in this work include:
i) the proton donating ability of the three hydrogen donor moieties
studied in this work decreases in the order O-H > N-H ~ S-H,
ii) the proton accepting competence of the three electron donor atoms
considered in this work decreases in the order N > 0 > S in all cases
except in the liquid phase systems involving dipropylamine and
propane-1-thiol as proton donors, where the proton accepting ability
of the atoms is in the opposite order i.e. S > 0 > N, and
iii) a direct correlation exists between the shift in the A-H stretching
wavenumber and the hydrogen bond interaction energy.
. Although a number of factors influence the stability of the hydrogen bond,
it was also tentatively concluded that in liquid phase systems involving
weakly self-associated hydrogen bond donor molecules, the available surface
area of the proton accepting atom becomes the dominant strength
determining factor, otherwise factors such as basicity and electronegativity
dominate. / Thesis (Ph.D.)-University of Natal, Durban, 1995
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Characterizing the failure envelope of a conductive adhesiveOlliff, Derrick K. 05 1900 (has links)
No description available.
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