Thesis (Ph. D.)--University of Notre Dame, 1941. / Cover title. Vita. Includes bibliographical references (p. 26).

Thesis (M.S.)--University of Missouri-Columbia, 2004. / The entire dissertation/thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file (which also appears in the research.pdf); a non-technical general description, or public abstract, appears in the public.pdf file. Title from title screen of research.pdf file viewed on (June 30, 2006). Includes bibliographical references.

No description available.

No description available.

Petrochemicals industry is one of the major industries in modern economy. Almost all synthetic chemicals or materials are related. Ethylene is the main product of this industry, which is produced from naphtha cracker. Butadiene is a by-product of naphtha cracking, but it is the most important raw material of synthetic rubbers. Most synthetic rubber plants do not have their own butadiene plant. All the materials were supplied from up-stream crackers. Due to the unstable supply and price surge recently, the cost of butadiene is higher than 70% of the total production cost in synthetic rubbers manufacturing. Huge price fluctuation in butadiene caused a big financial loss in 2008. These economic situations have made the price prediction an important issue for synthetic rubber manufacturers. In this research, we reviewed the historical price data of crude oil, naphtha, ethylene, propylene, butadiene and MTBE from the upper stream of petrochemicals in supply and the price of nature rubber, synthetic rubbers in demand. This study intends to find the petrochemicals price variation factors and uses butadiene as example. ¡§Time series¡¨ and OLS methods are used to build price prediction models to explain the price fluctuation in the past. Our research has found that the monthly price of butadiene is highly related to last month¡¦s price of butadiene, crude oil price and even related to last 9 month butadiene price. This may be because of the regular economical circulation and naphtha crackers annual turn around. The price of spot trading is related to the last week¡¦s price of butadiene and its co-product propylene. Those findings are valuable for synthetic rubber manufacturer in raw material procurement.

Thesis (Ph.D.)--McMaster University (Canada), 1995. / Source: Dissertation Abstracts International, Volume: 57-03, Section: B, page: 1804. Adviser: W. J. Leigh.

Thesis (M. Phil.)--Hong Kong University of Science and Technology, 2002. / Includes bibliographical references (leaves 93-100). Also available in electronic version. Access restricted to campus users.

No description available.

The tropospheric oxidation of unsaturated hydrocarbons is a central issue in atmospheric chemistry. These hydrocarbons are emitted into the atmosphere from both natural and anthropogenic sources, and their atmospheric oxidation leads to different atmospheric pollutants, including ground level ozone, photochemical smog and secondary organic aerosols. Isoprene and 1,3-butadiene represent a biogenic and an anthropogenic hydrocarbon, respectively, which primarily undergo electrophilic addition of OH radical, followed by chain propagating radical reactions. Their oxidation is the major source for ground level ozone formation in both rural and urban area and understanding their chemistry is essential for regional air quality modeling. Until recently, most of the studies of isoprene chemistry have been non-isomer specific, reflecting the reactivity of combined pathways and therefore were insensitive to specific details of the isomeric pathways. An isomeric selective approach to studying unsaturated hydrocarbon oxidation is described in this dissertation. A synthesized precursor, whose photolysis can provide a route to the formation of energy selected single isomer in the isoprene oxidation pathway, enables the study of important channels that are difficult to unravel in non isomer specific experiments. The major addition channel in OH isoprene oxidation has been studied following the isomeric selective approach and using Laser Photolysis-Laser Induced Fluorescence (LP-LIF) as the primary experimental technique. The study reveals important information about the oxidative chemistry of the δ-peroxy radicals, accounting for about 20 percent of missing carbon balance in isoprene oxidation, and isomeric specific rate constants. A similar approach was applied to study the oxidation of 1,3-butadiene, and the photolytic precursor for the dominant hydroxy alkyl isomer in the OH initiated oxidation of 1,3-butadiene was synthesized. The subsequent experiments and analysis revealed detailed information about the oxidative chemistry accounting for approximately 26 percent of the missing chemistry. Finally, non isomeric selective OH cycling experiments were carried out on the1,3-butadiene system. By analyzing the OH cycling data with the combined information obtained from the isomeric specific studies of the two isomeric channels of 1,3-butadiene oxidation, the relative branching between the two isomeric channels of OH-1,3-butadiene oxidation was determined.

Thesis (M.S.)--Brigham Young University. Dept. of Chemical Engineering, 2003. / Includes bibliographical references (p. 69-74).