High concentrations of sulfate in groundwater, up to ten times the amount recommended by the EPA, in Blanco and Hays Counties, Texas, are of concern as groundwater pumping and population increase. The goals of this study are to characterize the chemistry of groundwaters in Blanco and Hays Counties within the context of Texas Groundwater Management Area-9 and to determine chemically and hydrogeologically the explanation for the spatial distribution of sulfate between the Pedernales River, the Blanco River, and Onion Creek. Insights gained by examining sulfate distribution in Blanco and Hays Counties can be applied to the other counties on the Edwards-Trinity Plateau with similarly high concentrations of sulfate in groundwater. Hydrochemical data from the Cretaceous Edwards and Trinity Groups and water level measurements were used to analyze groundwater chemistry and flow. PHREEQC was used to examine whether phase changes in aquifer minerals could explain the observed geochemical patterns. COMSOL was used to develop a simplified groundwater flow model for a cross-sectional area between the Pedernales River and Onion Creek in Hays County. Water levels indicate that groundwater generally flows southeast in the study area and most streams are gaining. The groundwater flow model indicates a zone of slow-moving groundwater beneath the topographic high between the Pedernales River, the Blanco River, and Onion Creek. Chemical analyses of well data show the presence of four groundwater chemical endmembers in Groundwater Management Area-9; a Ca-Mg-HCO3 fresh endmember, a Ca-Mg-SO4 endmember, a Ca-Mg-SO4-Na-Cl endmember, and a Na-Cl endmember. High sulfate waters generally come from the Upper and Middle Trinity aquifers while fresher waters are from the Edwards aquifer. Physical and chemical analyses indicate that the zone of high sulfate in Blanco and Hays Counties may be the result of gypsum dissolution and dedolomitization in the Upper and Middle Trinity aquifers combined with low rates of groundwater flow beneath the topographic high. Groundwater flow analyses are consistent with those for the Groundwater Availability Models published for the region. Chemical analyses, specifically SO4 distributions and Ca/Mg ratios, are consistent with those found by Nance(2010) on the Edwards Plateau, farther west of the study area. / text

The fluctuations in solute concentrations from eight springs in the Ridge and Valley Province in northwestern Georgia were used to determine flow types and to measure each aquifer’s ability to remove contamination. The target springs are located along a northeast trending line in the Ridge and Valley Province of northwest Georgia. This study determined and interpreted the fluctuations in chemistry of each of the sampled spring’s water based upon temporal variations of precipitation in the area and variations in the chemistries measured at each weekly sampling event. Analysis determined that carbonate springs that showed characteristics of diffuse flow, including stable conductance during variable rain events and greater than zero saturation indices increase the potential for the aquifer to filter potential contaminants before the spring discharge. This study attempts to show that by identifying pre-filtered drinking water sources quickly is possible, through field and laboratory analysis.

Deep well injection into non-potable saline aquifers of treated domestic wastewater has been used in Florida for decades as a safe and effective alternative to ocean outfall disposal. The objectives of this study were to determine the fate and transport of injected wastewater at two deep well injection sites in Miami Dade County, Florida, USA. Detection of ammonium in the Middle Confining units of the Floridan aquifer above the injection zone at both sites has been interpreted as evidence of upward migration of injected wastewater, posing a risk to underground sources of drinking water. Historical water quality data, including ammonia, chloride, temperature, and pH from existing monitoring wells at both sites from 1983 to 2008, major ions collected monthly from 2006 and 2008, and a synoptic sampling event for stable isotopes, tritium, and dissolved gases in 2008, were used to determine the source of ammonium in groundwater and possible migration pathways. Geochemical modeling was used to determine possible effects of injected wastewater on native water and aquifer matrix geochemistry. Injected wastewater was determined to be the source of elevated ammonium concentrations above ambient water levels, based on the results of major ion concentrations, tritium, dissolved noble gases and 15N isotopes analyses. Various possible fluid migration pathways were identified at the sites. Data for the south site suggest buoyancy-driven vertical pathways to overlying aquifers bypassing the confining units, with little mixing of injected wastewater with native water as it migrated upward. Once it is introduced into an aquifer, the injectate appeared to migrate advectively with the regional groundwater flow. Geochemical modeling indicated that CO2 -enriched injected wastewater allowed for carbonate dissolution along the vertical pathways, enhancing permeability along these flowpaths. At the north site, diffusive upward flow through the confining units or offsite vertical pathways were determined to be possible, however no evidence was detected for any on-site confining unit bypass pathway. No evidence was observed at either site of injected wastewater migration to the Upper Floridan aquifer, which is used as a municipal water supply and for aquifer storage and recovery.

Groundwater quality in karst systems is difficult to monitor because the extreme heterogeneity within the recharge area and complex subsurface flow network makes flowpaths and travel rates difficult to predict. Understanding how flowpaths vary during storm events is important because water transmitted through conduit flowpaths can travel fast, may come from long distances, and has little filtration of contaminants. The hypothesis tested in this project is that ion ratios in spring discharge will show the timing of changes from diffuse to quick flow depending on storm intensity and antecedent conditions and provide more detail than total ion conductivity. Cedar Run Spring is located in the Cumberland Valley of south-central Pennsylvania. The valley is part of the larger Great Valley Section and is composed of Cambro-Ordovician aged carbonate units, collectively known as the Cumberland Valley Sequence. Initial background monitoring with data loggers and monthly samples indicated that Cedar Run Spring had a conduit component within the flow network. An automated stormwater sampler was installed at the spring and collected twenty-four water samples for major-ion analysis. Storm-intensity conditions ranged from high to low for the four storm events collected. In addition, the antecedent conditions varied from wet to dry. The Mg/Ca ratio characterizes the flowpath through which the water moves. A higher ratio indicates more diffuse flow because slower flow paths are needed to dissolve dolomite (which contains Mg), while a lower ratio indicates more conduit flow because calcite (Ca dominant) dissolves more readily. Hysteresis loops of conductivity versus discharge rotated counterclockwise because conductivity decreased on the rising limb of storm response, followed by an increase on the falling limb for all but the winter storm, which was influenced by road salt. In contrast, hysteresis loops for Mg/Ca versus discharge rotated in a clockwise direction for all but one of the storm events because of an increase in Mg/Ca that indicated a flush of older matrix water. The storm event that did not display in initial increase in Mg/Ca was apparently flushed by a recent previous storm event. Mg/Ca hysteresis for the storm events that were diffuse displayed several sharp increases and decrease in addition to several smaller hysteresis loops in response to multiple slugs of recharge water. These variations were not indicated in overall conductivity. High intensity events displayed a quick switch in flowpaths, as indicated by the increase in Mg/Ca early on the rising limb, and a single hysteresis loop. The rapid change in Mg/Ca suggested that during storm events water was able to enter the karst system through sinkholes, then activated flowpaths with older matrix water. Mg/Ca proved to be better at tracking the variability in flowpaths during storm events than the overall conductivity, because Mg/Ca is directly related to water-rock interactions. / Geology