<p>Surface mining is a common method of accessing coal. In high-elevation environments, vegetation and soils are typically removed prior to the blasting of overburden rock thereby allowing access to mineable ore. The removed waste rock is deposited in adjacent valleys where it may bury existing streams. Previous research, predominantly in Appalachia, has focused on downstream water quality impacts with less focus on how streamflow response and flow pathways are affected by surface mining. This study reports on how surface mining affects streamflow hydrological and chemical responses at the headwater catchment scale in the Elk Valley, British Columbia. A paired catchment approach was utilized between May and October 2012, where a reference catch- ment (Dry Creek - DC) was compared to an impacted catchment (West Line Creek - WLC), whose area is 30% covered by deposited waste rock. Hydrometrically, WLC had considerably lower flows and exhibited a damped, slower response to precipitation events than DC. Dissolved ions were an order of magnitude greater in WLC, with conductivity (SpC) ranging between 400 μS/cm at high flow to 1300 μS/cm at low flow. A strong hysteretic pattern was observed between SpC and flow and with specific ions at WLC, suggesting dilution or changing flowpaths as the season progressed. In contrast, patterns of SpC and flow at DC did not exhibit hysteresis. Major ion hydrochemistry at WLC shows dilution affecting ion concentrations whereas results at DC are consistent with chemostatic behavior. Stable isotopes were more depleted at DC compared with WLC, suggesting different sources and timing of water contributing to streamflow. Future research will work towards a conceptual model of surface mining impacts on catchment scale processes in montane environments through increased understanding of residence time and flowpath distributions at a number of impacted and reference catchments.</p> / Master of Science (MSc)