The internet is one of the most widely used mediums for communication in modern society and it has become an everyday necessity for many. It is therefore of utmost importance that it remains as secure as possible. SSL and TLS are the backbones of internet security and an integral part of these technologies are the certificates used. Certificate authorities (CAs) can issue certificates that validate that domains are who they claim to be. If a user trusts a CA they can in turn also trust domains that have been validated by them. CAs can in turn trust other CAs and this, in turn, creates a chain of trust called a certificate chain. In this thesis, the structure of these certificate chains is analysed and a longitudinal dataset is created. The analysis looks at how the certificate chains have changed over time and puts extra focus on the domains of big tech companies. The dataset created can also be used for further analysis in the future and will be a useful tool in the examination of historical certificate chains. Our findings show that the certificate chains of the domains studied do change over time; both their structure and the lengths of them vary noticeably. Most of the observed domains show a decrease in average chain length between the years of 2013 and 2020 and the structure of the chains vary significantly over the years.