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Effects of particle size, shape and density on the performance of an air fluidized bed in dry coal benefeciationChikerema, Pheneas 07 October 2011 (has links)
MSc (Eng), Faculty of Engineering and the Built Environment, University of the Witwatersrand, 2011 / Most of the remaining coalfields in South Africa are found in arid areas where process water is scarce and given the need to fully exploit all the coal reserves in the country, this presents a great challenge to the coal processing industry. Hence, the need to consider the implementation of dry coal beneficiation methods as the industry cannot continue relying on the conventional wet processing methods such as heavy medium separation. Dry coal beneficiation with an air dense-medium fluidized bed is one of the dry coal processing methods that have proved to be an efficient separation method with separation efficiencies comparable those of the wet heavy medium separation process.
Although the applications of the fluidized bed dry coal separator have been done successfully on an industrial scale, the process has been characterized by relatively poor (Ecart Probable Moyen), Ep values owing to complex hydrodynamics of these systems. Hence, the main objectives of this study is to develop a sound understanding of the key process parameters which govern the kinetics of coal and shale separation in an air fluidized bed focusing on the effect of the particle size, shape and density on the performance of the fluidized separator as well as developing a simple rise/settling velocity empirical model which can be used to predict the quality of separation.
As part of this study, a (40 x 40x 60) cm air fluidized bed was designed and constructed for the laboratory tests. A relatively uniform and stable average bed density of 1.64 with STDEV < 0.01 g/cm3 was achieved using a mixture of silica and magnetite as the fluidizing media. Different particle size ranges which varied from (+9.5 -16mm), (+16 -22mm), (+22 -31.5mm) and (+37 -53mm) were used for the detailed separation tests. In order to investigate the effect of the particle shape, only three different particle shapes were used namely blockish (+16 -22mm Blk), flat (+16 -22mm FB) and sharp pointed prism particles (+16 – 22mm SR).Different techniques were developed for measuring the rise and settling velocities of the particles in the bed.
The Klima and Luckie partition model (1989) was used to analyze the partition data for the different particles and high R2 values ranging from (0.9210 - 0.9992) were recorded. Average Ep
iii
values as low as 0.05 were recorded for the separation of (+37 -53mm) and (+22 -31.5mm) particles under steady state conditions with minimum fluctuation of the cut density. On the other hand, the separation of the (+16 -22mm) and (+9.5 – 16mm) particles was characterized by relatively high average Ep values of 0.07 and 0.11 respectively. However the continuous fluctuation or shift of the cut density for the (+9.5 -16mm) made it difficult to efficiently separate the particles. Although, particle shape is a difficult parameter to control, the different separation trends that were observed for the (+16 -22mm) particles of different shapes indicate that particle shape has got a significant effect on the separation performance of the particles in the air fluidized bed.
A simple empirical model which can be used to predict the rise/settling velocities or respective positions of the different particles in the air fluidized bed was developed based on the Stokes’ law. The proposed empirical model fitted the rise/settling data for the different particle size ranges very well with R2 values varying from 0.8672 to 0.9935. Validation of the empirical model indicate that the model can be used to accurately predict the rise/settling velocities or respective positions for all the other particles sizes ranges except for the (+9.5 – 16mm) particles where a relatively high average % error of (21.37%) was recorded.
The (+37 -53mm) and (+22 -31.5mm) particles separated faster and more efficiently than the (+16 -22mm) and (+9.5 -16mm) particles. However, the separation efficiency of the particles can be further improved by using deeper beds (bed height > 40cm) with relatively uniform and stable bed densities. Prescreening of the coal particles into relatively narrow ranges is important in the optimization of dry coal beneficiation using an air fluidized bed since different optimum operating conditions are required for the efficient separation of the different particle size ranges and shapes. The accuracy and the practical applicability of the proposed empirical model can be further improved by carrying out some detailed rise/settling tests using more accurate and precise equipment such as the gamma camera to track the motion of the particles in the fluidized bed as well as measuring the actual bed viscosity and incorporate it in the model.
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The development of binderless, smokeless briquettes from bituminous colliery wasteEngland, Trevor January 1993 (has links)
A project report submitted to the Faculty of Engineering,
University of the Witwatersrand, Johannesburg in partial
fulfilment of the requirements for the degree of Master of
Science in Engineering
Johannesburg, 1993 / Superfines of less than 200 micron are generated when mining coal. They have not been successfully beneficiated in the past and are not acceptable to the consumer.
A processh as been developed whereby the superfines are beneficiated, briquetted without the use of binders and devolatilised to produce a premium smokeless briquette which will attract a premium price in the export market. [Abbreviated abstract. Open document to view full version] / MT2017
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Development of a dust exposure level index (Deli) for South African underground coal mine workersBelle, Bharath Kumar 17 November 2006 (has links)
Faculty of Engineering and the Built Environment,
School of Mining / Inhaling excessive amounts of respirable coal dust will lead to work-related lung disease
commonly known as Coal Worker’s Pneumoconiosis (CWP) or black lung. Prevention and
control of CWP requires accurate knowledge of the dose-response relationship to set-up and
review occupational exposure limits (OELs), which do not exist in SA. Due to historical
reasons, poor emphasis of occupational health on the mines resulted in inadequate exposure
data in SA. The new Mine Health and Safety Act (1996) overcame the deficiencies of the
past and require quantifying the dust exposure and efficiency of dust control measures, and
continuous risk assessments for dust exposure.
The current method of exposure assessment is expressed using an Air Quality Index (AQI)
which is the ratio of the measured dust level and OEL of coal dust. The difficulties with the
usage of AQI are poor descriptions of dust problem areas and its magnitude, poor quality of
the data leading to “no dust problem situation” and failure to extract information on ‘dose in
milligram’ to relate them to the disease rate. Gravimetric size-selective dust sampling was
introduced for the first time in 1990 in SA. Due to the lack of critically important coal dust
exposure data available, this thesis has set out to examine several critical exposure related
parameters and determine dust levels underground.
This research study had the objective of the development of a pragmatic diagnostic tool
(method) called the Dust Exposure Level Index (DELI) to evaluate the exposure of workers.
The DELI incorporates a set of controllable parameters and influential areas and prioritises
them to manage and reduce the worker exposure. The DELI model was to provide critical
information as an index, i.e., to show whether the environment is dusty, border line or
relatively free of dust and effectiveness of administrative and engineering dust control
measures. The research work in this thesis has led to very explicit conclusions, which were
based on extensive dust measurements in various coal mines over a five year period.
Conclusions obtained for the various sets of controllable parameters used in the DELI model
are as follows:
1. A previous analysis of the dust data during 1990 indicated that the dust levels have
increased with mechanisation. The contamination of coal dust samples due to stone
dusting can result in high dust levels giving a “false” indication of the efficiencies of
the dust-control systems.
2. The dust exposure levels during coal cutting indicated that a worker positioned inside
the cabin of a CM during the cutting of a 24 m coal block is at a higher dust exposure
risk than the worker when cutting a 12 m coal block. Also, the miner who is operating
in a heading is exposed to higher dust exposure risk than in a split.
3. The analyses of measured real-time dust data showed a clear relationship between the
average dust levels and the frequency of occurrence of “peak” dust levels. The study
demonstrated a clear method of using real-time dust data for assessing exposure.
4. The average measured section intake dust level was 0.80 mg/m3 and 60 % of the
collected data exceeded the 0.5 mg/m3 limit indicating that this is a base dust level to
which the worker is exposed without carrying out any additional work in the section.
5. The average measured section return dust level was greater than 2.0 mg/m3 indicating
the high exposure levels of workers, and ineffectiveness of the ventilation and dustcontrol
systems.
6. The results of this research study indicated that there is no conclusive relationship
between the rate of coal production and respirable dust levels. Also, the type of dust
control system used has pronounced effect on dust levels in the sections. The capture
efficiency of any dust control system is not one hundred percent at any given time.
During any cutting process for a given time and dust control type, part of the escaped
respirable dust is added to the coal face atmosphere through air re-circulation.
Therefore, respirable dust levels can be expected to increase with time during the
shift, even at constant production levels.
7. A limited number of particle size analyses have indicated that there is no clear
relationship between the dust concentration in mg/m3 and total surface area (m2) of the
respirable dust sample.
8. For the first time, a clear delineation of coal types (semi-bituminous and semianthracite)
that possess the most inherent respirable dust generation potential
(IRDGP) was possible (p = 0.000). Also, there was no conclusive relationship
(p = 0.373) between different semi-bituminous coal seams (1, 2, 4 and 5) and IRDGP.
9. The laboratory roll-crusher test results of South African coal types indicated that
average inherent silica for the test coals was 3.54 %.
The DELI model took into account, the merits of personal exposure data in exposure
assessment, but the limitations and quality of data one obtains in the South African situation
overweighed use of the fixed-point sampling. The “limits of acceptability” used in DELI are
based upon acceptable guidelines prescribed by the authorities such as National Institute of
Occupational Safety and Health (NIOSH), Mine Safety and Health Administration (MSHA),
South African Department of Minerals and Energy Affairs (DME) and latest information on
epidemiological studies. The DELI model gives the visual “colour” coding and descriptive
categories for easy interpretation and understanding of exposed dust level to uneducated
workforce. This type of DELI index representation gives a clear and concise picture of the
mine or various section dust conditions. The DELI model exposure assessment technique
gives accurate feedback because it was based on latest recommended size-selective
sampling methods and instrument and vast amount of measured data, which was not
previously available. The application of the developed DELI model for exposure assessment
and its comparison with AQI were evaluated for coal mine dust data. The study
demonstrated that the DELI model is a practical diagnostic tool that gives a fair reflection
and information on dust levels and is an exposure assessment tool for the coal mining
industry that will assist in reduction of CWP in South Africa.
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A systematic approach to fireside boiler tube investigationsBroodryk, Gideon Jacobus 31 August 2016 (has links)
Submitted for t he
MASTERS OF SCIENCE
Chemistry
in the
Department of Chemistry
UNIVERSITY of the Witwatersrand
December 1995
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Titanium dioxide-carbon spheres composites for use as supports in cobalt Fischer-Tropsch synthesisPhadi, Thabiso Terence 14 February 2013 (has links)
Fischer-Tropsch (FT) synthesis is a reaction which entails the conversion of
synthesis gas, also known as syngas (a mixture of H2 and CO gases), to liquid
hydrocarbon fuels, oxygenated hydrocarbons, chemicals and water. This syngas
mixture is obtained from natural gas, coal, petroleum, biomass or even from
organic wastes. In this study cobalt catalysts supported on novel carbon spheretitania
(CS-TiO2) composite materials were synthesized and tested for their
performance in the FT process.
Initially carbon spheres (d = 80-120 nm) were prepared in a vertical swirled
floating chemical vapour deposition reactor without the use of a catalyst. The rate
of production was controlled and the highest production rate of about 195 mg/min
was obtained at an acetylene (C2H2) flow rate of 545 mL/min at 1000 °C. The
produced carbon spheres (CSs) had a narrow size distribution with a uniform
diameter size. Purification and functionalisation of the CSs improved the total
surface area, due to the removal of PAHs which blocked the CS pores. The
introduction of functional groups to the CSs was achieved and these changed the
wetting properties of the CSs. Functionalising the CSs for longer than 17 h in
HNO3 destroyed the morphology of the CSs.
After successful preparation of functionalised CSs, the interactions between CSs
and TiO2 were studied by in the TiO2 composite using two different sol-gel
methods, namely the conventional sol-gel and the surfactant wrapping sol-gel
method. The surfactant wrapping sol-gel method entailed the modification of the
CSs by dispersing them in a surfactant, in this case hexadecyltrimethylammonium
bromide or CTAB [(CH3(CH2)15N(CH3)3Br]. This introduced alkyl “tails” which
eased the dispersability of the CSs before coating them with Ti[O(CH2)3CH3]4 (a
source of TiO2) to produce a homogeneously coated CS-TiO2 composite material
(defined as ASW3). It should be mentioned that many, many experiments were
performed to develop an efficient and reliable method to make homogeneously coated CS-TiO2 composites since it was found to be very difficult to achieve an
interaction between carbonaceous materials and TiO2 especially by sol-gel
procedures.
The traditional sol-gel method was used to prepare CS-TiO2 composites with
different ratios viz. 1CS-1SG, 1CS-2.5SG, 1CS-5SG, 1CS-10SG, 1CS-25SG and
1CS-50SG. These composites showed weak interactions between CSs and TiO2
even at high TiO2 loading ratio. Interestingly the surface area of these composites
showed high values of 80 and 85 m2/g for 1CS-5SG and 1CS-10SG, respectively.
At lower TiO2 ratios the measured surface area was similar to that of CSs, i.e 10
m2/g for 1CS-1TiO2. At high TiO2 ratios the measured surface area was similar to
that of TiO2, i.e 49 m2/g for 1CS-50TiO2.
The TEM images of CS-TiO2 (ASW3) composites prepared by surfactant
wrapping methods showed a successful TiO2 coating of CSs. The TiO2 grain size
was 8.0 nm with both anatase and rutile phases. High surface areas (up to 98
m2/g) of composite materials were achieved by employing this procedure. The
high surface areas achieved suggest that the interaction between CSs and TiO2
was homogeneous and the increase was due to the “bridge” formed between CSs
and TiO2.
A series of cobalt catalysts (10% by weight) supported on these materials was
carried out by the deposition precipitation method using Co(NO3)2·6H2O as the
metal precursor. After appropriate drying and calcination the catalysts were
characterized using traditional characterisation techniques and tested in the FT
reaction using a fixed bed reactor. The the 10%Co/CS catalyst produced a CO
conversion of 15.2% while the catalyst had a low total BET surface area (6 m2/g)
compared to non-carbonaceous catalysts with higher BET surface areas. This
observation suggests that the surface area did not necessarily play a role in the CO
conversion, but that other properties (reducibility and dispersion) of CSs
influenced the catalyst activity. After coating CSs with TiO2 and loading cobalt to
produce 10%Co/ASW3 both the BET surface area of the catalyst and the CO conversion increased to 83 m2/g and 20.1%, respectively. CO-TPD of
10%Co/ASW3 showed a large amount of strongly adsorbed CO. This increased
CO was due to the interaction between CSs and TiO2 which developed CO
adsorptive sites.
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Alternative methods for coal resource classification of the geologically complex Witbank CoalfieldMagnus, Elaine Elizabeth January 2017 (has links)
A research report submitted in partial fulfilment of the requirements for the degree of
Master of
Science in Engineering (Mining)
to the faculty of engineering and the built environment, University of the Witwatersrand,
Johannesburg
Date of final submission 25 May 2017 / The Australasian code for Reporting of Exploration Results, Mineral Resources and Ore Reserves, of the Joint Ore Reserves Committee (JORC) sets out minimum standards, recommendations and guidelines for Public Reporting in Australasia. (JORC, (2012)). The Committee for Mineral Reserve International Reporting Standards (CRIRSCO) created a set of standard international definitions for reporting Mineral Resources and Mineral Reserves based on the evolving JORC code’s definitions (CRIRSCO, (2013)).
CRIRSCO’s members are National Reporting Organisations (NRO’s) which are responsible for developing mineral reporting codes for Australia (JORC), Canada (CIM Standing Committee on Reserve Definitions), Chile (National Committee), Europe (PERC), Russia (NAEN), South Africa (SAMCODES) and USA (SME) (JORC, (2012)).
The NRO’s for; South Africa (SAMREC), Australia (JORC) and Canada (CIM Standing Committee on Reserve Definitions) published supporting standards for Coal Resource and Reserve Classification and Reporting namely, South African National Standard: South African Guide to the Systematic Evaluation of Coal Resources and Coal Reserves (SANS10320:2004), the Australian Guidelines for the Estimation and Classification of Coal Resources (Australian Guidelines (2014)) and the GSC Paper 88-21: A Standardized Coal Resource/Reserve Reporting System for Canada (Hughes, et al., (1989)).
With the objective to identify the most appropriate Coal Resource Classification approach for the Witbank Coalfields in South Africa, Coal Resource Classification methods applied elsewhere in the world were investigated, these countries include Canada and Australia.
SANS10320:2004 relies on a minimum drillhole spacing dependant on two different coal seam deposit types, whereas the Australian Guideline for the Estimation and Classification of Coal Resources (2014) provide a guide as to which geological aspects need to be considered when classifying a coal deposit into the appropriate confidence category, and no fixed drillhole spacing is recommended. The Canadian Standardized Coal Resource/Reserve Reporting System (1989) differs from the afore mentioned standards in that it is a prescriptive method based on specific levels of geological complexity, governed by specific fixed parameters. None
of the other Coal Reporting codes/standards use a broad sweeping fixed drillhole spacing to classify Coal Resources as in South Africa.
It is noted from experience as well as by Coal Resource Classification methods used elsewhere in the world that the use of proposed fixed drillhole spacing, such as currently in use in SANS10320:2004, is an unsatisfactory method for assessing the uncertainty and variability associated with coal deposits. The Coal Resource Classification methodologies utilised on a local scale in South Africa, were investigated to establish how mining houses manage and assess the variability in their Coal Resources. Fourteen mines operating throughout the Witbank coalfield were compared, it was found that although the Coal Resource Classification of the governing code requires a 350m drillhole spacing for highest level of confidence, the mines drill to a much smaller grid for increased confidence. Despite this, the mines still report on the SANS10320:2004 minimum standard in the public domain. A map was created based on the average drillhole spacing drilled per mine. From this it was deduced that there are zones of higher coal seam variability which required a closer spaced drilling grid to derive sufficient geological confidence in the estimates. Based on these deductions four zones of comparable continuity/variability, were identified. The zones identified by means of geological investigation and those identified by differences in variability as perceived by the Competent Person (CP) correlate. The highest variability and smallest drillhole spacing is located toward the western portion of the coalfield whereas the lowest variability with the largest drillhole spacing is located toward the east.
The geologically complex Witbank coalfield was divided into four geo-zones/domains based on the depositional environment, basement rocks and post depositional influences. It is evident that a suitable Coal Resource Classification approach; which considers the characteristics of the geozones are followed. The question of which other classification methods are appropriate if not a predetermined drillhole spacing is addressed by this research.
Statistics on relevant variables can provide a measure of uncertainty and therefore reliability in the estimates, for this reason three methods of uncertainty and probability characterisation were investigated. Of the three, namely; Non-linear estimation approach, conditional simulation (CS) and global estimation variance (GEV), the latter was deemed the most appropriate. GEV forms the basis of Drillhole Spacing Analysis (DHSA) and was applied
to a mid-sized coal mine within the western portion of the Witbank coalfield. The analysis did not result in robust Coal Resource classification of estimates but rather provided more insight into the variability of the deposit. The results of DHSA are easily manipulated and are open for interpretation, it is therefore suggested as a valuable exercise/tool for understanding and assessing coal seam variability and to be used as a guide in Coal Resource classification.
Onsite practical geological information should not be underestimated and geostatistics should always confirm the geology. A purely mathematical approach to Coal Resource classification would be a gross oversight, a combination of geological factors in association with statistical inferences is suggested. A scorecard method with associated weights is proposed to improve the confidence in the Coal Resource classification. / MT 2017
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Development and evaluation of a dense media cyclone for the Southern African mineral and coal industriesSingleton, J. D. 25 February 2014 (has links)
Dense media separation (DMS) plays an integral part in coal processing as well as in the upgrade
of low grade ore bodies prior to further processing like flotation and leaching. Various
separating vessels are used in DMS; of which the dense media (DM) cyclone is the most
common. However, the limited materials of construction available for DM cyclones leave the
industry with little choice. In addition, the DM cyclones available moved away from the basic
principles of classification hydrocyclones which is to reduce the turbulence in the feed chamber
in order to achieve improved efficiency. The ceramic tiled DM cyclones available in the market
have ceramic tiles installed perpendicular to each other in the feed chamber, which increase the
turbulence in the feed chamber at the expense of longer equipment life. For that reason, a
research project was initiated to establish the current installed base of DM cyclones in Southern
Africa and to develop and evaluate a DM cyclone with a laminar spiral feed chamber design to
reduce the turbulence when feeding the cyclone, whilst achieving the same or superior wear
properties.
Because Cavex is well proven in hard rock mining and coal classification, it was used as basis for the development of a DM cyclone. Individual moulds were developed and produced in order
to fabricate a Cavex DM cyclone with the exact laminar spiral feed chamber that exists when
moulded out of rubber. Afterwards, the Cavex ceramic tiled (CVXT) cyclone was manufactured,
installed and commissioned. Using the basic operating principles of hydrocyclones, the
predicted results were achieved. The 650CVXT results confirmed that a DM cyclone and a
classification cyclone are inherently the same piece of equipment; it is the selection criteria and
material of construction that differ. There is a definite benefit in focussing on metallurgical
efficiency in conjunction with wear properties, rather than equipment life (wear life) as the only
parameter during equipment fabrication. A simple way to achieve improved performance is to reduce the turbulence in the feed chamber. Further work must include the evaluation of the Cavex CVXT DM cyclone in near gravity coal
circuits and to investigate whether the same lower operating pressures (6D compared to
conventional 9D) will result in improved coal yield, as was illustrated successfully in the
separation of fluorspar by DMS, whilst achieving the desired ash contents. The work must
include detailed studies on the effect of feed pressure vs. yield/recovery, when the turbulence the feed chamber is reduced. Overall energy savings should be quantified by reducing the cyclone feed pressure.
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Coal-based linkages and development in Mozambique: a political economy perspectiveSelemane, Tomás Mário 29 January 2015 (has links)
Thesis (M.Com. (Development Theory and Policy))--University of the Witwatersrand, Faculty of Commerce, Law and Management, School of Economic and Business Sciences, 2014. / Mozambique is currently moving from an aid dependent country to mineral dependent given the
mining boom happening there thanks to the discoveries of huge reserves of coal, mineral sands
and natural gas. The country is set to become one of the world's twenty top producers of natural
gas and top ten largest producers of coal.
This research is a case study focusing on coal-based linkages that can foster broad economic
growth and development in Mozambique. Using a political economy perspective, the research
investigates the question about how the country can optimise the mining boom through coalbased
economic linkages to foster broader socio-economic development.
The research finds that under the combination of its current fiscal and mineral regime with
infrastructure problems plus the inexistence of a coal-based linkage policy, Mozambique will get
negligible benefit from the exploitation of its finite coal resources. A major overhaul of these
regimes is needed for it to make use of its coal to catalyse wider growth and development, before
it is left with little other than large holes in the ground.
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Respirable quartz in coal mines in the Mpumalanga region of South Africa over the period 2002 to 2006Doyle, Bruce Anthony 16 April 2010 (has links)
MPH, Occupational Hygiene, School of Public Health, Faculty of Health Sciences, University of the Witwatersrand, 2009 / Introduction:
By 2030 silicosis should be eliminated in South Africa. This statement was made by
the Labour Minister, Mr. Membathisi Mdladlana on 28 June 2004 during the launch of
the National Programme for the Elimination of Silicosis in Johannesburg. Following
this launch the mining industry set its own milestone, which is to eradicate this disease
by 2014. Historically research has generally focused on the health effects associated
with exposures to coal dust, whilst limited work has been done on personal exposures
to respirable crystalline silica (commonly known as quartz), which is the main cause of
silicosis in the mining industry. Given the number of people that are involved in coal
mining, together with the seriousness of diseases associated with respirable quartz
exposure, such as silicosis and tuberculosis, it is important to quantify these
exposures. The aim of this study was to ascertain the magnitude of employee
exposures to respirable quartz, in the Mpumalanga region of the South African coal
mining industry, over the period 2002 and 2006.
Objectives:
The objectives of this study are:
• To describe respirable quartz concentrations in 41 coal mines in the
Mpumalanga region of South Africa over the period 2002 to 2006;
• To compare respirable quartz concentrations in nine magisterial districts of the
Mpumalanga region of South Africa over the period 2002 to 2006, to the South
African Occupational exposure limit of 0.1 mg/m3 and the American Congress
of Governmental Industrial Hygienists (ACGIH) Threshold Limit value of
0.025 mg/m3;
• To describe twenty four activity areas in 41 coal mines in the Mpumalanga
region of South Africa, over the period 2002 to 2006, which exceed 50 % of the
South African Occupational exposure limit of 0.1 mg/m3 (generally referred to
as the action limit).
3
Methodology:
The study setting comprises the workings of coal mines within the Mpumalanga
region, where various types of occupations exist. The research conducted consisted
of a descriptive study of retrospective respirable Time Weighted Average quartz
concentration results obtained from mines that use the company Colliery
Environmental Control Services (CECS) as their occupational hygiene service
provider. CECS provided the data that was analysed for this research. Sample
collection and analysis for respirable quartz was done using widely accepted
International methodologies.
Results:
The overall median respirable quartz concentration for all mines were 0.007 mg/m3,
whilst the mean was 0.038 mg/m3. The highest respirable quartz concentration
measured was 2.197 mg/m3 and the lowest 0.000 mg/m3. The majority of the mines,
i.e. 30, are situated in the Kriel, Secunda and Witbank magisterial districts, these
districts account for 78 % of the total number of measurements taken. A total of 191
measurements (8 %) and 674 (29 %) exceeded the South African OEL of 0.1 mg/m3
and ACGIH TLV of 0.025 mg/m3 respectively with the Secunda district having the
most measurements that exceeded both sets of limits (58 and 205 respectively). The
majority of measurements, i.e. 1784 (76 %), were from six activity areas and four
hundred and ninety one (21 %) of the total measurements taken were from the
continuous miner activity area. The highest ranked activity area is the longwall mining
one, which has a median respirable quartz concentration of 0.044 mg/m3. The highest
respirable quartz concentration, 2.197 mg/m3, was measured in the roving plant
activity area, which was followed by measurements of 1.706 mg/m3 and 1.528 mg/m3
in the continuous miner and unknown activity areas respectively. The longwall mining
activity area recorded the most measurements that exceeded the 50 % action limit
and 0.1 mg/m3 OEL, these been 47 and 38 respectively.
4
Discussion and Conclusion:
This research report describes similar exposure findings as has been reported
internationally. Persons employed in the high risk activity areas on the 41 mines
studied over the period 2002 to 2006 in the Mpumalanga region are at risk of
developing quartz-associated diseases, such as silicosis.
Recommendations:
It is recommended that the effectiveness of implemented interventions need to be
investigated and appropriate intervention strategies be implemented. Airborne quartz
contents from the nine magisterial districts and 24 activity areas should be analysed
and individual samples taken from the high risk tasks should be individually analysed
for their percentage airborne quartz content.
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Effect of fly ash composition on the synthesis of carbon nanomaterialsMatshitse, Refilwe Manyama Stephina 10 May 2016 (has links)
A dissertation submitted to the Faculty of Science, University of the Witwatersrand,
Johannesburg, in fulfilment of the requirements for the Degree of Master of
Science.
Johannesburg, 2015. / Fly ash is a by-product generated during the combustion of coal for electricity gen-
eration. Previous studies have shown that various waste fly-ashes (Japanese, Saudi
Arabian, and Australian) contain trace quantities of transition metal elements which
can be used in the synthesis of shaped carbon nanomaterials. A survey of the litera-
ture has shown that no attempts to correlate the composition of a particular coal fly
ash and the type or quantity of carbon nanomaterials (CNMs) that can be synthesized
has been made. Neither has the effect of leached fly ash been tested for the synthesis
of CNMs. Hence a study on the effect of the chemical composition of South African
fly ash (collected from ESKOM’s Duvha power station in Mpumalanga) upon the
chemical vapour deposition (CVD) synthesis of carbon nanostructures is justified.
Untreated and chemically treated fly ash samples were used as catalysts in the CVD
method to synthesize CNMs. In the latter case selective leaching experiments were
conducted on the fly ash samples under acidic, basic and neutral conditions. Op-
timal CNM synthetic conditions were achieved by initially flowing H2 gas to re-
duce the metal oxides within the fly ash catalyst followed by the introduction of
the carbon source (C2H2) at a temperature range of 600 - 800 ◦C. All samples were
quantitatively and/or qualitatively characterized. Inductively coupled plasma optical
emission spectrometry (ICP-OES) and X-ray fluorescence (XRF) techniques were
used to quantify the metal ions which were removed from the fly ash samples. Fur-
thermore, qualitative studies were conducted with (PXRD, and laser Raman spec-
troscopy), morphological and surface area characterization techniques (SEM, TEM
and BET) were used to investigate the synthesis of CNMs from the untreated and
chemically treated fly ash samples.
Results have shown that carbon nanofibers (CNFs) of different geometric morpholo-
gies were synthesized at an optimal yield temperature of 700◦C. A combination of
smooth, thin, wide, spiral platelet-like, stacked cup, and fishbone morphologies were
reported when the untreated fly ash catalyst was used. Fly ash catalysts under acidic,
basic and neutral treatments showed CNFs of varying sizes and specific morpholo-
gies. Smooth graphitic platelet-like, stacked cup and platelet-like CNFs were re-
ported when the fly ash catalyst was leached with neutral, basic and acidic solutions.
Carbon nanofibre sizes with the IG
ID
ratios were reported as follows 115 nm (1.092),
52 nm (0.799), and 200 nm (0.960) under neutral, basic and acidic mediums respec-
tively. Surface areas (41, 14 and 7) m2/g for the CNFs that were synthesised from
the neutral, basic and acidic treated fly ash catalysts were related to the selective
leaching of metals.
The quality and quantity of CNFs obtained under acidic medium were associated
with the leaching of iron (5.6%), cobalt (1.7%), calcium (20.4%), copper (12.5%),
chromium (4.6%), magnesium (23.3%), manganese (15.2%) and nickel (2%) from
the fly ash catalyst. Under a basic medium only chromium (0.2%), calcium (0.3%)
and copper (7.4%) were removed. Significantly the best quality of CNFs was ob-
tained when fly ash was treated under neutral conditions. Metal ions such as: cal-
cium (3.7%), copper (3.8%), chromium (0.1%), and magnesium (1.3%) were mod-
erately removed from the ash matrix. Therefore, composition and quantity of the fly
ash catalyst had an effect on the synthesis of CNFs.
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