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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Síntese de ligas à base de Cu-Ni-Ag de alta condutividade elétrica

Luongo, Leilah Delaretti 22 May 2015 (has links)
Made available in DSpace on 2016-03-15T19:36:50Z (GMT). No. of bitstreams: 1 Leilah Delaretti Luongo.pdf: 2162579 bytes, checksum: 76c30f5d2ee2f42b33cf84bd04999ac2 (MD5) Previous issue date: 2015-05-22 / In this work, samples of copper-silver and silver-copper-nickel alloys were synthesized by powder metallurgy. The alloys have received sintering and all of them were characterized metallographically. Different and significant effects were observed in the microstructure and conductivity of the samples studied. The influence of silver on the conductivity of the samples with nickel resulted to be lower than the alloy with chromium and nickel, studied in previous work of the research group, where the same procedures were applied to the same precursors. An interesting result is that the larger crystallite size favored the high electrical conductivity, which is presented in the samples without nickel. The presence of nickel helped to inhibit oxidation and the difference in the amount of nickel influenced the alloys behavior, however, it did not guarantee high conductivity observed in the aforementioned alloys copper-nickel-chromium. The structure of the samples was studied by the Rietveld Method, using data from x-ray diffraction. The differences in microstructure were investigated by comparing the parameters of the pure copper used as a precursor profile. / Neste trabalho foram sintetizadas amostras de ligas metálicas de cobre-prata e cobre-níquel-prata obtidas por metalurgia do pó. As ligas receberam tratamentos térmicos de sinterização e foram caracterizadas metalograficamente. Foram observados efeitos diferentes e significativos na microestrutura e na condutividade das amostras estudadas. A influência da prata na condutividade das amostras com níquel resultou ser inferior à de ligas com cromo e níquel, estudadas em trabalhos precedentes do grupo de pesquisa, onde se aplicaram os mesmos procedimentos aos mesmos precursores. Um resultado interessante é que o maior tamanho de cristalito favoreceu a condutividade elétrica, o qual se apresentou nas amostras sem níquel. A presença do níquel ajudou a inibir a oxidação e a diferença na quantidade de níquel se mostrou importante no comportamento das ligas, porém, não garantiu a alta condutividade verificada nas mencionadas ligas de cobre- níquel-cromo. A estrutura das amostras foi estudada pelo Método de Rietveld, usando dados de difração de raios x. As diferenças na microestrutura foram estudadas através da comparação com os parâmetros de perfil do cobre puro usado como precursor.

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