Alpha matting is one of the key techniques in image processing and is used to extract accurate foreground from a still image or video sequences. Chroma keying is a special case of alpha matting with a solid background color. Color spill is one of the difficulties in chroma keying, and it has not been effectively solved by current methods. Sometimes, an image contains both reflected regions and transparent regions. When the foreground in such images is chroma keyed, reflection on the foreground is often falsely treated as transparency and causes unreal foreground extraction and composition. This problem is called color spill. Color spill suppression aims to extract the opaque foreground with the correct transparency descriptor (i.e. alpha value) and remove the reflected background color on it. When the background color presented on the foreground is simultaneously caused by reflection and transparency, color spill suppression becomes extremely challenging. It is because that the reflection removal and the actual transparency estimation is a dilemma. Our proposed method for color spill suppression is to separate reflected regions from transparent regions, and process reflected regions as foreground while keeping transparency unchanged at the same time. In this thesis, we propose a novel method for color spill suppression for chroma keying. The quality of the estimated alpha matte could be significantly improved. In our approach, we suppress color spill by using the polarization and the optical flow algorithm based on disparity estimation. Specifically, we make the assumption that reflection changes more than transparency when the scene is captured by a binocular camera with a polaroid filter. Based on this assumption, we took stereo images with polarization filter, registered stereo images by optical flow and conducted the variance analysis on histograms of input images to separate transparency and reflection. Our experiments show that the opaque foreground with background color spill can be reliably extracted while the real transparency can be kept.