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Voltametrická a amperometrická detekce genotoxických derivátů pyrenu pomocí bórem dopované diamantové filmové elektrody / Voltammetric and amperometric detection of genotoxic pyrene derivatives at boron-doped diamond film electrodeYosypchuk, Oksana January 2010 (has links)
This thesis is concentrated on the optimization of conditions for determination of genotoxic environmental pollutants whitch belong to derivatives of polycyclic aromatic hydrocarbons − 1-nitropyrene (1-NP), 1-aminopyrene (1-AP) and 1-hydroxypyrene (1-HP). All three compounds were determined by differential pulse voltammetry (DPV) at boron-doped diamond film electrode in water-methanolic solutions. Further, 1-AP and 1-HP were determined in a model sample of urine. For this purpose, effective separative techniques such as solid phase extraction and high performance liquid chromatography with reverse phase and amperometric detection at above mentioned type of electrode were used. Limits of detection of all tested compounds in water-methanolic solutions are 9⋅10−8 −3⋅10−7 mol dm−3 using DPV and 1⋅10−8 mol dm−3 for 1-HP and 1-AP in model sample of urine determined by HPLC with amperometric detection.
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Totalsynthese der Mansouramycine A-E aus Streptomyces sp. und Rhodium-katalysierte 1,2-Additionen an cyclische Enone / Total synthesis of Mansouramycine A-E from streptomyces sp. and rhodium catalized 1,2-additions to cyclic enonesBeerlink, Johannes 14 October 2008 (has links)
No description available.
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