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Light-emitting hetero-cyclic polymers containing 2, 3, 4, 5- tetraphenylthiophene moietyYang, Cheng-Hsien 16 August 2002 (has links)
Polymers containing bulky tetraphenylthiophene (TP) moieties were prepared by different coupling reactions. Firstly, 2,5-bis(4-bromophenyl)-3,4-diphenylthiophene (TP-Br) was coupled together by either NiCl2/PPh3 or n-BuLi to form polymers with TP as the repeat unit. The resulting polymers (PTP-NiCl2 and PTP-BuLi) are easily soluble in organic solvents and are photoluminescent (PL) materials (
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