Thesis advisor: Rudolph Hon / The application of road de-icers has lead to increasing solute concentrations in surface and ground water across the northern US, Canada, and northern Europe. In a public water supply well field in southeastern Massachusetts, USA, chloride concentrations in ground water from an unconfined aquifer have steadily risen for the past twenty years. The objectives of this study are to understand spatial and temporal trends in road salt concentrations in order to identify contamination sources and fate. To this end, the methods of this project include field and lab work. Water samples were collected from surface, near-surface, and ground water from March 2012 to March 2013. The other major field data are specific conductance measurements from probes located in three piezometers. In the lab, all samples were analyzed for major ions with ion chromatography analysis. Additionally, trace elements were measured by inductively coupled plasma analysis on a subset of samples. The results of these hydrogeochemical procedures showed several important trends. First, the highest concentrations of sodium and chloride from near-surface samples were located near to roadways. Second, ground water samples taken from glacial sediments contained relatively high concentrations throughout the water column, whereas ground water samples from wetlands had high concentrations only near the surface. Third, there was no clear relationship between pH and cation concentrations. Finally, specific conductance data showed strong seasonal trends near to the surface, whereas values taken from deeper in the aquifer were steadily increasing. Based on these results, it is highly probable that road salt application is the dominate contamination source. The pathways of road salt in the watershed include runoff into surface water and infiltration into the vadose zone and ground water. Road salt appears to preferentially travel through glacial features rather than floodplain features. It is possible that sodium from road salt is sorbed to aquifer sediment and displaces other cations. However, the low values of trace metals suggest that cation exchange is not mobilizing heavy metals. Finally, the increasing specific conductance values deep in the aquifer suggest that road salt is retained within the aquifer and concentrations will likely increase in the future if the current road salt application procedures are continued. / Thesis (MS) — Boston College, 2013. / Submitted to: Boston College. Graduate School of Arts and Sciences. / Discipline: Earth and Environmental Sciences.

Mechanically Stabilized Earth (MSE) wall is a civil structure that has been used for various purposes e.g., supporting bridges, residential or commercial buildings, roadways, railroads etc. In general, MSE wall uses either metal strip, bar or geosynthetics materials as reinforcement. Roger et al. (2010) mentioned that an approximately 57% of the MSE wall constructed in U.S. utilize steel strips as the resources of reinforcement. The usage of metal steel strips is followed by usage of steel bar mats (24%) and geosynthetics grids (18%). Even though MSE walls are designed for a service life of 75 to 100 years, early complication has often been reported. Corrosion of the reinforced steel has been the major cause that afflicts the long-term performance of these walls. The deicing salts used on pavements to melt down snow is one of the major cause of corrosion of these reinforced steels. The aggressiveness of deicers in terms of corrosion of these reinforced steel is studied through the potentiodynamic polarization technique at various concentrations. This study aims to determine the corrosion behavior on galvanized steel and bare steel in presence of individual deicing salt or deicers e.g., sodium chloride, calcium chloride, magnesium chloride and potassium acetate at various (i.e., 0.25, 0.50 and 1.0 M) concentration. Subsequently, the surface morphology was analyzed by using Scanning Electron Microscopy (SEM) and the mineralogical composition was observed through X-Ray Diffraction (XRD). In addition, the corrosivity of two backfill aggregates, natural aggregate and recycled concrete aggregate, was compared. The result shows that the corrosion effect of deicers on reinforced steel depends on its chemical composition and concentration. The SEM imaging showed the presence of micro cracks on the surface of galvanized steel, resulting in pitting corrosion rather than general surficial corrosion. Comparing the corrosion rate of these deicers, the aggressiveness of these deicers on galvanized steel can be arranged in the following order: sodium chloride > calcium chloride > magnesium chloride > potassium acetate. Although sodium chloride was most aggressive for both the steel, the aggressiveness of these deicers on bare steel was different from that of galvanized steel and can be arranged in following order: sodium chloride > magnesium chloride > calcium chloride > potassium acetate. The pH and electrical resistivity of the natural and recycled aggregates were compared with standard provided by American Association of State Highway and Transportation Officials (AASHTO) and found to be non-corrosive. The corrosion rate of both the aggregates on galvanized and bare steel were inappreciable. While analyzing the corrosiveness of these two aggregates, recycled concrete aggregate was observed to be more aggressive than the natural aggregate.

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This research project, funded by the Federal Highway Administration, entails the construction of an outdoor exposure site in order to evaluate various methods for mitigating alkali-silica reaction (ASR) in hardened concrete. The exposure site, built at the Concrete Durability Center at the University of Texas at Austin J.J. Pickle Research campus, included a series of bridge deck, column and slab elements. The specimens were cast in 2008, allowed to expand to predetermined expansion levels and then treated with various mitigation measures, after which the specimens were monitored for expansion, humidity, and deterioration. / text