For the last two decades, solid oxide fuel cells (SOFCs) have been operated in high temperatures > 1000¢XC. Recently, more efforts have been concentrated on the intermediate temperature SOFCs in which Ba0.5Sr0.5Ce0.8Fe0.2O3-£_ (BSCF) is a very promising cathode material capable of working in this intermediate temperature range of 500~700¢XC. In this work, both glycine and citric acid methods were employed to prepare BSCF powders. Preparation parameters such as concentration of organic components and calcination temperature were varied to obtain powders of different morphologies and particle sizes. Slurries containing the prepared powders were then used to print BSCF cathode films on electrolyte disks. The impedances of the resultant cathodes were measured and analyzed to evaluate the effects of powder preparation parameters and film microstructures. The results show that the BSCF cathode derived from the powder prepared by the modified citric acid method and then sintered at 900¢XC has the best electrochemical performance. With high porosity and well dispersed pores, this cathode has interfacial area specific resistance (ASR) values as low as 0.78 £[cm2 at 500¢XC, 0.10 £[cm2 at 600¢XC and 0.018 £[cm2 at 700¢XC, which are significantly lower than that obtained from the unmodified citric acid or glycine method.

No description available.

No description available.

Master’s thesis deals with anti-lock braking system and systems for riding stabilization of vehicles. Theoretical part of this paper describes active forces on a vehicle with emphasis on the braking process. The next part describes a design of a braking system with anti-lock braking system, and anti-slip regulation, and design of electronic stabilization program. Every subchapter dealing with system also contains a description of its function. Practical part of this thesis deals with measurement of braking with active and no active ABS done with Volkswagen Golf IV. This measurement was done on chassis dynamometer. Measured results describe the process of braking force and braking acceleration or deceleration. In the end of the thesis is comparison of results of braking with ABS for different pressure inside of tires.

No description available.

The goal of an automatic speech recognition system is to enable the computer in understanding human speech and act accordingly. In order to realize this goal, language modeling plays an important role. It works as a knowledge source through mimicking human comprehension mechanism in understanding the language. Among many other approaches, statistical language modeling technique is widely used in automatic speech recognition systems. However, the generation of reliable and robust statistical model is very difficult task, especially for a large vocabulary system. For a large vocabulary system, the performance of such a language model degrades as the vocabulary size increases. Hence, the performance of the speech recognition system also degrades due to the increased complexity and mutual confusion among the candidate words in the language model. In order to solve these problems, reduction of language model size as well as minimization of mutual confusion between words are required. In our work, we have employed clustering techniques, using self-organizing map, to build topical language models. Moreover, in order to capture the inherent semantics of sentences, a lexical dictionary, WordNet has been used in the clustering process. This thesis work focuses on various aspects of clustering, language model generation, extraction of task dependent acoustic parameters, and their implementations under the framework of the CMU Sphinx3 speech engine decoder. The preliminary results, presented in this thesis show the effectiveness of the topical language models.

The goal of an automatic speech recognition system is to enable the computer in understanding human speech and act accordingly. In order to realize this goal, language modeling plays an important role. It works as a knowledge source through mimicking human comprehension mechanism in understanding the language. Among many other approaches, statistical language modeling technique is widely used in automatic speech recognition systems. However, the generation of reliable and robust statistical model is very difficult task, especially for a large vocabulary system. For a large vocabulary system, the performance of such a language model degrades as the vocabulary size increases. Hence, the performance of the speech recognition system also degrades due to the increased complexity and mutual confusion among the candidate words in the language model. In order to solve these problems, reduction of language model size as well as minimization of mutual confusion between words are required. In our work, we have employed clustering techniques, using self-organizing map, to build topical language models. Moreover, in order to capture the inherent semantics of sentences, a lexical dictionary, WordNet has been used in the clustering process. This thesis work focuses on various aspects of clustering, language model generation, extraction of task dependent acoustic parameters, and their implementations under the framework of the CMU Sphinx3 speech engine decoder. The preliminary results, presented in this thesis show the effectiveness of the topical language models.

Alkali silica reaction (ASR), a reaction which occurs between reactive siliceous mineral components in the aggregate and the alkaline pore solution in concrete, is responsible for substantial damage to concrete structures in the U. S. and across the world. Lithium admixtures, including lithium nitrate (LiNO3), have been demonstrated to mitigate ASR damage, and are of particular interest for use in concrete airfield pavement construction, where ASR damage has been recently linked to the use of certain de-icing chemicals. Although the effectiveness of lithium admixtures at ASR-mitigation is well-researched, relatively less is known regarding the potential effects, including negative effects, on overall concrete behavior. The goal of this research is to better understand the influence of LiNO3 admixture on early age concrete behavior, and to determine if a maximum dosage rate for its use exists. Isothermal calorimetry, rheology and bleed water testing, time of setting, chemical shrinkage, autogenous shrinkage, free and restrained concrete shrinkage, and compressive and flexural strength were measured for pastes and concretes prepared with a range of LiNO3 dosages (i.e., 0, 50, 100, 200, and 400% of the recommended dosage). In addition, the interaction of LiNO3 with cement was evaluated by comparing results obtained with six cements of varying alkali and tricalcium aluminate (C3A) contents. Additionally, one of these cements, was examined alone and with 20% by weight Class F fly ash replacement. Results indicate that the hydration of the tricalcium silicate and tricalcium aluminate components of cement are accelerated by the use of LiNO3, and that low alkali cements (typically specified to avoid damage by ASR) may be particularly susceptible to this acceleration. However, inclusion of Class F fly ash at 20% by weight replacement of cement (also common in applications where ASR is a concern) appears to diminish these possibly negative effects of LiNO3 on early age hydration acceleration and heat generation. Dosages higher than the current standard dosage of LiNO3 may have minor effects on fresh concrete workability, causing slight decreases in Bingham yield stress, corresponding to slightly higher slump. Fresh concrete viscosity may also be affected, though more research is necessary to confirm this effect. LiNO3 had no effect on quantity of bleed water in the mixes tested. Generally, LiNO3 had no effect on initial and final setting times, although increasing dosages caused faster set times in the lowest alkali (Na2Oeq = 0.295%) cement examined. In shrinkage testing, higher LiNO3 dosages appeared to cause initial expansion in some sealed paste specimens, but in all cases the highest dosage led to greater autogenous shrinkage after 40 days. In concrete specimens, however, the restraining effect of aggregates diminished shrinkage, and no effect of the LiNO3 was apparent. In no cases, with any dosage of lithium tested, with or without fly ash replacement, did restrained shrinkage specimens show any cracking. Strength testing produced mixed results, with laboratory specimens increasing in 28-day compressive strength, but companion specimens cast in the field and tested by an outside laboratory, exhibited lower 28-day compressive strength, with increasing lithium dosages. Flexural specimens, also cast in the field and tested by an outside laboratory, appeared to show an increase in 28-day flexural strength with increasing lithium dosages. However, because of the conflicting results when comparing the various strength data, further research is necessary for conclusive evidence of LiNO3 effects on concrete strength.

Kuwait is an arid country situated at the head of the Arabian Gulf and its water resources can be classified into three significant types: (1) natural (groundwater) and (2) artificial (desalinated sea water and treated wastewater). In the absence of surface water bodies, groundwater constitutes the most important natural water resource in Kuwait with TDS [less than or equal to]10000 mg/L in central and south Kuwait. Only in the north can one find fresh water lenses. Brackish groundwater are used for irrigation, landscaping, construction work, non-potable use in households and mixing with desalinated water up to 10%, to make it potable. The occurrence of usable groundwater is limited to the Kuwait Group and Dammam Formation. Due to over-pumping of groundwater over the last few years, the levels and quality of groundwater are deteriorating. Kuwait is described as the poorest country in terms of water availability (UN World Water-2003). The current rates of water consumption are very high, with 459.6 L/C/d and almost 91 L/C/d for fresh and brackish water, respectively. The water budget of the water resources, represented as percentages is 59% from desalination sea water plants, 32% from groundwater with the possibility to increase the use of this resource and 9% from waste water reuse plants. Although Kuwait does not have any surface water, but it depends on technology to produce water recourses to meet the demand. The best solution for solve the issues of declining water levels and increasing salinity is artificial recharge. Artificial recharge has been applied in Kuwait in different groundwater fields since the 1980s. In addition, the available surface storage capacity of 11.7 Mm³ freshwater is sufficient to meet demand for about 7 days. So, Aquifer storage and recovery (ASR) can be used to store the water in aquifers instead of surface storage. ASR entails storing water in aquifers during wet times and recovering the water from the same well during drought times. Surface storage needs construction resources and vast land. In contrast, storing water in aquifer storage does not need that and it can decrease salinity and keep the water table constant. The water availability for artificial recharge can come from desalination and wastewater plant. The capacity and production of desalination plants are 1.425Mm³/day (525.125Mm³/yr) and 1.31Mm³/day (478.15 Mm³/yr), respectively from 5 stations. The excess capacity is 115000 m³ per day and could reach 290000 m³ per day in the winter season. Wastewater treatment plants produce from 3 plants around 0.337 Mm³/day (123.342 Mm³/yr) and the newest plant (operating by RO system) produces 0.32 Mm³/day (117.12 Mm³/yr) and will reach 0.643 Mm³/day (235.338 Mm³/yr) in 2015. The water produced from wastewater treatment plants has good quality and can be used for irrigation, greening enhancement, landscaping, recreation (artificial river and lakes) and artificial recharge. Also, using water treated for artificial recharge will improve the quality of injected water that has been successfully treated with soil aquifer treatment technology. Groundwater pumping is 200 Mm³ annually and is likely to reach 280 Mm³ in the future. This research will explore and create a database for water resource by GIS software using its tool to select and display suitable areas for ASR operation. Artificial recharge in Kuwait has used the concept of injection and recovery of water in one cycle, while here we will apply the multi-cycle concept to avoid increasing the piezometric head and clogging the porous media. The injected water will be from wastewater treatment plants with a TDS content of less 500 ppm and the TDS of recovered water in each well less than 1500 ppm. Moreover, there are criteria for selecting a domain for artificial recharge, for example, moderate transmissivity, The TDS of the aquifer should not exceed 5000 ppm, and the horizontal and vertical hydraulic gradient should be as small as possible and close to the stations suppler and demand center. The success of artificial recharge will depend on the recovery efficiency (RE) in every cycle which will increase if artificial recharge done in the correct way. The RE increases with a decrease in time between the stopping of injection and the starting of the recovery operation. Aquifer storage and recovery can play an important role as sustainability tool to resolve water resource problems, improving water quality, better than surface water storage since it minimizes construction of new infrastructure and uses that cost to initiate new desalination or waste water plants. At the end of this research we will have demonstrated the concept of the process of ASR including the volume and time for injection and recovery of water in multi-cycles and in different suitable sites. / text

Partial replacement of cement by metakaolin is known to improve concrete durability, by refining the pore structure to improve fluid transport properties and by reducing the alkalinity of the pore solution to make ASR less problematic. A gap exists in the literature as to the salt scaling performance and magnesium sulphate performance of metakaolin concrete. 10 concrete mixes were cast at w/cm ratios of 0.4 and 0.5. In addition to metakaolin, grade 80 slag was used as well as CSA GU cement. All replacement levels were tested for setting properties, compressive strength, drying shrinkage, sulphate resistance, salt scaling, ASR mitigation and chloride diffusion characteristics according to the appropriate CSA and ASTM standards. It was found that metakaolin showed better performance in magnesium sulphate solutions than slag and that metakaolin concretes attained strength and other durability properties much faster than mixes without it. Keywords: metakaolin, ASR, sulphate, magnesium, scaling, setting, diffusion