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No description available.

The objective of this research was to synthesis dibenzo-dihydroxy-26-crown-8 (1) as an ionophore for variety of chemosensors. Complexation of the ionophore (1) to a cation would cause a change of conformation. The conformational changes could affect fluorescence, UV spectra and/or Carbon-13 NMR of the chemosensor, depending on the fluorophores attached to the hydroxyl groups of crown 1 and/ or the identity of the ion. Several synthetic routes for crown 1 formation are given in the proposed synthetic procedure. Bis-1,2[2-hydroxyethoxy]benzene (17), bis-1,2[2-(3-chloro-2-hydroxypropoxy)ethoxy]benzene (18), bis-1,2[2-(2,3-epoxypropoxy)ethoxy]benzene (19) and bis-1,2[2(3-chloro-2-oxopropoxy)ethoxy]benzene (22) were synthesized. The reaction of 17 and 19 was attempted in the presence of SnC14, basic and acidic conditions, and in several solvents. The reaction of 17 and 22, and the reaction of 17 and 1,3-dichloroacetone were attempted in various reaction conditions. Crown 1 may have formed in the reaction of 17 and 19 in methylene chloride/ toluene in the presence of SnCl4 as the Lewis acid. / Department of Chemistry

Future fundamental physics experiments in neutron beta-decay require highly efficient detection of protons. Many of the experiments use electrostatic acceleration of the recoil protons into large-area silicon detectors for this purpose. A 30~keV proton accelerator was designed, created, and commissioned in order to characterize silicon detectors of this type. Final construction and initial results on the performance of the accelerator are presented. A unique aspect of the work is the use of a Penning ion generator as an ion source. The accelerator produced protons with momentum resolution ~1%. The ion source produced current stably, over a range of parameters, and over long periods of time. The accelerator achieved proton rates sufficient to calibrate silicon detectors.

The smuggling of special nuclear material (SNM) has long been a concern. In April 2009, President Obama declared that a terrorist acquiring a nuclear weapon was the most immediate threat to global security. The Second Line of Defense (SLD) initiative was stood up by the National Nuclear Security Administration to deter, detect, and interdict illicit trafficking of nuclear and radioactive materials across international borders and maritime shipping. The SLD initiative does not provide for the detection of SNM being carried on small, personal watercraft. Previous work examined the possibility of using active neutron detectors to induce fission in SNM and detect the response. This thesis examines the possibility of detecting SNM using passive 3He neutron detectors. Monte Carlo N-Particle (MCNP) simulations were run to determine the best detector configuration. Detecting sources at increasing depths, detecting moving sources and the effects of waves were also simulated in MCNP. Comparisons with experimental measurements showed that detectors parallel to the surface of water were best at detecting neutron sources below the surface. Additionally, stacking detectors and placing a cadmium sheet between the polyethylene blocks resulted in a greater ability to determine the height of a source by taking the ratio of count rates in the lower and upper detectors. Using this configuration, a source of strength 3.39 x 10^5 n/s could be detected to a depth of 12.00 in below the water surface. Count rates in the presence of waves did not average out to count rates taken above a flat plane of water. Detectors closer to the water performed worse than above a flat plane while detectors placed higher recorded more counts than above a flat plane. Moving sources were also simulated; sources under water, 3.00 ft from the detectors, and moving at 5.8 kts could be detected above background.

This work investigates advanced single-electron transistor (SET) devices for detection of charge motion in solid-state systems. In particular, novel, nanoscale twin-SET and double-island SET (DISET) detectors are introduced as sensitive charge detectors. Some advantages over conventional SET detectors in terms of noise performance, sensitivity and versatility are pointed out. With the prospect of present, transistor-based microelectronics facing serious limitations due to quantum effects and heat dissipation, alternative computing paradigms ??? such as quantum computers, quantum-dot cellular automata and single-electronics ??? have emerged, promising an extension of highlevel integration and computing power beyond the above limitations. The most promising proposals are based on solid-state systems, and readout of a computational result often requires ultra-sensitive charge detectors capable of sensing the motion of single charges on fast timescales. SETs have been shown to combine all these qualities. However, random fluctuations of the background charge in solid-state systems can affect SETs and cause errors during readout. A twin-SET detector is presented that consists of two independent SETs, which were used to detect controlled single electron transfers on a small, floating metal double-dot. By cross-correlating the two SET signals, rejection of random charge noise is successfully demonstrated, thus decreasing the error probability during readout. Detection of single-electron transfer in a double-dot is also demonstrated using a double-island SET. In addition, conductance suppression in this novel DISET detector allows the detection of electrostatically degenerate charge con- figurations of a double-dot, which cannot be achieved with single-island SETs. We consider the noise performance of the DISET, and an intuitive definition of the DISET charge sensitivity suggests that under certain conditions, DISETs can have a better charge sensitivity than conventional SETs, which would be attractive for quantum limited measurements. Finally we present the first study of a DISET operated at radio-frequencies (rf-DISET), compatible with charge detection on ms timescales. This capability is a prerequisite when reading out the charge state of quantum mechanical systems. A very good charge sensitivity (5.6 x 10i6 e/pHz) and noise temperature (2.1 K) of the rf-DISET setup are reported.

This work investigates advanced single-electron transistor (SET) devices for detection of charge motion in solid-state systems. In particular, novel, nanoscale twin-SET and double-island SET (DISET) detectors are introduced as sensitive charge detectors. Some advantages over conventional SET detectors in terms of noise performance, sensitivity and versatility are pointed out. With the prospect of present, transistor-based microelectronics facing serious limitations due to quantum effects and heat dissipation, alternative computing paradigms ??? such as quantum computers, quantum-dot cellular automata and single-electronics ??? have emerged, promising an extension of highlevel integration and computing power beyond the above limitations. The most promising proposals are based on solid-state systems, and readout of a computational result often requires ultra-sensitive charge detectors capable of sensing the motion of single charges on fast timescales. SETs have been shown to combine all these qualities. However, random fluctuations of the background charge in solid-state systems can affect SETs and cause errors during readout. A twin-SET detector is presented that consists of two independent SETs, which were used to detect controlled single electron transfers on a small, floating metal double-dot. By cross-correlating the two SET signals, rejection of random charge noise is successfully demonstrated, thus decreasing the error probability during readout. Detection of single-electron transfer in a double-dot is also demonstrated using a double-island SET. In addition, conductance suppression in this novel DISET detector allows the detection of electrostatically degenerate charge con- figurations of a double-dot, which cannot be achieved with single-island SETs. We consider the noise performance of the DISET, and an intuitive definition of the DISET charge sensitivity suggests that under certain conditions, DISETs can have a better charge sensitivity than conventional SETs, which would be attractive for quantum limited measurements. Finally we present the first study of a DISET operated at radio-frequencies (rf-DISET), compatible with charge detection on ms timescales. This capability is a prerequisite when reading out the charge state of quantum mechanical systems. A very good charge sensitivity (5.6 x 10i6 e/pHz) and noise temperature (2.1 K) of the rf-DISET setup are reported.

This work investigates advanced single-electron transistor (SET) devices for detection of charge motion in solid-state systems. In particular, novel, nanoscale twin-SET and double-island SET (DISET) detectors are introduced as sensitive charge detectors. Some advantages over conventional SET detectors in terms of noise performance, sensitivity and versatility are pointed out. With the prospect of present, transistor-based microelectronics facing serious limitations due to quantum effects and heat dissipation, alternative computing paradigms ??? such as quantum computers, quantum-dot cellular automata and single-electronics ??? have emerged, promising an extension of highlevel integration and computing power beyond the above limitations. The most promising proposals are based on solid-state systems, and readout of a computational result often requires ultra-sensitive charge detectors capable of sensing the motion of single charges on fast timescales. SETs have been shown to combine all these qualities. However, random fluctuations of the background charge in solid-state systems can affect SETs and cause errors during readout. A twin-SET detector is presented that consists of two independent SETs, which were used to detect controlled single electron transfers on a small, floating metal double-dot. By cross-correlating the two SET signals, rejection of random charge noise is successfully demonstrated, thus decreasing the error probability during readout. Detection of single-electron transfer in a double-dot is also demonstrated using a double-island SET. In addition, conductance suppression in this novel DISET detector allows the detection of electrostatically degenerate charge con- figurations of a double-dot, which cannot be achieved with single-island SETs. We consider the noise performance of the DISET, and an intuitive definition of the DISET charge sensitivity suggests that under certain conditions, DISETs can have a better charge sensitivity than conventional SETs, which would be attractive for quantum limited measurements. Finally we present the first study of a DISET operated at radio-frequencies (rf-DISET), compatible with charge detection on ms timescales. This capability is a prerequisite when reading out the charge state of quantum mechanical systems. A very good charge sensitivity (5.6 x 10i6 e/pHz) and noise temperature (2.1 K) of the rf-DISET setup are reported.

This work investigates advanced single-electron transistor (SET) devices for detection of charge motion in solid-state systems. In particular, novel, nanoscale twin-SET and double-island SET (DISET) detectors are introduced as sensitive charge detectors. Some advantages over conventional SET detectors in terms of noise performance, sensitivity and versatility are pointed out. With the prospect of present, transistor-based microelectronics facing serious limitations due to quantum effects and heat dissipation, alternative computing paradigms ??? such as quantum computers, quantum-dot cellular automata and single-electronics ??? have emerged, promising an extension of highlevel integration and computing power beyond the above limitations. The most promising proposals are based on solid-state systems, and readout of a computational result often requires ultra-sensitive charge detectors capable of sensing the motion of single charges on fast timescales. SETs have been shown to combine all these qualities. However, random fluctuations of the background charge in solid-state systems can affect SETs and cause errors during readout. A twin-SET detector is presented that consists of two independent SETs, which were used to detect controlled single electron transfers on a small, floating metal double-dot. By cross-correlating the two SET signals, rejection of random charge noise is successfully demonstrated, thus decreasing the error probability during readout. Detection of single-electron transfer in a double-dot is also demonstrated using a double-island SET. In addition, conductance suppression in this novel DISET detector allows the detection of electrostatically degenerate charge con- figurations of a double-dot, which cannot be achieved with single-island SETs. We consider the noise performance of the DISET, and an intuitive definition of the DISET charge sensitivity suggests that under certain conditions, DISETs can have a better charge sensitivity than conventional SETs, which would be attractive for quantum limited measurements. Finally we present the first study of a DISET operated at radio-frequencies (rf-DISET), compatible with charge detection on ms timescales. This capability is a prerequisite when reading out the charge state of quantum mechanical systems. A very good charge sensitivity (5.6 x 10i6 e/pHz) and noise temperature (2.1 K) of the rf-DISET setup are reported.

Thesis (Ph.D.)--Tufts University, 2003. / Adviser: David R. Walt. Submitted to the Dept. of Chemistry. Includes bibliographical references. Access restricted to members of the Tufts University community. Also available via the World Wide Web;