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N/A / Thesis / Master of Science (MS)

The purpose of these studies was to determine if results similar to those of Fleischmann and Pons could be obtained using a titanium cathode instead of palladium in an electrolysis in a heavy water cell. The electrolyte consists of D20 and H2S04• Two experiments have been performed to examine the features of this electrolysis. As titanium shows the same properties to attract hydrogen, it seemed possible that excess heat could be produced. Radiation was monitored, and the surface of the titanium cathode was examined before and after electrolysis for any changes in the morphology and composition, hoping to discover new elements that can be created only by fusion reactions in the cell, i.e. by transmutation. The heat and radiation effects have been evaluated in comparison to a control cell, using the same electrolyte and current. The only difference was the cathode, which was of platinum. It appears that excess heat is produced during electrolyses of heavy water with a titanium cathode. The amount of this excess heat was 750 cal in a one hour period, an energy gain of 44%. No significant emission of any of the products associated with a "classical" deuterium-deuterium fusion was observed during either experiment, i.e. heat but no radiation. Unexpected elements were found in both experiments, i.e. K. Cr, Fe, Ni and Zn. Remarkable is the fact that the new elements always occur very close in the periodic table to an impurity element, i.e. Cu and Zn.

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In this thesis we make a new measurement of the primordial deuterium abundance, and analyse five other systems selected as possible D/H candidates. We also undertake an investigation of systematic errors in a system where an existing deuterium measurement has been made. We measure the number of hydrogen components and their velocity distributions in a moderate and high redshift sample of Lyman limit systems in one Angstrom resolution spectra. We present a new measurement of the deuterium-to-hydrogen ratio, D/H, at z=3.2560 in a newly-discovered low metallicity absorption system towards the quasar PG1937-1009. We attempt to account for any systematic effects that could influence the D/H measurement. We find a 1 sigma range for D/H*1e5 of 1.6 (+0.25) (-0.30). Using high resolution spectra from the Hubble Space Telescope and the Very Large Telescope, we assess the suitability of five D/H candidate absorption systems. These systems were selected as candidates using lower resolution spectra. We measure the neutral hydrogen column density, identify metal lines and analyse the velocity structure of each system, and show them to be unsuitable for measuring D/H. We also investigate the systematic errors in the absorber at z=0.701 towards quasar PG1718-4801 that was initially thought to show a high primordial D/H value. We analyse the dependence of the putative deuterium line's parameters on wavelength calibration errors in the HST spectra and present a revised deuterium measurement. We examine the velocity widths of two samples of one Angstrom resolution quasar spectra showing Lyman limit absorption systems. The first sample is at high redshifts, taken from the Sloan quasar data release 3 catalogue. The second is at intermediate redshifts, compiled from a survey for UV quasar absorption systems taken with the Hubble Space Telescope. We use a modified version of the Voigt profile fitting program, VPFIT, to estimate the number of hydrogen velocity components and column density in the Lyman limit systems. We compare the velocity distributions of the higher and lower redshift samples. We find the distributions are consistent with other measures of the velocity spread in absorption systems, and find no compelling evidence for evolution between the redshift samples.

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Tungsten is a candidate plasma facing material for next generation magnetic fusion devices such as ITER and there are major operational and safety issues associated with hydrogen (tritium) retention in plasma facing components. An ion gun was used to simulate plasmamaterial interactions under various conditions in order to study hydrogen retention characteristics of tungsten thus enabling better predictions of hydrogen retention in ITER. Thermal Desorption Spectroscopy (TDS) was used to measure deuterium retention from ion irradiation while modelling of TDS spectra with the Tritium Migration Analysis Program (TMAP) was used to provide information about the trapping mechanisms involved in deuterium retention in tungsten. X-ray Photoelectron Spectroscopy (XPS) and Secondary Ion Mass Spectrometry (SIMS) were used to determine the depth resolved composition of specimens used for irradiation experiments. Carbon and oxygen atoms will be among the most common contaminants within ITER. C and O contamination in polycrystalline tungsten (PCW) specimens even at low levels (~0.1%) was shown to reduce deuterium retention by preventing diffusion of deuterium into the bulk of the specimen. This diffusion barrier was also responsible for the inhibition of blister formation during irradiations at 500 K. These observations may provide possible mitigation techniques for iii problems associated with tritium retention and mechanical damage to plasma facing components caused by hydrogen implantation. Deuterium trapping in PCW and single crystal tungsten (SCW) was studied as a function of ion energy and substrate temperature. Deuterium retention was shown to decrease with decreasing ion energy below 100 eV/D+. Irradiation of tungsten specimens with 10 eV/D+ ions was shown to retain up to an order of magnitude less deuterium than irradiation with 500 eV/D+ ions. Furthermore, the retention mechanism for deuterium was shown to be consistent across the entire energy range studied (10-500 eV) with the shallow penetration depth of low energy ions being the major factor in the reduction in retention. A change in retention mechanism was observed as tungsten temperature during irradiation was increased from 300 to 500 K. Modelling of deuterium retention in 300 and 500 K SCW specimens revealed that two traps, 1.0 and 1.3 eV, are involved in retention for irradiations performed at 300K while a single 2.1 eV trap is present for 500 K irradiations. Experiments suggest that the 2.1 eV trap is created during irradiation of tungsten at 500 K and this process also involves the annihilation of the 1.3 and 1.0 eV traps.

Deuterium retention in two types of polycrystalline tungsten was studied as a function of ion fluence, irradiation temperature and ion energy. Fluence dependence: D retention at 300 K tends to saturate in both Rembar and Plansee PCW. At 500 K, D retention in the Plansee PCW increases with increasing ion fluence, similar to previous results for Rembar tungsten. Even at a fluence of 8×10^25 D+/m2, no sign of saturation was observed. Temperature dependence: D retention in Plansee PCW decreases with increasing irradiation temperature (300 - 500 K). Energy dependence: varying the D+ energy from 100 to 500 eV/D+ plays a minor role in D retention in W, suggesting that D retention depends more on the W structure, irradiation temperature and fluence, rather than on the ion energy when the energy is below the displacement threshold.