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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.

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Crystal Structure of Tetrakis(μ-N-Phenylacetamidato)-κ<sup>4</sup>N:O;κ<sup>4</sup>O:N-bis[(2-Methylbenzonitrile-κN)Rhodium(II)](Rh - Rh)

Eagle, Cassandra T., Atem-Tambe, Nkongho, Kpogo, Kenneth K., Tan, Jennie, Cook, Kevin M. 01 January 2014 (has links)
The complex molecule of the title compound, [Rh2{N(C6H5)COCH3}4(C8H7N)2], exhibits inversion symmetry. The four acetamidate ligands bridging the dirhodium core are arranged in a 2,2-trans manner with two N atoms and two O atoms coordinating to each RhIIatom trans to one another. The Neq - Rh - Rh - Oeq torsion angles on the acetamidate bridge vary between -4.07 (5) and -6.78 (7)°. The axial nitrile ligands complete the distorted octahedral coordination sphere of each RhIIatom and show a nonlinear coordination with Rh - N - C bond angles of 151.6 (3) and 152.5 (3)°. The bond lengths of the two nitrile triple bonds are 1.133 (5) and 1.137 (5) Å.
acetamidate ligand
crystal structure
dirhodium core
Rh complex II
Chemistry

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