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Improvements of Atmospheric Deposition Sampling Procedures and Further Analysis of its Impact on Utah LakeBarrus, Seth Michael 08 April 2021 (has links)
This study focused on Atmospheric Deposition (AD) loading on Utah Lake. Utah Lake is susceptible to Harmful Algal Blooms (HABs) because of its large surface area to volume ratio, proximity to Great Basin dust sources, and various wind patterns from close mountain ranges that blow AD towards the lake. In this study, we continued the collection and analysis of AD samples that started in 2017 and 2018, while reporting additional 2019 and 2020 data. We constructed a sampler on Utah Lake itself, which allowed us to better estimate how AD loads were distributed over the lake. An interpolation assumption was made in the previous studies that the amount of AD decreases exponentially as it passes onto the lake from the shore. Results from 5 months of Bird Island AD sampling on Utah Lake indicate that this assumption was incorrect. We performed statistical comparison tests on 2 variables: (1) the difference in AD between 2 table heights at the same site and (2) the difference in AD between a filtered sample and an unfiltered sample. We were able to statistically conclude that there was no difference in AD between 1-meter and 2-meter tall sample tables and that filtered AD samples had as much as 3 times lower concentration than unfiltered AD samples. In 2017, the total AD loading was estimated to be, on the high end, approximately 350 tons of total phosphorous (TP) and 460 tons of dissolved inorganic nitrogen (DIN) (Olsen JM, 2018). After making some changes to the interpolation methods, Joshua Reidhead in 2018 estimated AD loads of 153 tons of TP and 505 tons of DIN (Reidhead, 2019). With no changes to the 2018 sampling methods, but using an updated interpolation method, we determined the AD results for Utah Lake in 2019 to be 262 tons of TP and 1052 tons of DIN. After adjustments to the sampling tables, the bucket filters, and incorporating the Bird Island sampler results, we calculated the 2020 AD loading totals to be 133 tons of TP and 482 tons of DIN on the lake.
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Evaluating the origins and transformations of organic matter and dissolved inorganic nitrogen in two contrasting North Sea estuariesAhad, Jason Michael Elias January 2005 (has links)
In order to delineate the potential sources and to understand the main controls on the biogeochemical cycling of dissolved and particulate organic matter (DOM, POM) and dissolved inorganic nitrogen (DIN) during estuarine mixing, comprehensive seasonal geochemical and isotopic and surveys across the freshwater-tidal interface were carried out in the Tyne and Tweed Estuaries, NE UK. This study provided a contrast between a relatively pristine system (Tweed) with one that is heavily influenced by anthropogenic activity (Tyne). Geochemical and isotopic (13C, 14C and 15N) analyses demonstrated the predominance of terrigenous organic matter in both these estuaries, with elevated river discharges leading to enhanced terrestrial loading. High pCO2 values in the Tyne (summer) and Tweed (winter) suggested that a significant fraction of this terrestrially-derived organic matter (both DOM and POM pools) is relatively labile and can potentially undergo significant mineralization during estuarine mixing. In both estuaries in situ processing of DIN was relatively minor, with mixing between different sources being the main factor in controlling the distribution of nitrate and ammonium across the salinity gradient. However, anthropogenic ammonium discharges in the Tyne were found to have an enormous direct and indirect impact on estuarine nitrogen cycling. Large, concave removals of terrigenous high molecular weight (HMW) DOC caused by flocculation, biodegradation, and/or photochemical oxidation were associated with a non-conservative 13C-enrichment in d13C signatures. Radiocarbon dates showed an export of young (modern) HMW DOC and old (100-1000s of years), terrigenous POC to the North Sea. 14C-enriched values in coastal North Sea HMW DOC were attributed to anthropogenic discharges originating from within the coastal North Sea environment. In the Tweed, seasonal changes in soil characteristics resulted in an older age for POM during the summer. In the Tyne, decreases in POC% with increasing salinity sometimes coincided with an increase in POC age. This was attributed to mixing with older sediment and to the possible preferential loss of the younger, more labile POC fraction during mineralization. This study has shown that land use patterns, sewage inputs, and freshwater flushing time are the main influences in determining the behaviour and origin of organic matter and DIN entering the coastal North Sea in these two systems.
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Nutrient uptake by seagrass communities and associated organisms [electronic resource] : impact of hydrodynamic regime quantified through field measurements and use of an isotope label / by Christopher David Cornelisen.Cornelisen, Christopher David. January 2003 (has links)
Includes vita. / Title from PDF of title page. / Document formatted into pages; contains 185 pages. / Thesis (Ph.D.)--University of South Florida, 2003. / Includes bibliographical references. / Text (Electronic thesis) in PDF format. / ABSTRACT: Seagrass communities are composed of numerous organisms that depend on water-column nutrients for metabolic processes. The rate at which these organisms remove a nutrient from the water column can be controlled by physical factors such as hydrodynamic regime or by biological factors such as speed of enzyme reactions. The impact of hydrodynamic regime on rates of nutrient uptake for seagrass (Thalassia testudinum) communities and for organisms that comprise the community (seagrass, epiphytes, phytoplankton, and microphytobenthos) was quantified in a series of field flume experiments employing the use of 15N-labeled ammonium and nitrate. Rates of ammonium uptake for the entire community and for seagrass leaves and epiphytes were significantly dependent on bulk velocity, bottom shear stress, and the rate of turbulent energy dissipation. / ABSTRACT: Relationships between uptake rates and these parameters were consistent with mass-transfer theory and suggest that the effect of water flow on ammonium uptake is the same for the benthos as a whole and for the organisms that form the canopy. In addition, epiphytes on the surface of T. testudinum leaves were shown to depress leaf uptake by an amount proportional to the area of the leaf covered by epiphytes. Water flow influenced rates of nitrate uptake for the community and the epiphytes; however, uptake rates were depressed relative to those for ammonium suggesting that uptake of nitrate was also affected by biological factors such as enzyme activity. Epiphytes reduced uptake of nitrate by the leaves; however, the amount of reduction was not proportional to the extent of epiphyte cover, which provided further evidence that nitrate uptake by T. testudinum leaves was biologically limited. / ABSTRACT: As an additional component of the research, hydrodynamic regime of a mixed seagrass and coral community in Florida Bay was characterized using an acoustic Doppler velocimeter. Hydrodynamic parameters estimated from velocity data were used in mass-transfer equations to predict nutrient uptake by the benthos over a range of water velocity. Measured rates of uptake from field flume experiments conducted in the same community confirmed that hydrodynamic data could be used to accurately predict nutrient transport to the benthos under natural flow conditions. / System requirements: World Wide Web browser and PDF reader. / Mode of access: World Wide Web.
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Dissolved Inorganic Nitrogen Removal Efficiency Of The Reed Beds Surrounding Lake Mogan Using Modeling ApproachesGokmen, Mustafa 01 January 2004 (has links) (PDF)
In this study, yearly and seasonally nitrogen retention dynamics of reed beds surrounding Lake Mogan were investigated by comparing surface aerial nitrogen load and in-lake concentrations. The analyses were performed separately for nitrate-N, ammonium-N and dissolved inorganic nitrogen (sum of nitrate-N and ammonium-N) to reveal differences between them in terms of retention dynamics. 1998, 1999 and 2002 were relatively high-load years in terms of DIN-input to reed beds surrounding Lake Mogan, compared with the DIN-loadings of 1997, 2000 and 2001. A significant difference was observed between NO3-N input and output for the relatively high-load years to Lake Mogan reed beds indicating significantly high NO3-N retention rates for that periods, while no significant difference was observed in the relatively low-load years. Also, a clear linear relationship (R2 = 0.975) was found between amount of NO3-N retention and amount of NO3-N input to the system. NH4-N input and output were not significantly different in none of the study years.
Then, a dynamic Wetland Nitrogen Model was utilized to model dissolved inorganic nitrogen removal capacity of the reed beds surrounding Lake Mogan. The model was firstly calibrated and validated using data sets of different study years and then used for prediction under wet and dry year scenarios. The model predictions revealed that NO3-N retention efficiency was distinctively higher in wet rather than the dry year conditions since the reed beds might have limited denitrification capacity in dry years due to unavailability of enough NO3-N load.
Finally, the land-use changes occurred in the closer catchment of Lake Mogan and the potential risk areas for non-point nitrogen input to Lake Mogan were determined using aerial photos of the region and Geographical Information Systems (GIS). It was observed that highest potential risk area for non-point nitrogen input around the lake was north-east of the lake whereas, north end of the lake was least potential risk area.
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