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Geosynthetic Clay Liners (GCLs) are commonly paired with a geomembrane and used as part of a composite liner system for landfill barriers. Under some circumstances, leaving a composite geomembrane/geosynthetic clay liner exposed to solar radiation in the field has been shown to cause shrinkage of the underlying GCL. Recent field studies have shown that leaving a composite liner exposed can also lead to down-slope erosion of bentonite from the GCL due to the down-slope movement of moisture. To investigate the factors that can affect the onset of bentonite erosion in a GCL an experimental technique was developed to reproduce similar erosion in the laboratory. The test method simulates the features that occur with the erosion of bentonite caused by down-slope migration of evaporative water in the field. One needle-punched GCL was tested to examine the factors that can affect the onset of erosion of bentonite particles with the flow of water. The factors examined include the effect of the initial wet/dry cycle, water source chemistry, flow rate, slope, prior cation exchange, and the effect of no drying phase in the test cycle. Ten different manufactured GCL products were tested to examine the effect of material properties on the erosion of bentonite from a GCL. The material properties of the products tested differed in terms of the type of carrier and cover geotextiles, bentonite (powdered, fine and coarse grained, and some with a polymer enhancement additive) and the presence of a polypropylene coating over the geotextile. It was found that the most critical factor to trigger the onset of bentonite erosion was the water source chemistry, with the tests that simulated the evaporation and condensation of water (deionized water) below an exposed composite liner leading to the formation of major erosion features. The results of the laboratory testing program also show that erosion features are more visible in products with white coloured geotextiles. The products containing a polypropylene coated geotextile and polymer enhanced bentonite slowed or, in some cases, prevented erosion features from developing. / Thesis (Master, Civil Engineering) -- Queen's University, 2014-05-01 10:16:14.05

Downslope flows and regions of enhanced cooling have important impacts on society and the environment. Parameterisation of these often subgrid-scale phenomena in numerical models requires a sound understanding of the underlying physical processes, which has been the overarching aim of this work. A numerical model has been used to characterise the development of a region of enhanced cooling in an idealised alpine valley with width and depth of order 10 and 1 km, respectively, under stable, decoupled, poorly-drained conditions. A focus of this work has been to remove the uncertainty surrounding the forcing mechanisms behind the development of regions of enhanced cooling. The average valley-atmosphere cooling has been found to be almost equally partitioned between radiative and dynamics effects. Complex interactions between the downslope flows and the region of enhanced cooling have been quantified for the first time. For example, relatively large variations in the downslope flows are generally restricted to the region of enhanced cooling and cannot solely be attributed to the analytical model of [McNider, 1982a]. These flow variations generally coincide with return flows above the downslope flows, where a thin region of unstable air occurs, as well as coinciding with elongated downslope flow structures. The impact of these interactions on the dispersion of passive pollutants has been investigated. For example, pollutants are generally trapped within the region of enhanced cooling. The concentration of pollutants within the region of enhanced cooling, emitted over the lower half of the slopes, increase as the emission source moves away from the ground-based inversion that expands from the bottom of the valley. The concentration of pollutants within the region of enhanced cooling is very similar when varying the location of the emission source over the top half of the valley slopes. This work includes a test of the effects of varying the horizontal numerical grid resolution on average valley-atmosphere temperature changes.