¡@Ecological and environmental problems of the 21st century are a serious threat to human survival and economic development. From open policy, Mainland China has made remarkable achievements in economic development, but also pays a heavy consideration for the resources and environment, unbalanced regional development and environmental diplomacy issues with neighboring countries. This paper tries to use literature, induction, case analysis of three research methods to analysis. This paper tries to find wrong creation of "because of" on Mainland China environmental problem. This paper comes by experience of developed countries to examine transformation of politics, economy, society policy in Mainland China, and tries in the economic development and pollution of the environment to achieve a balance. ¡@¡@Ecological environment has the properties of public goods and externalities. Central government is main actor of ecological environmental governance is no doubt. But state and society relations began to change with the transformation of the social and institutional change. Originally, Government monopoly to supply public goods began to shift to multiple actors supply model. This paper presents enterprises, Non-Governmental Organizations (NGOs), citizens of the three non-governmental actors and the relationship of the ecological environmental governance, and explores the interactive relationship between of central government and local government. On this basis, ecological environmental governance network theory as the core, proposed new ways to analysis the necessity and feasibility of ecological environmental governance network, and construct multiple actors of collaboration the new model of governance network. ¡@¡@The serious of environment problem in Mainland China faces severity influence economy growth, society security and people healthy. The environment depravation degree forces the environment non- government organization and citizen to joins. This paper used the case in the Huaihe River Valley. The environmental NGO, Huaihe River Guider, successes to connect with central government, citizen, and enterprise. Mainland China's central government still needs to strengthen rule of law construction and market mechanism establishment, particularly lawmaking guarantee the citizen participate, the solution mechanism of environment dispute, an arrange taking of dirty tax and fees etc., and then to expand this model to the pollution of various type in each city. Government absorbs the environmental governance experience, funds and technique of developed country by attending global governance, and then raises the environment quality of earth.