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Water resources are increasingly precious, so wastewater reclaiming has become an important source of water nowadays. There are many types of industry including conventional and hi-tech ones in the selected industrial processing zone, where different process wastewaters are treated by a centralized wastewater treatment plant. The effluent is then discharged into the ocean (EDO). On the other hand, among several other industries backside grinding (BG) wastewater generated by the IC (integrated-circuit) packaging and testing industry is treated by their owned wastewater treatment plants and then discharged onto land (EDL). Normally, BG wastewater is huge in quantity and it contains microscale and nanoscale particles. The objectives of this research were two-fold: (1) to evaluate the feasibility of using two tubular ceramic membranes (microfiltration and ultrafiltration) coupled with the electrocoagulation/electrofiltration (EC/EF) process to effectively treat the effluent discharged into the ocean, effluent discharged onto land, and BG wastewater for the purpose of reclamation; and (2) to investigate the best time for backwashing of membranes through the analysis of components of membrane fouling using resistances in series model. The experimental results showed that the ultrafiltration (UF) membrane (i.e., tubular TiO2/Al2O3 composite membrane) outperformed the mictrofiltration (MF) membrane (i.e., tubular Al2O3 membrane) in terms of permeate quality. But, generally, the later yielded a greater membrane flux. In the case of BG wastewater by UF and EC/EF, the quality of permeate met the tap water standards in terms of water quality items analyzed. As for EDO and EDL further treated by UF and EC/EF, all the analyzed water quality items of permeate, except pH and total dissolved solids, met the tap water standards in Taiwan. Thus, more efforts have to be made to reclaim these two types of effluent. Finally, the components of membrane fouling were analyzed using resistances in series model for the tested water specimens. The results showed that generally the irreversible resistance component (Rirr) had a greater contribution to a better quality of permeate than that of the reversible resistance component (Rr). It was also found that the magnitude of Rirr of BG wastewater was greater than Rirr values of the other two effluents. This might explain why the quality of permeate of the former was better than the latter. The results further indicated that Rr increased more than Rirr as the operating time elapsed, resulting in a limited improvement of permeate quality even a longer treatment time was employed. To recover the membrane flux to its optimum, in this study the best time for backwashing of membrane was determined based on the time at which Rr was greater than Rirr. However, the flux recovery was found to be in the range of 60-77% as compared with the initial flux for a virgin membrane in treating new batch of water specimens. The fraction unable to recover by backwashing might be contributed by Rirr in the membrane pores. A further acid washing would resolve this problem.

Liquid wastes discharged from industrial outfalls have been researched for many years in the past. Majority of past studies, initiated in 1960s, were experimental studies mainly focused on basics of discharges such as key geometrical properties. Eventually, more robust experimental studies were performed to measure the mixing properties of effluent discharges with various jet configurations and ambient water conditions. Discharges could be as a means of submerged diffusers or surface channels and receiving water could vary from a homogenous calm ambient to a very complex stratified turbulent cross flow ambient. Depending on the bathymetric and economic situation around an outfall project, submerged discharges are preferred designs for most of ocean outfalls. It is the reason that majority of past studies have evaluated the mixing characteristics of submerged jets. Since early 1990s, the numerical modelling has emerged to support complex fluid mechanic problems. Later in 1990s and early in 2000s, the use of computational fluid dynamic (CFD) tools emerged in predicting the jet properties for the effluent discharges. Since then different numerical models have been developed for different applications. Similar to experimental studies, most of numerical studies have been focused on the submerged dense jet discharges. The current study intends to stay focused on the numerical modelling of such jets too; however, to cover the gaps in the literature. To achieve this, a thorough literature review was performed on the past CFD studies of over past 20 years to better understand what was done and what the gaps are. The results of this thorough review revealed that although there has been a great progress in the CFD studies in the field of effluent discharges, there are some applications that have not been investigated before, yet. It was found that there are some discharge inclinations that were not studied numerically before. Four discharge angles of 60°,75°, 80° and 85° were selected in this study, as previous studies mostly focused on 30° and 45°. The higher inclinations are more suitable for deep water outfalls where terminal rise height of the jet does not attach to the ambient water surface. The numerical model OpenFOAM was used in this study which is based on the Finite Volume Method (FVM) applying LRR turbulence model closure. LRR turbulence models was proved to be a capable choice for effluent discharge modelling. The second gap identified in the comprehensive literature review completed was the submerged dense effluent discharge into shallow water with surface attachment (for both inclined and vertical discharges). There was no previous numerical study of such jets identified. Three different regimes were identified: full submergence, plume contact and centerline impingement regimes (i.e. FSR, PCR and CIR). Key geometrical and dilution properties of these jets at surface contact (Xs, Ss) and return point (Xr, Sr) were extracted numerically and compared to those available from experiments. Two discharge angles (30° and 45°) were investigated based on the available experimental data. Five Reynolds-averaged Navier-Stokes (RANS) turbulence models were examined in this study: realizable k-ε and k-ω SST models (known as two-equation turbulence models), v2f (four equations to model anisotropic behavior) and LRR and SSG turbulence models (known as Reynolds stress models - six equations to model anisotropic behavior). Vertical dense effluent discharges are popular in the design of outfall systems. Vertical jets provide the opportunity to be efficient for a range of ambient currents, where the jet will be pushed away not to fall on itself. This research work investigates worst case scenario in terms of mixing and dilution of such jets: vertical dense effluent discharges with no ambient current and in shallow water where jet impacts the surface. This scenario provides a conservative design criteria for such outfall systems. The numerical modelling of such jets has not been studied before and this research work provides novel, though preliminary, insights in simulations of vertical dense effluent discharges in shallow waters. Turbulent vertical discharges with Froude numbers ranging from 9 to 24 were simulated using a Reynolds stress model (RSM), based on the results from inclined dense discharges to characterize the geometrical (i.e., maximum discharge rise Zm and lateral spread Rsp) and dilution μmin properties of such jets. Three flow regimes were reproduced numerically, based on the experimental data: deep, intermediate and impinging flow regimes.

Magister Scientiae (Biodiversity and Conservation Biology) - MSc (Biodiv and Cons Biol) / The study illustrates the current ecological integrity of the Diep River system, based on the recent river health assessment using the South African Scoring System version 5 (2000-2003) and the water quality data (1996-2002). Some of the major land-use impacts on the river system are highlighted.

Liquid waste discharged from industrial outfalls is categorized into two major classes based on their density. One type is the effluent that has a higher density than that of the ambient water body. In this case, the discharged effluent has a tendency to sink as a negatively buoyant jet. The second type is the effluent that has a lower density than that of the ambient water body and is hence defined as a (positively) buoyant jet that causes the effluent to rise. Negatively/Positively buoyant jets are found in various civil and environmental engineering projects: discharges of desalination plants, discharges of cooling water from nuclear power plants turbines, mixing chambers, etc. This thesis investigated the mixing and dispersion characteristics of such jets numerically. In this thesis, mixing behavior of these jets is studied using a finite volume model (OpenFOAM). Various turbulence models have been applied in the numerical model to assess the accuracy of turbulence models in predicting the effluent discharges in submerged outfalls. Four Linear Eddy Viscosity Models (LEVMs) are used in the positively buoyant wall jet model for discharging of heated waste including: standard k-ε, RNG k-ε, realizable k-ε and SST k-ω turbulence models. It was found that RNG k-ε, and realizable k-ε turbulence models performed better among the four models chosen. Then, in the next step, numerical simulations of 30˚ and 45˚ inclined dense turbulent jets in stationary ambient water have been conducted. These two angles are examined in this study due to lower terminal rise height for 30˚ and 45˚, which is very important for discharges of effluent in shallow waters compared to higher angles. Five Reynolds-Averaged Navier-Stokes (RANS) turbulence models are applied to evaluate the accuracy of CFD predictions. These models include two LEVMs: RNG k-ε, and realizable k-ε; one Nonlinear Eddy Viscosity Model (NLEVM): Nonlinear k-ε; and two Reynolds Stress Models (RSMs): LRR and Launder-Gibson. It has been observed that the LRR turbulence model as well as the realizable k-ε model predict the flow more accurately among the various turbulence models studied herein.

Liquid waste discharged from industrial outfalls is categorized into two major classes based on their density. One type is the effluent that has a higher density than that of the ambient water body. In this case, the discharged effluent has a tendency to sink as a negatively buoyant jet. The second type is the effluent that has a lower density than that of the ambient water body and is hence defined as a (positively) buoyant jet that causes the effluent to rise. Negatively/Positively buoyant jets are found in various civil and environmental engineering projects: discharges of desalination plants, discharges of cooling water from nuclear power plants turbines, mixing chambers, etc. This thesis investigated the mixing and dispersion characteristics of such jets numerically. In this thesis, mixing behavior of these jets is studied using a finite volume model (OpenFOAM). Various turbulence models have been applied in the numerical model to assess the accuracy of turbulence models in predicting the effluent discharges in submerged outfalls. Four Linear Eddy Viscosity Models (LEVMs) are used in the positively buoyant wall jet model for discharging of heated waste including: standard k-ε, RNG k-ε, realizable k-ε and SST k-ω turbulence models. It was found that RNG k-ε, and realizable k-ε turbulence models performed better among the four models chosen. Then, in the next step, numerical simulations of 30˚ and 45˚ inclined dense turbulent jets in stationary ambient water have been conducted. These two angles are examined in this study due to lower terminal rise height for 30˚ and 45˚, which is very important for discharges of effluent in shallow waters compared to higher angles. Five Reynolds-Averaged Navier-Stokes (RANS) turbulence models are applied to evaluate the accuracy of CFD predictions. These models include two LEVMs: RNG k-ε, and realizable k-ε; one Nonlinear Eddy Viscosity Model (NLEVM): Nonlinear k-ε; and two Reynolds Stress Models (RSMs): LRR and Launder-Gibson. It has been observed that the LRR turbulence model as well as the realizable k-ε model predict the flow more accurately among the various turbulence models studied herein.

Wastewater treatment is traditionally considered a separate part of an industrial activity, hardly connected to the production units themselves. It is nowadays essential to ensure that the quality of water is not degraded and that water that has been polluted is purified to acceptable levels, especially in a country with scarce water resources such as South Africa. Where water quality is concerned, Zero Effluent Discharge (ZED) is the ultimate goal, in order to avoid any releases of contaminants to the water environment. The push towards ZED in South Africa is also promoted further by the South African Government’s plan to reduce freshwater usage and the pollution of water sources due to the water scarcity in a semi-arid South Africa. Future legislation will see a marked increase in the cost of freshwater usage and/or a possible limitation of the quantity of freshwater available. There is a need in the South African Industry for a framework of Best Management Practices (BMPs) in order to provide interested stakeholders, which include not only industry, but also academia, environmental interest groups and members of the public, with a procedure to meet the ZED statutory requirements. This dissertation explores the regulatory requirements and current environmental management practices implemented. A framework of BMPs to successfully attain ZED status in South African industries is developed from the literature study and the researcher’s own experience. The BMP framework embodies practices for one integrated strategy within three dimensions. The three dimensions of the BMP framework were selected to differentiate between BMPs for management (Governance BMPs), the project management team responsible for ZED projects (Project Management BMPs) and the implementation of preventative and operational measures to obtain and sustain ZED compliance for South African industries. The BMP framework was validated against the practices applied by Mittal Steel. The Mittal Steel plant in Vanderbijlpark implemented various projects, reduced the intake of water and eliminated the discharge of effluent and by doing this successfully realised their ZED status. The BMP framework will enable South African industries to develop their own BMPs Manual which should be specific to their operational and environmental requirements. The implementation of these BMPs should be tailored and used accordingly to demonstrate compliance to ZED requirements in South African industries. / Thesis (M.Ing. (Development and Management))--North-West University, Potchefstroom Campus, 2009.

Wastewater treatment is traditionally considered a separate part of an industrial activity, hardly connected to the production units themselves. It is nowadays essential to ensure that the quality of water is not degraded and that water that has been polluted is purified to acceptable levels, especially in a country with scarce water resources such as South Africa. Where water quality is concerned, Zero Effluent Discharge (ZED) is the ultimate goal, in order to avoid any releases of contaminants to the water environment. The push towards ZED in South Africa is also promoted further by the South African Government’s plan to reduce freshwater usage and the pollution of water sources due to the water scarcity in a semi-arid South Africa. Future legislation will see a marked increase in the cost of freshwater usage and/or a possible limitation of the quantity of freshwater available. There is a need in the South African Industry for a framework of Best Management Practices (BMPs) in order to provide interested stakeholders, which include not only industry, but also academia, environmental interest groups and members of the public, with a procedure to meet the ZED statutory requirements. This dissertation explores the regulatory requirements and current environmental management practices implemented. A framework of BMPs to successfully attain ZED status in South African industries is developed from the literature study and the researcher’s own experience. The BMP framework embodies practices for one integrated strategy within three dimensions. The three dimensions of the BMP framework were selected to differentiate between BMPs for management (Governance BMPs), the project management team responsible for ZED projects (Project Management BMPs) and the implementation of preventative and operational measures to obtain and sustain ZED compliance for South African industries. The BMP framework was validated against the practices applied by Mittal Steel. The Mittal Steel plant in Vanderbijlpark implemented various projects, reduced the intake of water and eliminated the discharge of effluent and by doing this successfully realised their ZED status. The BMP framework will enable South African industries to develop their own BMPs Manual which should be specific to their operational and environmental requirements. The implementation of these BMPs should be tailored and used accordingly to demonstrate compliance to ZED requirements in South African industries. / Thesis (M.Ing. (Development and Management))--North-West University, Potchefstroom Campus, 2009.