Urbanization causes various environmental issues including water pollution, air pollution, and solid waste. Urbanization of watersheds has a profound influence on the quality of stormwater runoff. The quality of stormwater runoff is highly associated with land use. This study analyzed the exceedance frequency of stormwater quality in five watersheds of Denton over eleven years and also analyzed the relationship between stormwater quality and land use/cover of each watershed. The results showed that the most of the water quality parameters that were examined in the Lower Pecan watershed exceeded their threshold most frequently. The higher frequency of exceedance in this watershed can be attributed to the wastewater treatment plant and landfill site. Total suspended solids and turbidity were frequently exceeded in Hickory and Clear Creek watersheds. Conductivity was found to have highest percentage of exceedance in Upper Pecan and Cooper watersheds. Thus, rural watersheds were related with higher exceedance of TSS and turbidity whereas urban watersheds were related with higher exceedance of conductivity.