"The hazard associated with dust deflagrations has increased over the last decade industries that manufacture, transport, process, or use combustible dusts. Identification of the controlling parameters of dust deflagration mechanisms is crucial to our understanding of the problem. The objective of this study is to develop an experimental platform, called the Hybrid Flame Analyzer (HFA), capable of measuring the laminar and turbulent burning velocity of gas, dust, and hybrid (gas and dust) air premixed flames as a function of properties specific to the reactants such as dust-particle size and concentration. In this work the HFA is used to analyze a particle-gas-air premixed system composed of coal dust particles (75-90 µm and 106-120 µm) in a premixed CH4-air ( = 0.8, 1.0 and 1.2) flame. This work ultimately aims to improve the knowledge on fundamental aspects of dust flames which is essential for the development of mathematical models. This study is the first of its kind where multiple different parameters that govern flame propagation (initial particle radius, particle concentration, gas phase equivalence ratio, turbulent intensity, and integral length scale) are systematically analyzed in a spatially uniform cloud of volatile particles forming a stationary flame. The experiments show that the turbulent burning velocity is more than two-times larger than the laminar counter-part for each and every case studied. It is observed that smaller particles and larger concentrations (> 50 g/m3) tend to enhance the turbulent burning velocity significantly compared to larger particle sizes and lower concentration ranges. The experimental data is used to develop a correlation similar to turbulent gas flames to facilitate modeling of the complex behavior. "

This research investigates the decomposition and burning behaviours of polyurethane foams experimentally and compares the experimental results obtained with the numerical results from the pyrolysis model of Fire Dynamics Simulator, Version 5 (FDS 5). Based on the comparison of model and experimental heat release rates, the accuracy of the pyrolysis model is quantified. In total, this research tested seven polyurethane foams consisting of three non-fire retardant (NFR) and four fire retardant (FR) foams. According to the simultaneous differential scanning calorimetry and thermogravimetric analysis (SDT) experiments, the decomposition behaviour of polyurethane foams under nitrogen environment is represented by two pyrolysis reactions. The first reaction consists of foam decomposition into melts and gases while the second reaction consists of the decomposition of the remaining melts into gases. The kinetic properties which govern the rate of decomposition are the activation energy (E), pre-exponential factor (A), reaction order (n) and heat of reaction (Δhr). Using graphical techniques, E, A and n of the first and second reactions are determined from the thermogravimetric analysis (TGA) results. Through analysing the differential scanning calorimetry (DSC) results, Δhr is determined from the changes in heat flow and sample mass. The thermophysical properties govern the heat transfer through material and these are the thermal conductivity (λ) and specific heat (cp) which are measured experimentally at ambient temperature through the Hot Disk method. Through the Sample Feeding Vertical Cone, the decomposition and melting behaviours of polyurethane foams in a vertical orientation are investigated and the foams tested can be categorised into those which produce melts only after ignition and those which produce melts and char after ignition. The 1-dimensional burning behaviour of foams is obtained from the cone calorimeter experiments. The NFR foams show a change from plateau burning behaviour at low heat flux to two stage burning behaviour at high heat flux while the FR foams consistently show two stage burning behaviour. The combustion property governs the amount of heat released when fuel combusts and this is the effective heat of combustion (Δhc,eff) which is determined from the heat released and mass consumed in the cone experiment. The 1-dimensional burning behaviour is simulated using the pyrolysis model of FDS 5 and two different modelling approaches are considered. The direct method uses the material properties determined experimentally as FDS 5 inputs while the refined method uses the genetic algorithm of Gpyro to refine the kinetic properties which are later used as FDS 5 inputs. The heat release rate of the model and experiment are compared through linear regression analysis which quantifies the accuracy of both methods. The accuracy is defined as the percentage of data points within the boundary of acceptance which is bounded by 25 % of the greatest experimental heat release rate. This assessment method places greater emphasis on the accuracy of developed burning phases and lesser emphasis on the accuracy of initial growth and final decay. The accuracy of the direct method is found to be 56 % while the refined method with estimated kinetic properties achieves a higher accuracy of 75 %. The 2-dimensional burning behaviours are investigated in the foam slab experiments for two different slab thicknesses, 120 and 100 mm. The opposed-flow spread of 120 mm slab is more intense and rapid while for the 100 mm slab, the flame spread is less intense and slow. FDS 5 is used to simulate the experimental results but when the material properties either developed experimentally or refined by Gpyro are used as inputs, the model fails to produce flame spread. This is because FDS 5 does not yet have the features which address the dynamics of foam melting and the reactive nature of the flame. In order to produce flame spread in the model, E of the reactions have been reduced to increase the decomposition rate.

<p>  </p> <p>Polymer bonded explosives (PBX) are a particle reinforced composite containing a high solids loading of explosive particulates bound in a polymer matrix. Commercially produced energetic particulates contain some percentage of flaws in the form of contaminants, porosity, and preexisting fractures. Additional large-scale porosity within the composite is generated during PBX formulation. The introduction of novel additive manufacturing techniques to the energetics field alters the known composite structure and introduces a porosity variable that has not been fully characterized. Porosity collapse during deformation is believed to be a predominant mechanism for hotspot formation, which dominates shock initiation behaviors. These phenomena are difficult to experimentally characterize due to inherent small spectral and temporal scales, and as such numerical and computational models are relied upon to inform fundamental physics. Experimental characterization of the behaviors of energetic materials during deformation is necessary to better inform computational studies and improve our understanding of hotspot formation mechanisms. </p> <p>This dissertation experimentally evaluates the high-rate deformation of porosity in individual explosive particulates and within the overall composite structure. This has included the development of a novel micromachining technique for pore generation in energetic single crystals using the focused ion beam (FIB), resulting in precise and controllable porosity generation that is easily reproducible in collaboration with computational studies. FIB was shown to be an effective pore generation technique, verified by assessing surface roughness and pore quality compared to contemporary manufacturing methods. Three experimental subsets are evaluated: surface cracks in HMX single crystals, polygonal pores in HMX single crystals, and large-scale porosity variations in mock vibration assisted print (VAP) produced composites of borosilicate glass beads and Sylgard 184® binder. A single stage light gas gun was used to impact the samples at 400 m/s and the impact event and resultant material response were observed in real time using x-ray phase contrast imaging (PCI). Machined surface cracks were shown to have negligible effect on the final fracture behaviors of HMX crystals. In polygonal pores fractures were shown to originate due to stress concentration during impact followed by otherwise expected brittle fracture behaviors. For wedge-like pores, the shockwave culminates on the front face of the pore and contributed to early fracture in some samples as well as a consistent open fracture opposite the impact along the shockwave direction in later stages of impact. For the blunt rectangular-like pores two differing behaviors were observed, wherein either the pore condensed and fracture at the pore was not seen during the impact event or large open fractures formed at the pore corners opposite the shockwave. The variance in response is attributed to the energy of fracture dissipating somewhere else in the material bulk, like the behaviors observed in the milled slot samples. Finally, additively manufactured PBX deformation behaviors were observed to be dominated by the collapse of the existing ordered porosity in the bulk which occurred at an increased rate relative to the bulk material compression. This resulted in a three-stage progression of deformation, consisting of a rapid collapse of large-scale ordered porosity, followed by the densification of the remaining features, and ultimately ending in compaction of the bulk as the impact projectile fully compressed the samples. Future work includes exploration of further FIB produced pore effects on dynamic fractures, evaluation of printed material deformation behaviors at additional rates, as well as application and evaluation of additional VAP printed material formulations.  </p>

<p>Predmet istraživanja načelno se odnosi na razmatranje koncepta dvostrukih ventilisanih fasada (DVF) i njihov uticaj na energetsku efikasnost objekta. Ovaj koncept predstavlja jedan od primera adaptivnih fasada. Plan istraživanja zasnovan je na eksperimentalnom radu (na realnom objektu) i na numeričkim simulacijama modela objekta. Rezultati eksperimentalnog dela istraživanja pokazuju na koji način zavise termičke osobine objekta sa DVF od trenutnih meteorolo&scaron;kih uslova. Takođe, ovi rezultati poslužili su za fino pode&scaron;avanje modela i za postizanje &scaron;to vernije slike realnog objekta. Kriterijum prihvatljivosti, kada je model potvrđen, definisani su sa preporučenim statističkim indikatorima. Na taj način, formiran model u daljoj analizi je kori&scaron;ćen za definisanje sezonskih operativnih strategija. Rezultati simulacija za sve predložene operativne strategije, ocenjuju kakav je njihov uticaj na potro&scaron;nju energije za grejanje i klimatizaciju posmatranog objekta. Poređenjem sa modelima objekta sa tradicionalnom fasadom, pokazana je opravdanost primene koncepta DVF u klimatskim uslovima Beograda.</p> / <p>Research generally refers to the consideration of the concept of a double skin facades (DSF) and their impact on energy efficiency of the building. This concept is an example of adaptive facades. The research plan is based on experimental work and on the numerical model simulation. The results of experimental research works show how energy characteristics of the object with the DSF depend of current meteorological conditions. Also, these results were used to fine-tune the model to achieve as closely as possible the real presentation of the real building. The criterion of eligibility, when the model is verified, are defined with the recommended statistical indicators. Validated model in further analysis is used to define seasonal operational strategies. The simulation results for all proposed operational strategies, assess what is their impact on the building energy consumption for heating and air-conditioning. Compared to the models with a traditional facade, analysis show justification for the application of the concept of DSF in the climatic conditions of Belgrade.</p>