This thesis is primarily concerned in studying the relationship between different exponents of Diophantine approximation, which are quantities arising naturally in the study of rational approximation to a fixed n-tuple of real irrational numbers. As Khinchin observed, these exponents are not independent of each other, spurring interest in the study of the spectrum of a given family of exponents, which is the set of all possible values that can be taken by said family of exponents. Introduced in 2009-2013 by Schmidt and Summerer and completed by Roy in 2015, the parametric geometry of numbers provides strong tools with regards to the study of exponents of Diophantine approximation and their associated spectra by the introduction of combinatorial objects called n-systems. Roy proved the very surprising result that the study of spectra of exponents is equivalent to the study of certain quantities attached to n-systems. Thus, the study of rational approximation can be replaced by the study of n-systems when attempting to determine such spectra. Recently, Roy proved two new results for the case n=3, the first being that spectra are semi-algebraic sets, and the second being that spectra are stable under the minimum with respect to the product ordering. In this thesis, it is shown that both of these results do not hold in general for n>3, and examples are given. This thesis also provides non-trivial examples for n=4 where the spectra is stable under the minimum. An alternate and much simpler proof of a recent result of Marnat-Moshchevitin proving an important conjecture of Schmidt-Summerer is also given, relying only on the parametric geometry of numbers instead. Further, a conjecture which generalizes this result is also established, and some partial results are given towards its validity. Among these results, the simplest, but non-trivial, new case is also proven to be true. In a different vein, this thesis considers certain generalizations theta(q) of the classical theta q-series. We show under conditions on the coefficients of the series that theta(q) is neither rational nor quadratic irrational for each integer q>1.