Master of Science / Department of Architectural Engineering / Donald J. Phillippi / For this thesis, research was performed on CFRP bonded composite lap-joints with one and two continuous laminas through the lap. Composite wraps used to retrofit existing structures use lap joints to maintain their integrity. The use of composites for retrofitting structures has many advantages over traditional methods, such as steel jacketing, and is becoming more widely accepted in the structural engineering industry. While much literature exists documenting the performance of composite wraps as a whole when applied to concrete columns, less information is available on the behavior of the lap-joint of the wrap. Developing a better understanding of how the lap-joint behaves will help researchers further understand composite column wraps. This research sought to determine what affect continuous middle laminas may have on the stiffness of lap joints and whether or not stress concentrations exist in the lap-joint due to a change in stiffness.

abstract: The main objective of this study is to investigate the effect of polypropylene fiber morphology on the tensile response of cementitious composites. Two proprietary polypropylene fibers manufactured by BASF – MAC 2200CB, a crimped monofilament macro fiber and MF40, a bundled multi filament polypropylene made up of 500 filaments,40-micron diameter each were compared. The stiff structure and crimped geometry of MAC 2200 CB was studied in comparison with the multifilament MF40, which provide a higher surface area and a bundled fiber effect. Uniaxial tensile tests were performed on individual fibers to study fiber strength and failure pattern at three different gage lengths. The interaction of these 2 fibers with cement matrix was studied under varying strain rate, embedded fiber length and matrix mixes by a series of quassi - static fiber pullout tests. Unidirectional filament wound composite laminates were manufactures with the two fibers and only MF40 woven textiles were used to manufacture MF40 textile reinforced composites. The mechanical behavior of polypropylene fiber and textile reinforced cementitious composites subjected to static tensile loading with the effects of fiber type and dosage, textile weave and dosage, matrix formulations, processing techniques etc. is studied. Evolution of distributed cracking mechanism and local strain fields was documented using digital image correlation (DIC) and correlated with the tensile response and stiffness degradation. VIC 3D-7, commercial software developed by Correlated Solutions, Inc. was used to run the DIC analysis for the tensile tests on laminates. The DIC technique was further used for automated determination of crack density, crack spacing, and characterizing damage evolution. / Dissertation/Thesis / Masters Thesis Civil Engineering 2017

abstract: The concept of Creep is a term used to define the tendency of stressed materials to develop an increasing strain through time under a sustained load, thus having an increase in deflection or having an elongation with time in relation to the short term strain. While the subject of compression creep of concrete is well developed, use of concrete under tension loads has been limited at best due to brittleness of concrete. However with the advent of using fiber reinforced concrete, more and more applications where concrete is expected to carry tensile loads due to incorporation of fibers is gaining popularity. While the creep behavior of concrete in tension is important, the main case of the study is what happened when the concrete that is cracked in service is subjected to sustained loads causing creep. The relationship of opening cracks under these conditions are of utmost importance especially when the serviceability criteria is addressed. Little work has been reported in literature on the long-term behavior of FRC under sustained flexural loadings. The main objective of this study is to investigate the Long Term Flexural Behavior of Pre-Cracked Fiber Reinforced Beams under Sustained Loads. The experimental reports document the effect of loading and temperature on the creep characteristics of concrete. A variety of study has been carried out for the different responses generated by the creep tests based on factors like effect of temperature and humidity, effect of fiber content, effect of fiber type, and effect of different loading levels. The Creep Testing Experimental Methodology is divided into three main parts which includes: (1) The Pre-cracking Partial Fracture Test; (2) Creep Test; (3) Post Creep Full Fracture Test. The magnitude of load applied to a specific specimen during creep testing was based on the results of average residual strength (ARS) tests, determined using EN14651. Specimens of the synthetic FRC mixture were creep tested at loads nominally equivalent to 30% and 50% of the FR1 value. The creep tests are usually continued until a steady Time versus CMOD response was obtained for the specimen signifying its presence in the secondary stage of creep. The creep recovery response is generated after unloading the specimen from the creep set up and later a full fracture test is carried out to obtain the complete post creep response of the beam under flexure. The behavior of the Creep Coefficient versus Time response has been studied using various existing models like the ACI 209-R 92 Model and the CEB-FIP Model. Basic and hybrid rheological viscoelastic models have also been used in order to generate the material behavior response. A study has been developed in order to understand the applicability of various viscoelastic models for obtaining the material response of real materials. An analytical model for predicting the Flexural Behavior of FRC under sustained creep loads is presented at the end. This model helps generate the stress strain and Moment Curvature response of FRC beams when subjected to creep loads post initial cracking / Dissertation/Thesis / Masters Thesis Civil Engineering 2017

The degree of cure and temperature are consistent variables used in models to describe the state of material behaviour development for a thermoset during cure. Therefore, the validity of a cure kinetics model is an underlying concern when combining several material models to describe a part forming process, as is the case for process modeling. The goals of this work are to identify sources of uncertainty in the decision-making process from cure measurement by differential scanning calorimeter (DSC) to cure kinetics modeling, and to recommend practices for reducing uncertainty. Variability of cure kinetics model predictions based on DSC measurements are investigated in this work by a study on the carbon-fiber-reinforced-plastic (CFRP) T800H/3900-2, an interlaboratory Round Robin comparison of cure studies on T800H/3900-2, and a literature review of cure models for Hexcel 8552. It is shown that variability between model predictions can be as large as 50% for some process conditions when uncertainty goes unchecked for decisions of instrument quality, material consistency, measurement quality, data reduction and modeling practices. The variability decreases to 10% when all of the above decisions are identical except for the data reduction and modeling practices. In this work, recommendations are offered for the following practices: baseline selection, balancing heats of reaction, comparing data over an extensive temperature range (300 K), choosing appropriate models to describe a wide range of behaviour, testing model reliability, and visualization techniques for cure cycle selection. Specific insight is offered to the data reduction and analysis of thermoplastic-toughened systems which undergo phase separation during cure, as is the case for T800H/3900-2. The evidence of phase separation is a history-dependent Tg-α relationship. In the absence of a concise outline of best practices for cure measurement by DSC and modeling of complex materials, a list of guidelines based on the literature and the studies herein is proposed. / Applied Science, Faculty of / Materials Engineering, Department of / Graduate

This research program investigates the performance of a steel truss bridge when subjected to both localized web damage and a subsequent post-tensioned strengthening approach. The investigation utilizes a combined approach involving an experimental scale model bridge and a numerical computer model generated using the commercial finite element software RISA 3-D. The numerical model is validated using test data and further extended to parametric studies in order to investigate the theoretical load rating, strain energy, load redistribution, mode shapes and frequency of the bridge for control, damaged and strengthened states. The presence and severity of damage are found to significantly influence the global safety and reliability of the bridge. Also, higher order modes are more susceptible to changes in shape and frequency in the presence of damage. A recovery of truss deflection and a reduction of member forces are achieved by the proposed strengthening method.

By adding annealed plain carbon steel fibers and stainless steel fibers into Ultra-High Performance Concrete (UHPC), we have increased UHPC’s toughness through optimized thermal processing and alloy selection of steel fiber reinforcements. Currently, steel fiber reinforcements used in UHPCs are extremely brittle and have limited energy dissipation mainly through debonding due to matrix crumbling with some pullout. Implementing optimized heat treatments and selecting proper alternative alloys can drastically improve the post-yield carrying capacity of UHPCs for static and dynamic applications through plastic deformations, phase transformations, and fiber pullout. By using a phase transformable stainless steel, the ultimate flexural strength increased from 32.0 MPa to 42.5 MPa (33%) and decreased the post-impact or residual projectile velocity measurements an average of 31.5 m/s for 2.54 cm and 5.08 cm thick dynamic impact panels.

UHPC (ultra-high performance concrete) is a relatively new type of concrete that exhibits mechanical properties that are far superior to those of conventional concrete and in some cases rival those of steel. The main characteristics that distinguish UHPC from conventional reinforced concrete are the improved compressive strength, the tensile strength, the addition of steel fibers, and the resistance to corrosion and degradation. The mechanical properties of UHPC allow for smaller, thinner, lighter sections to be designed while strength is maintained or improved. The use of UHPC has been limited to a few structural applications due to the high cost of the materials and the lack of established design guidelines. A proposed material model based on material and finite element models has served as the foundation of this research effort. The model was used to minimize the dimension of an optimum section in order to limit the material usage and maximize the performance. In the model, the top flange served as the riding surface and contained no reinforcing steel to resist shear. The lack of steel reinforcement allowed for the possibility of a punching shear failure to occur from the application of a point load such as a wheel tire patch load. The model and optimized section served as the foundation for this research, the characterization of punching shear capacity of thin UHPC plates. A total of 12 UHPC slabs were tested to failure to determine the boundary between a flexural failure and a punching shear failure. The variables considered were the slab thickness and loading plate dimensions. The results of the testing were compared to existing models for punching shears and other failure modes, with varying success. The test results aided in the development of a design equation for the prediction of punching shear in UHPC slabs. After evaluation of the test results, recommendations are made as to which model predicts the punching shear capacity of UHPC slabs and the minimum slab thickness required to prevent a punching shear failure. / Master of Science

The role of the interphase in fiberglass reinforced composites was studied by a combination of theoretical analysis, mechanical tests, and several high-resolution analytical techniques. The interphase was varied in composition by using epoxy and polyester matrix polymers with and without added coupling agents, as well as four fiber surface modifications. Different coupling agents on the fibers were shown to change the fiber tensile strength markedly. Filament wound unidirectional composites were tested in short beam "shear." Corresponding samples were fabricated by embedding one to seven fibers in the center of polymer dogbone specimens that were tested in tension to determine critical fiber lengths. Those values were used in a new theoretical treatment (that combines stress gradient shear-lag theory with Weibull statistics) to evaluate "interfacial shear strengths". The fact that results did not correlate with the short beam data was examined in detail via a combination of polarized light microscopy, electron microscopy (SEM) and spectroscopy (XPS or ESCA) and mass spectroscopy (SIMS). When the single fiber specimens were unloaded, a residual birefringent zone was measured and correlated with composite properties, as well as with SIMS and SEM analysis that identified changes in the locus of interphase failure. Variations in the interphase had dramatic effects upon composite properties, but it appears ·that there may be an optimum level of fiber-matrix adhesion depending upon the properties of both fiber and matrix. Fiber-fiber interactions were elucidated by combining tensile tests on multiple fiber dogbone specimens with high-resolution analytical techniques. In general, this work exemplifies a multidisciplinary approach that promises to help understand and characterize the structure and properties of the fiber-matrix interphase, and to optimize the properties of composite materials. / Master of Science

This thesis presents the results of a study done on the damage accumulation process in poly(ether ketone ketone) and its AS4 carbon fiber reinforced composites. The damage accumulation process was studied as a function of applied heat treatment. This study is the result of a project funded by duPont and was done in part to explain the dramatic change in fatigue properties observed at duPont as the applied heat treatment is changed. The mechanical properties were characterized using a battery of tests. The quenched composite systems have lower moduli, but higher toughness and elongations. The quenched systems also have the best fatigue performance and therefore, it can be concluded that the quenched composite systems have the best potential as far as industrial applications are concerned. Quenching has other advantages in industrial applications. These include decreased chances of operator error, and decreased processing times. The damage accumulation process was characterized using the acoustic emission method and also the drop in stiffness during flexure testing. It has been observed that the ultimate mechanical properties show a weak dependence on the applied heat treatment, whereas the damage accumulation process changes dramatically. A model has been developed to simulate the damage accumulation process. This model has then been used to predict the fatigue S-N curve in stroke control and to qualitatively relate it to the available fatigue data in stress control. / Master of Science

published_or_final_version / abstract / Civil Engineering / Master / Master of Philosophy