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The concept of employing engineering thermoplastics as toughness modifiers for Bismaleimide resins was utilized to improve the fracture toughness properties of these important materials, which have applications as matrix resins for high performance composites. Modifier molecular weight, end group functionality, backbone structure and weight percent incorporation were all studied with respect to their influence on K_lc, fracture toughness properties. Increases in fracture toughness were created with thermoplastic oligomers without sacrificing high temperature properties and desirable hot-melt processing conditions. Investigations were also made to study the morphological features that develop within these modified thermosets and their resistance to specific environments. In addition, unidirectional carbon fiber composites were prepared and their mode I and II strain energy release rates measured. Respectable increases in the interlaminar fracture toughness were obtained, 15 and 20 percent by weight loadings of maleimide terminated polysulfone modifiers yielded G_lc values of 489±25 and 734±10 J/m² respectively, a substantial improvement over the control value of 359±17 J/m². Laminates were prepared using carbon fibers that had been investigated in terms of their surface energies using Inverse Gas Chromatography. It was illustrated how this technique could distinguish between the acid-base properties of fibers possessing different degrees of proprietary surface treatments. Fiber composites containing both contrasting and subtle changes at the fiber-matrix interphase were prepared and their mechanical properties evaluated using a variety of test methods. Dramatic increases in laminate properties were measured for composites possessing contrasting interphases. Furthermore, the mode II fracture toughness test was sensitive to interphase differences; however, the mode I fracture toughness test was not. Specimens subjected to the new Continuous Ball Indentation test method (meso-indentation) were compared with single fiber micro-indentation test results. Differences were detected in composites prepared using untreated and surface treated fibers. The new method was also sensitive to changes in matrix ductility. Certain anomalies that were noted to be surprising from micro-indentation measurements were not present in the meso-indentation test results. These observations brought to light certain limitations found within the micro-indentation test, but further supported the new test method as a potential technique for fiber-matrix interphase evaluation. / Ph. D.

A detailed study of the feasibility of anchoring fiber reinforced plastic wires for civil engineering applications is presented. An experimental investigation using tensile testing machines is performed, testing anchorages of 1, 7 and 19 wires. Conventional strain gage and acoustic emission measurement techniques are used. The tests are essential in determining the failure load and failure mode. However, the experimental data alone do not provide enough information about the behavior of the anchorage to be used exclusively in the design process. The results are used to modify the design of the anchorage system. It is shown that for a successful anchorage system the choice of material for the load transfer medium is crucial. A solution is presented to overcome the high stress concentration at the load entry area of the wire into the anchor. A finite element analysis of the anchors for 1 and for 19 wires is used to assess the stress and strain fields inside the anchor, to validate the analytical model, and to determine locations of possible high stress concentrations. Three-dimensional and one-dimensional models, that utilize axisymmetry, are evaluated. The results of the numerical analysis are used to demonstrate the improvement as a result of a change in material choice or design of the anchor. It is shown that the modification of the load transfer medium results in a decrease of 30 % of the average stress level. In the analytical investigation, several common models are introduced that describe the fiber pullout behavior. Based on a recent treatment by C. H. Hsueh, a model is developed that describes the anchorage of a wire in a conical shaped socket using orthotropic materials. This model includes boundary conditions that are similar to the ones observed in the experiments. A parametric study is performed to obtain information on the ideal geometry of the anchor system. The results and predictions of the applied techniques, i. e. analytical description, finite element method and experimental investigation, are compared and contrasted. Based on the analytical, numerical and experimental results, recommendations for improving the design of the anchor system are made. Subsequently, a modified anchor system is proposed that utilizes the properties of a load transfer medium that has a variable stiffness. The inclusion of a pure resin collar and supporting wires is suggested. For a successful completion of this project, ideas are proposed and suggestions made for future work. / Ph. D.

Lewis acid/base interactions were shown to play an important role in the optimization of the interfacial adhesion of reinforcing carbon fibers to thermoplastic polymer matrices. Inverse gas chromatography (IGC) and x-ray photoelectron spectroscopy (XPS) were used to characterize the acid/base nature of the carbon fiber surfaces. Capillary column IGC (CIGC) was used to determine the acid/base nature of thermoplastic polymer surfaces. To quantify the non-dispersive (acid/base) interactions, the dispersive component had to be factored out by separate experiments. The carbon fibers (both surface pretreated and untreated) were found to be predominantly acidic while the polymer matrices (polysulfone, polycarbonate, and polyetherimide) exhibited basic properties. Single fiber fracture tests showed that increased acidity in the fiber surfaces (as a result of surface pretreatment) resulted in a significant improvement in the interfacial adhesion to the basic polymers. The acid/base interactions, however, were not solely responsible for the most favorable adhesion. The dispersive component and thus, the carbon fiber structure also played a role. / Master of Science

Linear viscoelasticity theory is used to analyze the dynamic stability of composite, viscoelastic flat plates subjected to in-plane, biaxial edge loads. In deriving the associated governing equations, a hereditary constitutive law is assumed. In addition, having in view that composite-type structures exhibit weak rigidity in transverse shear, the associated governing equations account for the transverse shear deformations, as well as the transverse normal stress effect. The integro-differential equations governing the stability are solved for simply-supported boundary conditions by using the Laplace transform technique, thus yielding the characteristic equation of the system. In order to predict the effective time-dependent properties of the orthotropic plate, an elastic behavior is assumed for tile fiber, whereas the matrix is considered as linearly viscoelastic. In order to evaluate the nine independent properties of the orthotropic viscoelastic material in terms of its isotropic constituents, the micromechanical relations developed by Aboudi [24] are considered in conjunction with the correspondence principle for linear viscoelasticity. The stability behavior analyzed here concerns the determination of the critical in-plane normal edge loads yielding asymptotic stability of the plate. The problem is studied as an eigenvalue problem. The general dynamic stability solutions are compared with their quasi-static counterparts. Comparisons of the various solutions obtained in the framework of the Third Order Transverse Shear Deformation Theory (TTSD) are made with its first order counterpart. Several special cases are considered and pertinent numerical results are compared with the very few ones available in the field literature. / Master of Science

Approximately fifty percent of the bridges in the United States are considered deficient. The deterioration of the concrete components is a leading cause of the problem. The deterioration of concrete bridge decks is due primarily to corrosion of the reinforcing steel in the concrete. A promising solution to the problem is the use of fiber reinforced plastics (FRP) as a replacement for reinforcing steel. The use of FRP as reinforcement has the following advantages of lightweight, high tensile strength, corrosion resistance, flexibility, and electromagnetic resistance. This paper looks at the use of FRP as reinforcement in concrete beams and compares the information from deflection measurements of different configurations. Also, a material cost comparison is made to determine the cost of using the FRP reinforcement over standard steel reinforcement. Concrete bridge deck systems are designed using steel and fiber-reinforced plastics and allowable stress and load resistance factor methods. Recommendations for further study and uses of FRP are made. / Master of Science

This thesis presents the results of an experimental investigation into the behavior of a pultruded E-glass/polyester fiber reinforced polymer (FRP) composite under sustained loads at elevated temperatures in the range of those that might be seen in service. This investigation involved compression creep tests of material coupons performed at a constant stress level of 33% of ultimate strength and three temperatures levels; 23.3°C (74°F), 37.7°F (100°F), and 54.4°C (130°F). The results of these experiments were used in conjunction with the Findley power law and the Time- Temperature Superposition Principle (TTSP) to formulate a predictive curve for the longterm creep behavior of these pultruded sections. Further experiments were performed to investigate the effects of thermal cycles in order to better simulate service conditions.

Polymeric composites reinforced with bio-materials have advantages over composites with synthetic reinforcements. Bio-based composites use low-cost and renewable reinforcements, have nonabrasive properties for machining, have improved damping characteristics, and have potential for energy recycling. However, the limited use of bio-based composites is because their mechanical properties are typically much lower than those of synthetic composites. The objective of this study was to combine state-of-the-art imaging tools with emerging numerical modeling methods for an integrated, multi-level characterization of bio-based reinforcements and their composites. Digital photography (2D) will allow collection of full-field digital images of the surface of sample composites, which will be used for characterization of the morphological structure of fillers (copper wire or wood particle) and of model composites. Mechanical experiments (tension load) on isolated fillers and on model composites will allow imaging of the deformed material. By correlating relative positions of thousands of surface features between consecutive images, digital image correlation (DIC) algorithms can be used to map surface deformation fields and calculate surface strain fields. Digital imaging methods can only record deformations and strains. The interpretation of those strains in terms of material properties, such as position-dependent modulus of a heterogeneous composite material, requires simultaneous modeling. The modeling must use morphology-based methods that can handle anisotropy, heterogeneity, and the complex structure of bio-based composites such as wood plastic composites. This research used the material point method (MPM) as a modeling tool. MPM is a particle-based, meshless method for solving problems in computational mechanics. The crucial advantage of MPM over other methods is the relative ease of translating pixels from digital images into material points in the analysis. Thus digital images (2D) used in our experiments were used as direct input to the MPM software, so that the actual morphologies, rather than idealized geometries, were modeled. This procedure removes typical uncertainties connected with idealization of the internal features of modeled materials. It also removes variability of specimen to specimen due to morphology variations. Full-field imaging techniques and computer modeling methods for analysis of complex materials have developed independently. This research Coupled imaging and modeling and used inverse problem methodology for studying bio-particulate composites. The potential of coupling experiments with morphology-based modeling is a relatively new area. This work studied the morphology and mechanical properties of copper wire (for validation experiments) and wood particles used for reinforcement in polymer composites. The goal was to determine the in situ mechanical and interfacial properties of copper wire and then wood particles. By comparison of DIC results to MPM, the conclusion is MPM simulation works well by simulating 3D composite structure and using Matlab software to do qualitative and quantitative comparisons. Copper validation tests showed that copper wire is too stiff compared to polymer such that the inclusion modulus had low effect on the surface strains (DIC experimental results). Wood particle worked better because modulus of wood is much lower than copper. By qualitative comparison of the wood particle specimens, we could deduce that the in situ properties of wood particles are lower than bulk wood. Quantitative analysis concentrated on small area and got more exact results. In a 90 degree particle quantitative study, MPM simulations were shown to be capable of tracking the structure of wood particle plastic, which involved failure. The entire approach, however, is not very robust. We can get some results for mechanical properties, but it does not seem possible to extract all anisotropic properties from a few DIC tests, as some researcher have suggested. / Graduation date: 2012

Conserving energy in large structural buildings has become very important in today's economy. A number of buildings today are constructed with sandwich wall panels. Steel connections are most commonly used in these panels. The problem with steel is that it has a tendency to reduce the thermal resistance of the insulation. This project considers glass fiber reinforcing polymers (GFRP) and carbon fiber reinforcing polymers (CFRP) as an alternate material to steel. An experimental sandwich wall panel was constructed and subjected to freezing temperatures. The results of the experimental program were compared to a theoretical model using the ANSYS computer program. The model was verified using current analytical methods that determine the heat flux of a sandwich wall panel. The methods investigated include the parallel path, zone, parallel flow, and isothermal planes methods. The results suggest that the GFRP connectors perform slightly better than the steel and CFRP connectors. / ND EPSCoR

Thesis (M.Tech.:Mechanical Engineering)-Dept. of Mechanical Engineering, Durban University of Technology, 2006 xv, iii, 108 leaves / Fibre Reinforced Plastics (FRPs) have been used in many practical structural applications due to their excellent strength and weight characteristics as well as the ability for their properties to be tailored to the requirements of a given application. Thus, designing with FRPs can be extremely challenging, particularly when the number of design variables contained in the design space is large. For example, to determine the ply orientations and the material properties optimally is typically difficult without a considered approach. Optimization of composite structures with respect to the ply angles is necessary to realize the full potential of fibre-reinforced materials. Evaluating the fitness of each candidate in the design space, and selecting the most efficient can be very time consuming and costly. Structures composed of composite materials often contain components which may be modelled as rectangular plates or cylindrical shells, for example. Modelling of components such as plates can be useful as it is a means of simplifying elements of structures, and this can save time and thus cost. Variations in manufacturing processes and user environment may affect the quality and performance of a product. It is usually beneficial to account for such variances or tolerances in the design process, and in fact, sometimes it may be crucial, particularly when the effect is of consequence. The work conducted within this project focused on methodologies for optimally designing fibre-reinforced laminated composite structures with the effects of manufacturing tolerances included. For this study it is assumed that the probability of any tolerance value occurring within the tolerance band, compared with any other, is equal, and thus the techniques are aimed at designing for the worst-case scenario. This thesis thus discusses four new procedures for the optimization of composite structures with the effects of manufacturing uncertainties included.